原子荧光光谱法测定化探样品时有机质对As,Sb,Bi的干扰   总被引：1，自引：0，他引：1  

汪明启  刘应汉 《地质科技情报》2003,22(1):105-109

通过研究黑龙江省森林沼泽景观区有机水系沉积物（泥炭）、土壤中As,Sb,Bi的测定结果，发现样品中的有机质对王水消解氢化物原子荧光法测定上述元素存在极大的干扰，提出采用低温（＜450℃）灰化处理可完全消除干扰。对比研究还发现，过去森林沼泽景观区的区域化探扫面资料中的As,Sb,Bi数据存在问题，应专门对其进行评价研究。  相似文献   

煤岩显微组分热解气相色谱特征与化学结构剖析   总被引：3，自引：0，他引：3       下载免费PDF全文

孙旭光  陈建平等 《地质学报》2003,77(1):135-143

煤结构是目前地球化学研究领域中的一个难点，但却具有极其重要的理论及实际意义，本文采用分步热解气相色谱技术将树皮体，镜质体和丝质体分解为分子量较小的可测定的有机化合物，在此基础上，据不同温度下热解产物的组成特征来还原显微组分的化学结构，实验结果表明，煤显微组分主要由四大类官能团组成，一是热稳定性较低的NOS杂原子官能团；二是脂族（脂链、脂环）结构；三是苯、烷基苯（甲苯、二甲苯）、萘等芳香族化合物，四是热稳定性很高的难以分解的稠环芳烃。上述四类化合物集中于显微组分的不同结构简单中，树皮体和镜质体结构单元外侧主要由热稳定性较低的杂原子化合物以及分子量较小的苯和烷基苯组成，而丝质体结构单元外侧则主要以短链脂族结构为主，三组分结构核部由热稳定性很高的难以分解的稠环芳烃组成。连结核部稠环芳烃与结构单元外侧杂原子等官能团的主要是热稳定性较高的脂链结构，煤显微组分热成烃主要按结构中各官能团键的强弱随热演化程度的加深依次脱除，生成油气，基本上属平行独立依次反应机制，亦“官能团脱除型”，此外，还包括少量的长链脂族结构裂解为短链脂肪烃的“解聚”过程。  相似文献   

Formation of Concentric Rings Around Sources     

B. P. Harlamov 《Mathematical Geology》2003,35(4):431-449

Zones of increased concentration formed by a solvent flowing from a source are considered. A matehmatical model for forming such zones is proposed. It takes into account that such a zone is composed of a set of independent particles. Hence the distribution of a substance around the source can be explained by movement of an individual particle. In the model this movement is a continuous semi-Markov process with terminal stopping at some random point in space. Parameters of the process depend on the velocity field of the flow. Forward and backward partial differential equations for the distribution density of a random stopping point of the process are derived. The forward equation is investigated for the centrally symmetric case. Solutions of the equation demonstrate either a maximum or a local minimum at the source location. In the latter case a concentric ring around the source is formed. If different substances vary in their absorption rates, they can form separable concentration zones as a family of concentric rings.  相似文献   

Determination of Halogens (F, Cl, Br, I), Sulfur and Water in Seventeen Geological Reference Materials   总被引：5，自引：0，他引：5  

Agnès Michel  Benoît Villemant 《Geostandards and Geoanalytical Research》2003,27(2):163-171

Fluorine, chlorine, bromine, iodine and sulfur were determined in seventeen geological reference materials after extraction by pyrohydrolysis. Fluorine, Cl and S (as sulfate ions) were determined in the extraction solution by ion chromatography with detection limits of around 0.2 mg l⁻¹. Bromine and I were measured by ICP-MS with detection limits of 1 μg l⁻¹ for Br and 0.1 μg l⁻¹ for I. For rock samples, using normal extraction conditions (500 mg of sample and 100 ml of final solution) detection limits were 40 mg kg⁻¹ for F and Cl, 15 mg kg⁻¹ for S, 0.2 mg kg⁻¹ for Br and 0.02 mg kg⁻¹ for I. These detection limits may be improved by increasing the amount of sample and hence the concentration of the final solution. Water was also determined using an extraction technique based on H₂O degassing, reduction on zinc at 1000 °C and H₂ manometry. Our results for fluorine, chlorine, sulfur and water are in good agreement with literature data. Very few reference materials have recommended values for bromine and especially for iodine. Among the analysed samples, three are new reference materials: BHVO-2, BCR-2 and AGV-2.  相似文献   

A Reappraisal of Rb, Y, Zr, Pb and Th Values in Geochemical Reference Material BHVO-1     

William J. Chazey III  Clive R. Neal  Jinesh C. Jain  William S. Kinman 《Geostandards and Geoanalytical Research》2003,27(2):181-192

