The structural role of Ti in aluminosilicate liquids in the glass transition range: insights from heat capacity and shear viscosity measurements     

Mathieu Roskosz  M.J Toplis 《Geochimica et cosmochimica acta》2004,68(3):591-606

The shear viscosities and 1 bar heat capacities of glasses and melts along the 67mol% silica isopleth in the system SiO₂-Al₂O₃-Na₂O-TiO₂ have been determined in the temperature ranges 780-1140 K and 305-1090 K respectively. Anomalous behaviour of both these properties is observed for compositions rich in TiO₂ and/or Al₂O₃, an observation attributed to liquid-liquid phase separation followed by anatase crystallization. For samples which do not show anomalous behaviour, it is found that the partial molar heat capacity of the TiO₂ component previously determined in Al-free compositions reproduces our heat capacities to within 1.3%. Viscosity data show that addition of TiO₂ tends to increase viscosity and melt fragility at constant temperature. Furthermore, heat capacity and viscosity data may be combined within the framework of the Adam-Gibbs theory to extract values of the configurational entropy of the liquids and qualitative estimates of the variation of the average energy barrier to viscous flow. Configurational entropy at 900K is inferred to decrease upon addition of TiO₂, in contrast to previous results from Al-free systems. The compositional limit separating normal from anomalous behaviour, as well as the data for homogenous melts have been used to constrain the structural role of Ti in these samples. Our data are consistent with a majority of Ti in five-fold coordination associated with a titanyl bond, in agreement with previous spectroscopic studies. Furthermore, we find no evidence for a Ti-Al interaction in our samples, and we are led to the conclusion that Al and Ti are incompletely mixed, a hypothesis consistent with the observed reduction of configurational entropy upon addition of TiO₂, suggesting an important role of medium range order in controlling the variations in thermodynamic properties.  相似文献   

From Chicago to L.A. and Back Again: A Chicago‐Inspired Quantitative Analysis of Income Distribution in Montreal*     

Richard Shearmur  Mathieu Charron 《The Professional geographer》2004,56(1):109-126

In a recent issue of Urban Geography (2001) , a number of key players in the 1960s and 1970s school of quantitative urban geography (called Chicago II in this article) set out some of the approach's key methodological premises and assessed its influence in the wider arena of urban studies. At about the same time, the 1920s and 1930s Chicago School of urban sociology (called the Chicago School in this article) was being reassessed in France ( Huet 2000 ), and deconstructed in Los Angeles ( Dear 2001 ). In this article, we outline a selection of basic models of urban space proposed by the Chicago School and further elaborated by Chicago II. We then consider certain aspects of three important critiques: humanist/aesthetic, Marxist, and postmodern. We argue that none of these invalidates the Chicago II approach to the study of urban areas, and we demonstrate its resilience and usefulness by way of the empirical example of Montreal. Though the results are of interest in their own right, the principal purpose of the analysis is to illustrate the type of insight that a structured quantitative approach provides and the way this approach rests on a theoretical understanding of processes at work in cities. We conclude by arguing that the humanist and Marxist critiques shed important light upon the possibilities and limits of the Chicago II approach, but that the postmodern claim that the spatial development of urban areas is not structured by at least some general processes is inaccurate.  相似文献   

Mantle tectonics beneath New Zealand inferred from SKS splitting and petrophysics   总被引：1，自引：0，他引：1  

Mathieu Duclos  Martha K. Savage  réa Tommasi  Ken R. Gledhill 《Geophysical Journal International》2005,163(2):760-774

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Hydro-geochemistry of groundwater and surface water in Dschang town(West Cameroon): Alkali and alkaline-earth elements ascertain lithological and anthropogenic constraints          下载免费PDF全文

Yemeli Elida Joelle  Temgoua Emile  Kengni Lucas  Ambrosi Jean-Paul  Momo-nouazi Mathieu  Silatsa-Tedou Francis Brice  Wamba Franck Robean  Tchakam-Kamtchueng Brice 《地下水科学与工程》2021,9(3):212-224

