河流调整中的熵、熵产生和能耗率的变化   总被引：8，自引：0，他引：8       下载免费PDF全文

徐国宾  练继建 《水科学进展》2004,15(1):1-5

河流是一个真正的开放系统,而不是孤立系统或封闭系统。运用经典热力学和非平衡态热力学基本原理,分析研究了河流调整中的熵、熵产生和能耗率的变化。指出:熵和熵产生是两个不同的概念;最小熵产生原理等价于最小能耗率原理;冲积河流在调整过程中遵循最小熵产生原理或最小能耗率原理,而不是最大熵原理。  相似文献   

The structural role of Ti in aluminosilicate liquids in the glass transition range: insights from heat capacity and shear viscosity measurements     

Mathieu Roskosz  M.J Toplis 《Geochimica et cosmochimica acta》2004,68(3):591-606

The shear viscosities and 1 bar heat capacities of glasses and melts along the 67mol% silica isopleth in the system SiO₂-Al₂O₃-Na₂O-TiO₂ have been determined in the temperature ranges 780-1140 K and 305-1090 K respectively. Anomalous behaviour of both these properties is observed for compositions rich in TiO₂ and/or Al₂O₃, an observation attributed to liquid-liquid phase separation followed by anatase crystallization. For samples which do not show anomalous behaviour, it is found that the partial molar heat capacity of the TiO₂ component previously determined in Al-free compositions reproduces our heat capacities to within 1.3%. Viscosity data show that addition of TiO₂ tends to increase viscosity and melt fragility at constant temperature. Furthermore, heat capacity and viscosity data may be combined within the framework of the Adam-Gibbs theory to extract values of the configurational entropy of the liquids and qualitative estimates of the variation of the average energy barrier to viscous flow. Configurational entropy at 900K is inferred to decrease upon addition of TiO₂, in contrast to previous results from Al-free systems. The compositional limit separating normal from anomalous behaviour, as well as the data for homogenous melts have been used to constrain the structural role of Ti in these samples. Our data are consistent with a majority of Ti in five-fold coordination associated with a titanyl bond, in agreement with previous spectroscopic studies. Furthermore, we find no evidence for a Ti-Al interaction in our samples, and we are led to the conclusion that Al and Ti are incompletely mixed, a hypothesis consistent with the observed reduction of configurational entropy upon addition of TiO₂, suggesting an important role of medium range order in controlling the variations in thermodynamic properties.  相似文献   

Entropy Analysis of Multiple Scale Causality and Qualitative Causal Shifts in Spatial Systems*     

Jonathan D. Phillips 《The Professional geographer》2005,57(1):83-93

Spatial systems are typically characterized by multiple controlling factors and processes operating at different spatial and temporal scales (multiple scale causality [MSC]). An entropy decomposition‐based approach to MSC is presented here in two contexts. First, given maps or distributions of an observed phenomenon at two or more scales, the contribution at more local or global (relative to the primary scale of observation) controls to the observed entropy can be estimated. Second, a theoretical treatment of the entropy decomposition equations shows that as the range of scale is increased by broadening or narrowing resolutions or by incorporating more controls, the influence of larger or smaller‐scale influences not only changes, but may change qualitatively, e.g., in terms of having positive (entropy‐increasing) or negative (information‐increasing) effects. Such qualitative causal shifts have implications for efforts to use any single causal explanation across the molecular to planetary spatial and instantaneous to geological range of scales relevant to physical geography. The entropy decomposition method is illustrated with an application to soil landscapes in the Ouachita Mountains, Arkansas.  相似文献   

Are peatlands in different states with respect to their thermodynamic behaviour? A simple test of peatland energy and entropy budgets     

Fred Worrall  Ross Morrison  Chris Evans  Joerg Kaduk  Susan Page  Alex Cumming  Mark Rayment  Nicholas Kettridge 《水文研究》2021,35(12):e14431

Whilst all ecosystems must obey the second law of thermodynamics, these physical bounds and controls on ecosystem evolution and development are largely ignored across the ecohydrological literature. To unravel the importance of these underlying restraints on ecosystem form and function, and their power to inform our scientific understanding, we have calculated the entropy budget of a range of peat ecosystems. We hypothesize that less disturbed peatlands are ‘near equilibrium’ with respect to the second law of thermodynamics and thus respond to change by minimizing entropy production. This ‘near equilibrium’ state is best achieved by limiting evaporative losses. Alternatively, peatlands ‘far-from-equilibrium’ respond to a change in energy inputs by maximizing entropy production which is best achieved by increasing evapotranspiration. To test these alternatives this study examined the energy balance time series from seven peatlands across a disturbance gradient. We estimate the entropy budgets for each and determine how a change in net radiation (ΔR_n) was transferred to a change in latent heat flux (ΔλE). The study showed that: (i) The transfer of net radiation to latent heat differed significantly between peatlands. One group transferred up to 64% of the change in net radiation to a change in latent heat flux, while the second transferred as little as 27%. (ii) Sites that transferred the most energy to latent heat flux were those that produced the greatest entropy. The study shows that an ecosystem could be ‘near equilibrium’ rather than ‘far from equilibrium’.  相似文献   

A fully coupled THM model based on a non‐equilibrium thermodynamic approach and its application          下载免费PDF全文