The geochemical reference material BHVO-1 was analysed by a variety of techniques over a six year period. These techniques included inductively coupled plasma-mass spectrometry and atomic emission spectroscopy (ICP-MS and ICP-AES, respectively), laser ablation ICP-MS and spark source mass spectroscopy. Inconsistencies between the published consensus values reported by Gladney and Roelandts (1988, Geostandards Newsletter) and the results of our study are noted for Rb, Y, Zr, Pb and Th. The values reported here for Rb, Y, Zr and Pb are generally lower, while Th is higher than the consensus value. This is not an analytical artefact unique to the University of Notre Dame ICP-MS facility, as most of the BHVO-1 analyses reported over the last ten to twenty years are in agreement with our results. We propose new consensus values for each of these elements as follows: Rb = 9.3 ± 0.2 μg g-1 (compared to 11 ± 2 μg g-1), Y = 24.4 ± 1.3 μg g-1 (compared to 27.6 ± 1.7 μg g-1), Zr = 172 ± 10 μg g-1 (compared to 179 ± 21 μg g-1), Pb = 2.2 ± 0.2 μg g-1 (compared to 2.6 ± 0.9 μg g-1) and Th = 1.22 ± 0.02 μg g-1 (compared to 1.08 ± 0.15 μg g-1).  相似文献   

MTMD对建筑结构多模态控制的减震分析   总被引：5，自引：1，他引：5  

涂文戈  邹银生 《地震工程与工程振动》2003,23(5):174-179

本文研究了MTMD对建筑结构多模态减震控制。将主结构简化为多自由度模型，MTMD对结构的反力与地震荷载共同作为结构的荷载输入进行分析；基于主结构多模态耦合进行推导分析，阐述了MTMD与结构之间的相互作用关系，提出MTMD的复惯性质量。提出MTMD的控制类型是加速度相关型的无源被动控制。从频域传递函数，白噪声、宽带和窄带地震激励下的结构相对位移和绝对加速度谱密度，以及El-centro地震波作用下结构的地震响应三个方面，分析了MTMD对顶部带有结构附属物的结构的控制效果。并且给出TMD的控制效果加以比较验证。算例说明MTMD多模态控制对结构的相对位移和绝对加速度均有较好的控制效果，并且优于TMD控制效果。  相似文献   

In-situ Formation of Light-Absorbing Organic Matter in Cloud Water   总被引：1，自引：0，他引：1  

A. Gelencsér  A. Hoffer  G. Kiss  E. Tombácz  R. Kurdi  L. Bencze 《Journal of Atmospheric Chemistry》2003,45(1):25-33

Current climate models seem to underestimate the flux of solar energy absorbed by the global troposphere. All of these models are constrained with the assumption that cloud droplets consist of pure water. Here we demonstrate in a simple laboratory experiment that aromatic hydroxy-acids which are found in continental fine aerosol can react with hydroxyl radicals under typical conditions prevalent in cloud water influenced by biomass burning. The reactions yield colored organic species which do absorb solar radiation. We also suggest that the products of such reactions may be humic-like substances whose presence in continental aerosol has been confirmed but their source mechanisms are still much sought after. We also attempt to give a first order estimate of the enhancement of water absorption at a visible wavelength under atmospheric conditions.  相似文献   

激光探针质谱及单颗粒矿物^40Ar／^39Ar法年龄的测定     

蒲志平  许景荣  邱华宁  张永良  胡世玲 《岩矿测试》1997,16(1):1-6

将掺钕的钇铝榴石（Ｎｄ：ＹＡＧ）激光器与高精密ＭＭ１２００质谱计、电子倍增器联网，应用连续激光质谱对单颗粒矿物、光片样品进行微区４０Ａｒ／３９Ａｒ测年、坪年龄和等时线年龄研究。在光片上测定南极乔治王岛北海岸玄武岩等时线年龄（５２．３８±１．０５）Ｍａ和贵州绿豆岩年龄（２３９．１６±１４．１３）Ｍａ，两者与实际地质背景吻合。对两个中生代和太古代单颗粒黑云母进行连续激光质谱阶段升温４０Ａｒ／３９Ａｒ坪年龄谱测定，获得与常规法相一致的坪年龄谱  相似文献   

单道扫描电感耦合等离子体发射光谱法测定大洋标准物质中稀土元素     

查立新  刘洪青 《岩矿测试》1997,16(1):23-27

采用单道扫描等离子体发射光谱法测定了大洋多金属结核及深海沉积物中的稀土元素与钪，比较了不同功率下各稀土元素的检测限，研究了低功率下的稳定性，拟定了可靠的样品处理方法。方法经多金属结核及深海沉积物国家标准ＧＢＷ０７３１３、ＧＢＷ０７２４９分析验证，结果与标准值相符。测定精度（ＲＳＤ）在１３％～５３％。已用此法为第２批多金属结核和深海沉积物标准物质提供了定值数据，其结果无剔除值  相似文献   

悬浮液进样—石墨炉原子吸收测定钒钛磁铁矿中痕量镓   总被引：5，自引：0，他引：5  

张秀荣  单孝全 《岩矿测试》1997,16(1):60-64

研究了悬浮液进样＿石墨炉原子吸收测定钒钛磁铁矿中痕量镓的分析方法。以Ｎｉ（Ⅱ）作为基体改进剂时，可直接用镓标准溶液进行校准。样品粒度＜３８μｍ、悬浮液中试样质量浓度在０１～８０ｇ／Ｌ、含镓质量浓度不超过１００μｇ／Ｌ时呈良好线性关系，检出限为２４μｇ／Ｌ镓。用所拟方法测定了含镓量在１６～４２μｇ／ｇ的标准矿样，结果与标准值相符，６次平行测定的相对标准偏差不超过９％，满足痕量分析的要求。  相似文献