The structural role of Ti in aluminosilicate liquids in the glass transition range: insights from heat capacity and shear viscosity measurements     

Mathieu Roskosz  M.J Toplis 《Geochimica et cosmochimica acta》2004,68(3):591-606

The shear viscosities and 1 bar heat capacities of glasses and melts along the 67mol% silica isopleth in the system SiO₂-Al₂O₃-Na₂O-TiO₂ have been determined in the temperature ranges 780-1140 K and 305-1090 K respectively. Anomalous behaviour of both these properties is observed for compositions rich in TiO₂ and/or Al₂O₃, an observation attributed to liquid-liquid phase separation followed by anatase crystallization. For samples which do not show anomalous behaviour, it is found that the partial molar heat capacity of the TiO₂ component previously determined in Al-free compositions reproduces our heat capacities to within 1.3%. Viscosity data show that addition of TiO₂ tends to increase viscosity and melt fragility at constant temperature. Furthermore, heat capacity and viscosity data may be combined within the framework of the Adam-Gibbs theory to extract values of the configurational entropy of the liquids and qualitative estimates of the variation of the average energy barrier to viscous flow. Configurational entropy at 900K is inferred to decrease upon addition of TiO₂, in contrast to previous results from Al-free systems. The compositional limit separating normal from anomalous behaviour, as well as the data for homogenous melts have been used to constrain the structural role of Ti in these samples. Our data are consistent with a majority of Ti in five-fold coordination associated with a titanyl bond, in agreement with previous spectroscopic studies. Furthermore, we find no evidence for a Ti-Al interaction in our samples, and we are led to the conclusion that Al and Ti are incompletely mixed, a hypothesis consistent with the observed reduction of configurational entropy upon addition of TiO₂, suggesting an important role of medium range order in controlling the variations in thermodynamic properties.  相似文献   

Dynamic theory of rigid-plasticity     

Meiketsu  Binh Xuan  Noboru  Katsuhisa 《Soil Dynamics and Earthquake Engineering》2005,25(7-10):635-647

This paper deals with an analysis method for the response and motion of soil-like rigid-plastic bodies under seismic loading conditions. A continuity condition to determine the acceleration distribution within the rigid-plastic body when the failure occurs during seismic motions is proposed. Combining this continuity condition of acceleration and the ‘Generalized Limit Equilibrium Method (GLEM)’, the responses of the earth structure during seismic motions as well as the permanent displacements can be obtained, where GLEM is one of the limit equilibrium methods proposed by the authors for static problems and providing the approximate solution for Kötter's equation. The theoretical formulation of the method, the illustrative examples, and some comparisons between the analytical and experimental results are demonstrated.  相似文献   

Delayed geochemical hazard: Concept, digital model and case study     

CHEN Ming  FENG Liu  Jacques Yvon 《中国科学D辑(英文版)》2005,48(Z2)

Delayed Geochemical Hazard (DGH briefly) presents the whole process of a kind of serious ecological and environmental hazard caused by sudden reactivation and sharp release of long-term accumulated pollutant from stable species to active ones in soil or sediment system due to the change of physical-chemical conditions (such as temperature, pH, Eh, moisture, the concentrations of organic matters, etc.) or the decrease of environment capacity. The characteristics of DGH are discussed. The process of a typical DGH can be expressed as a nonlinear polynomial. The points where the derivative functions of the first and second orders of the polynomial reach zero, minimum and maximum are keys for risk assessment and harzard pridication.The process and mechanism of the hazard is due to the transform of pollutant among different species principally. The concepts of "total releasable content of pollutant", TRCP, and "total concentration of active specie", TCAS, are necessarily defined to describe the mechanism of DGH. The possibility of the temporal and spatial propagation is discussed. Case study shows that there exists a transform mechanism of "gradual release" and "chain reaction" among the species of the exchangeable and the bounds to carbonate, iron and manganese oxides and organic matter, thus causing the delayed geochemical hazard.  相似文献   

Developing efficient scalar and vector intensity measures for IDA capacity estimation by incorporating elastic spectral shape information     

Dimitrios Vamvatsikos  C. Allin Cornell 《地震工程与结构动力学》2005,34(13):1573-1600

Scalar and vector intensity measures are developed for the efficient estimation of limit‐state capacities through incremental dynamic analysis (IDA) by exploiting the elastic spectral shape of individual records. IDA is a powerful analysis method that involves subjecting a structural model to several ground motion records, each scaled to multiple levels of intensity (measured by the intensity measure or IM), thus producing curves of structural response parameterized by the IM on top of which limit‐states can be defined and corresponding capacities can be calculated. When traditional IMs are used, such as the peak ground acceleration or the first‐mode spectral acceleration, the IM‐values of the capacities can display large record‐to‐record variability, forcing the use of many records to achieve reliable results. By using single optimal spectral values as well as vectors and scalar combinations of them on three multistorey buildings significant dispersion reductions are realized. Furthermore, IDA is extended to vector IMs, resulting in intricate fractile IDA surfaces. The results reveal the most influential spectral regions/periods for each limit‐state and building, illustrating the evolution of such periods as the seismic intensity and the structural response increase towards global collapse. The ordinates of the elastic spectrum and the spectral shape of each individual record are found to significantly influence the seismic performance and they are shown to provide promising candidates for highly efficient IMs. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