This study focuses on the sources of alkali and alkaline-earth elements based on the geochemistry of groundwater and surface water in Dschang concerning environmental and anthropogenic constraints. A comprehensive set of 50 samples from groundwater and surface water were analyzed by ICPMS and processed by spatial interpolation in a GIS environment. The results highlight a geochemical anomaly at the center of the densely inhabited area subject to a profusion of open dumps discharges. This anomaly with the highest spatial contents of Be(Cs, Rb, Mg) suggests an anthropogenic source that demarcates with the lowest alkali and alkaline-earth elements on the peripheral area of Dschang. Other findings include lithological constraints with volcanic rocks being the main source compared to granitoid.The study points out good correlations between Be, Cs, Rb and Mg spatial distributions and physicochemical parameters of waters(K, EC, TDS), and inversely with the lowest p H. p H is established as the most functioning physico-chemical constraint of alkali and alkaline-earth mobility in Dschang. The p H lowest values within the geochemical anomaly also highlight the impact of human activities on water acidity, which later enhance elements mobility and enrichment. Despite low elements contents relative to WHO standards, our findings point out an example of anthropogenic impact on water geochemistry linked to solid waste pollution; it also demonstrates significant anthropogenic changes of environmental physicochemical parameters of prime importance in the mobility and distribution of elements in the study area.Similar assessments should be extended in major towns in Cameroon.  相似文献   

CONSONORM_HG: a new method of norm calculation for mid‐ to high‐grade metamorphic rocks          下载免费PDF全文

L. Mathieu  S. Trépanier  R. Daigneault 《Journal of Metamorphic Geology》2016,34(1):1-15

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Methane-derived authigenic carbonates from active hydrocarbon seeps of the St. Lawrence Estuary,Canada     

Denis Lavoie  Nicolas Pinet  Mathieu Duchesne  Andrée Bolduc  Richard Larocque 《Marine and Petroleum Geology》2010

Nearly 2000 pockmarks with diameters ranging from a few tens of meters up to 700 m are present on the seafloor of the St. Lawrence Estuary in eastern Canada. Coring of some pockmarks resulted in the recovery of various-sized and shaped carbonate concretions in a predominantly silty mud matrix. Petrographic and geochemical data on four authigenic carbonate concretions are reported as well as data from shell material in the unconsolidated sediment. Video observations and echo-sounder images indicate that the sampled pockmarks are actively gas venting. The video images show significant look-alike microbial mats in areas where gas is venting. The carbonate concretions are primarily made up of carbonate cements with varying percentage of shell fragments, micrite particles and fine-grained clastics. Orthorhombic crystal morphology and diagenetic fabrics including isopachous layers and botryoids characterize the aragonite cement. Oxygen isotopes ratios for the cement crusts do not record any thermal anomaly at the site of precipitation with δ¹⁸O_VPDB ratios (+3‰) in equilibrium with cold (5 °C) deep marine waters, whereas significant negative δ¹³C_VPDB ratios (−9.9 to −33.5‰) for cement and shell material within concretions indicate that the carbonates largely derive from the microbial oxidation of methane. The δ¹³C_VPDB ratios of aragonite shells (−2.7 to −5.6‰) taken from unconsolidated sediments at some distance from the concretions/vents show variable dilution of HCO₃⁻ with negative δ¹³C_VPDB ratios derived from microbial oxidation of methane with isotopically normal (0‰) marine bicarbonate. These results are in agreement with other lines of evidence suggesting that pockmarks formed through the recent and still active release of gas from a reservoir within the Paleozoic sedimentary succession.  相似文献   

Field‐based and spectral indicators for soil erosion mapping in semi‐arid mediterranean environments (Coastal Cordillera of central Chile)     

Renaud Mathieu  Bernard Cervelle  Dominique Rémy  Marcel Pouget 《地球表面变化过程与地形》2007,32(1):13-31