Z. Zhang  X. Cheng 《国际地质力学数值与分析法杂志》2017,41(4):527-554

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纹理特征向量与最大化熵法相结合的SAR影像非监督变化检测   总被引：1，自引：0，他引：1  

庄会富  邓喀中  范洪冬 《测绘学报》2016,45(3):339-346

合成孔径雷达(SAR)影像具有明显的斑点噪声,在变化检测中,一般需要考虑空间邻域信息。本文结合SAR影像丰富的纹理信息,提出一种考虑空间邻域信息的高分辨率SAR影像非监督变化检测方法,用基于灰度共生矩阵(GLCM)的32维纹理特征向量构造差异影像。通过最大化熵法自动选取阈值,对精度指标随窗口大小的变化进行回归分析,得到适合于变化检测的窗口为11×11。试验表明,本文方法优于马尔科夫随机场法,可以减小斑点噪声的影响,有效提高高分辨率SAR影像变化检测的精度。  相似文献   

县域经济发展水平评价及时空格局演变——以河北省为例   总被引：1，自引：0，他引：1  

陈红娟  冯文钊  彭立芹 《测绘科学》2016,(4):97-101

针对河北省县域经济发展特点和时空变化规律的问题,该文将GIS技术与定量分析方法相结合,选取2000年和2010年的15个能够反映河北省县域经济发展状况的指标,采用熵值法系统地测算了河北省136个县的经济发展水平,并利用空间自相关分析法分析了河北省县域经济发展空间格局的演变特征。研究结果表明:河北省县域经济发展依然存在明显的南北差异,并已形成"一线+两点"的经济空间格局;2000—2010年,Moran指数不断下降,高-高集聚区和低-低集聚区的县域数量与土地面积不断减少,河北省县域经济集聚效应减弱,经济发展渐趋均衡。  相似文献   

Temporal replication of the national land cover database using active machine learning     

Galen J. Maclaurin 《地理信息系统科学与遥感》2016,53(6):759-777

Regional and national level land cover datasets, such as the National Land Cover Database (NLCD) in the United States, have become an important resource in physical and social science research. Updates to the NLCD have been conducted every 5 years since 2001; however, the procedure for producing a new release is labor-intensive and time-consuming, taking 3 or 4 years to complete. Furthermore, in most countries very few, if any, such releases exist, and thus there is high demand for efficient production of land cover data at different points in time. In this paper, an active machine learning framework for temporal updating (or backcasting) of land cover data is proposed and tested for three study sites covered by the NLCD. The approach employs a maximum entropy classifier to extract information from one Landsat image using the NLCD, and then replicate the classification on a Landsat image for the same geographic extent from a different point in time to create land cover data of similar quality. Results show that this framework can effectively replicate the land cover database in the temporal domain with similar levels of overall and within class agreement when compared against high resolution reference land cover datasets. These results demonstrate that the land cover information encapsulated in the NLCD can effectively be extracted using solely Landsat imagery for replication purposes. The algorithm is fully automated and scalable for applications at landscape and regional scales for multiple points in time.  相似文献   

Modeling the risk of spread and establishment for Asian longhorned beetle (Anoplophora glabripennis) in Massachusetts from 2008-2009     

Andrew J. Shatz  Florencia Sangermano  Jennifer Miller  Arthur Elmes 《国际地球制图》2016,31(8):813-831

Land managers responsible for invasive species removal in the USA require tools to prevent the Asian longhorned beetle (Anoplophora glabripennis) (ALB) from decimating the maple-dominant hardwood forests of Massachusetts and New England. Species distribution models (SDMs) and spread models have been applied individually to predict the invasion distribution and rate of spread, but the combination of both models can increase the accuracy of predictions of species spread over time when habitat suitability is heterogeneous across landscapes. First, a SDM was fit to 2008 ALB presence-only locations. Then, a stratified spread model was generated to measure the probability of spread due to natural and human causes. Finally, the SDM and spread models were combined to evaluate the risk of ALB spread in Central Massachusetts in 2008–2009. The SDM predicted many urban locations in Central Massachusetts as having suitable environments for species establishment. The combined model shows the greatest risk of spread and establishment in suitable locations immediately surrounding the epicentre of the ALB outbreak in Northern Worcester with lower risk areas in suitable locations only accessible through long-range dispersal from access to human transportation networks. The risk map achieved an accuracy of 67% using 2009 ALB locations for model validation. This model framework can effectively provide risk managers with valuable information concerning the timing and spatial extent of spread/establishment risk of ALB and potential strategies needed for effective future risk management efforts.  相似文献   

基于模糊熵的GLLE熵阈值分割方法     

何春明  许磊  卢国胜  邓丽珍 《南京气象学院学报》2019,11(6):757-763

图像分割是计算机视觉中基础且重要的一个问题.熵阈值图像分割作为一种有效的分割方法,被广泛应用于模式识别和图像处理中.传统的图像分割方法并不能获得足够有效的图像特征.为解决这个问题且进一步探究熵阈值在图像分割中的应用,引入一种GLLE（Gray Level and Local Entropy）二维直方图改进熵阈值图像分割模型,并提出了基于模糊熵的方法计算所建立的二维直方图模型.通过标准实验数据集上的对比实验表明,基于模糊熵的GLLE熵阈值分割方法可以得到更加准确的阈值,提高了分割精度.同时在处理不同类型图像的表现上优于往常的算法,具有更强的鲁棒性.  相似文献