挤扩支盘桩极限承载力的预测   总被引：2，自引：0，他引：2  

高笑娟  杨晓斌 《岩土工程技术》2005,19(5):254-257

用双曲线方法对110根挤扩支盘桩的极限承载力进行预测,并与直杆桩预测结果进行对比。结果表明由于支盘桩受力性状复杂,加载前期和中期预测精度较高,后期较低,误差超过15%;支盘桩的沉降曲线出现台阶时预测值与实测值误差较大;支盘桩极限承载力的预测精度与工程地质条件和桩本身的参数密切相关,桩身参数和地质条件相同条件下各桩预测精度比较接近。总体上直杆桩的预测结果优于支盘桩。  相似文献   

钻孔灌注桩后压浆作用机理与应用     

陈飞  兰凯 《地质科技情报》2005,24(Z1):97-100

通过对桩侧和桩底后压浆,可大幅度提高钻孔灌注桩单桩承载力.应用桩-土理论分析了后压浆中浆液对土体及桩体的作用,并从分析影响桩基承载力的因素出发,研究了后压浆的作用机理.在渗透率小的地层中后压浆以压密注浆为主,在渗透率大的地层中后压浆以渗透注浆为主.为避免过分压裂土层,在压浆过程中应控制灌浆压力.压浆量是影响后压浆质量和提高单桩承载力的关键因素之一.  相似文献   

Analysis on Bearing Capacity of Tunnel-Type Anchorage of a Long-Span Suspension Bridge     

Zhu Yu Wei Jun Yang Manjuan Li Hao Liu Hongqing 《中国地质大学学报(英文版)》2005,16(3):277-282

INTRODUCTION Tunnel typeanchoragehasobviousadvantages inbearingcapacityversusinvestment(LiuandHu,1996).However,itisrarelyusedinapracticalpro jectbecauseofitsrequirementofgoodrockcondi tions.Siduhebridge(Fig.1),whichliesintheBa dongmountainsinthewestplatea…  相似文献   

Uncertainty in adaptive capacity     

W. Neil Adger  Katharine Vincent 《Comptes Rendus Geoscience》2005,337(4):399-410

The capacity to adapt is a critical element of the process of adaptation: it is the vector of resources that represent the asset base from which adaptation actions can be made. Adaptive capacity can in theory be identified and measured at various scales, from the individual to the nation. The assessment of uncertainty within such measures comes from the contested knowledge domain and theories surrounding the nature of the determinants of adaptive capacity and the human action of adaptation. While generic adaptive capacity at the national level, for example, is often postulated as being dependent on health, governance and political rights, and literacy, and economic well-being, the determinants of these variables at national levels are not widely understood. We outline the nature of this uncertainty for the major elements of adaptive capacity and illustrate these issues with the example of a social vulnerability index for countries in Africa. To cite this article: W.N. Adger, K. Vincent, C. R. Geoscience 337 (2005).  相似文献   

生态足迹模型在山区生态可持续评价中的初步应用--以1999年北京西部山区为例   总被引：3，自引：0，他引：3  

李红  张凤荣  孙丹峰  周连第 《山地学报》2005,23(5):636-640

在剖析生态足迹分析法的理论基础上，进一步考虑不同消费水平对生态足迹时空变异的影响，划分农村居民和城镇居民两类不同的消费群体，分别计算各自的生态足迹，其次进一步细化模型中人均水资源足迹，从而构建生态足迹与生态容量平衡模型。根据平衡模型计算出生态盈亏，得出区域生态持续性评价结果。并以1999年北京西部山区门头沟区为例，进行模型计算和生态可持续评价，结果表明1999年门头沟区处于生态赤字状态，说明该区生态系统处于不可持续状态。在对门头沟区的初步研究基础上，指出生态足迹作为山区生态可持续评价指标的优点及当前存在的缺点。  相似文献   

Why asymptotic limit of the acid dissolution capacity can lead to a sharp dissolution front in chemical dissolution of porous rocks?          下载免费PDF全文

Chongbin Zhao  B.E. Hobbs  A. Ord 《国际地质力学数值与分析法杂志》2017,41(15):1590-1602

The use of the asymptotic limit can greatly simplify the theoretical analysis of chemical dissolution front instabilities in fluid‐saturated rocks and therefore make it possible to obtain mathematical solutions, which often play a crucial role in understanding the propagation behavior of chemical dissolution fronts in chemical dissolution systems. However, there has been a debate in recent years that the asymptotic limit of the acid dissolution capacity (i.e., the acid dissolution capacity number approaching zero) alone cannot lead to a sharp dissolution front of the Stefan type in the acidization dissolution system, in which the dissolvable minerals of carbonate rocks are chemically dissolved by the injected acid flow. The acid dissolution capacity number is commonly defined as the ratio of the volume of the carbonate rock dissolved by an acid to that of the acid. In this paper, we use four different proof methods, including (i) direct use of the fundamental concepts; (ii) use of the mathematical governing equations of an acidization dissolution system; (iii) use of the different time scaling approach; and (iv) use of a moving coordinate system approach, to demonstrate that the asymptotic limit of the acid dissolution capacity can indeed lead to sharp dissolution fronts of the Stefan type in acidization dissolution systems on a much larger time scale (than the dissolution time scale). Our new finding is that on the reaction time scale, the condition of the conventional time derivative of porosity approaching zero alone can ensure that the acidization dissolution front has a sharp shape of the Stefan type. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献