The Coastal Cordillera of central Chile is naturally sensitive to soil erosion due to moderate to steep slopes, intense winter rains when the vegetation cover is scarce, and deeply weathered granitic rocks. In 1965, 60 per cent of its surface was moderately to very severely eroded. Today this process is still largely active, but no data are currently available to evaluate the real extent, distribution and severity of soil degradation on a regional scale. This information is vital to support efficient soil conservation plans. A multi‐scale approach was implemented to produce regional land degradation maps based on remote sensing technologies. Fieldwork has shown that the surface colour or ‘redness’ and the density of coarse fragments are pertinent erosion indicators to describe a typical sequence of soil degradation in the context of mediterranean soil developed on granitic materials and micaschists. Field radiometric experiments concluded that both factors influence the reflectance of natural surfaces and can be modelled using radiometric indices accessible from most satellites operating in the optical domain, i.e. redness index and brightness index. Finally the radiometric indices were successfully applied to SPOT images to produce land degradation maps. Only broad classes of erosion status were discriminated and the detection of the degradation processes was only possible when most of the fertile layer had already been removed. This technology provides decision‐making information required to develop regional soil conservation plans and to prioritize actions between catchment areas, especially in vast inter‐tropical regions where spatialized data are not always readily available. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

Flexible Automatic Scheduling for Autonomous Telescopes: The MAJORDOME     

Mathieu Bringer  Michel Boër  Cedric Peignot  Gérard Fontan  Colette Mercé 《Experimental Astronomy》2001,12(1):33-48

We have developped a new method for the scheduling ofastronomical automatic telescopes, in the framework of theautonomous TAROT instrument. The MAJORDOME software canhandle a variety of observations, constrained, periodic,etc., and produces a timeline for the night, which may bemodified at any time to take into account the specificconditions of the night. The MAJORDOME can also handletarget of opportunity observations without delay.  相似文献   

A simple mass estimate for central black holes in cuspy galaxies     

Herwig Dejonghe  Anne Mathieu  Veronique De Bruyne  Sven De Rijcke 《Celestial Mechanics and Dynamical Astronomy》1998,72(3):219-233

We argue that the temperature of the stellar phase is likely a monotically decreasing function of radius in the central regions of elliptical galaxies with cusps. We show that it requires the presence of a central mass concentration. An estimate of its minimum mass based on few parameters is given. This lower bound is consistent with current mass values of the central objects in galaxies derived from detailed models. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Precipitation water storage capacity in a temperate mixed oak–beech canopy     

Frédéric André  Mathieu Jonard  Quentin Ponette 《水文研究》2008,22(20):4130-4141

The storage capacity of a temperate mixed oak–beech stand was investigated as a function of stand density and species composition. Measurements were performed in selected zones delimited by three neighbouring trees. Three independent approaches were compared: (i) a spraying laboratory experiment to estimate the water storage on foliage before and after dripping; (ii) a mechanistic model describing rainfall partitioning within the forest canopy and providing estimates of foliage storage capacities; and (iii) linear regression analyses to evaluate the canopy (foliage + branches) storage capacity using the relationship between throughfall and rainfall. Good agreement was generally observed between the laboratory experiment and the mechanistic model estimates, while estimations from the regression method tended to exceed those from the other approaches. Storage capacity estimates ranged from 0·22 mm to 0·80 mm for pure oak zones, from 0·24 mm to 1·12 mm for mixed zones and from 0·53 mm to 1·17 mm for pure beech zones. The increase of storage capacity with increasing proportion of beech in the canopy resulted from higher beech LAI compared with oak. Similarly, for mixed and pure beech canopies, storage capacity was higher for high density zones than for low density zones as a result of the increase in LAI with increasing local basal area; in contrast, for pure oak, the storage capacity was not related to basal area because of the lower shade‐tolerance of this species compared with beech. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献