下庄铀成矿古水热系统排泄区（减压区）铀成矿作用研究     

刘金辉  李学礼 《矿床地质》2001,20(3):259-264

形成于古水热系统排泄区（减压区）的下庄花岗岩型铀矿床是地下热水与岩石相互作用的产物。矿物流体包裹体水文地球化学分析表明，成矿期铀成矿古热水溶液气体成分主要为CO2，水化学类型为HCO3－Ca.Na型，F－Ca型和HCO3.F－K型。地球化学模式和热力学计算证明，热水溶液中铀的存在形式为UO2（CO3）2^2-,UO2F3^-和UO2F4^2-。热水溶液深循环过程中CO2的加入可使溶液铀沉淀临界电位值（EhC,U)明显降低，从而保持水－铀比电位值（ΔEhW,U)为正值（ΔEhW,U=EhW-EhC,U)使铀在深部相对还原的条件下仍能稳定迁移。当富铀成矿热液进入减压排泄区时，由于溶液物理－化学条件的改变，发生CO2脱气作用和中和还原作用，导致ΔEhW,U小于零，使铀沉淀、富集，最终形成花岗岩型铀矿床。  相似文献   

红辉沸石合成P型沸石试验研究   总被引：8，自引：0，他引：8  

申少华  张术根  王大伟 《矿物学报》2001,21(3):493-496

以广西资源红辉沸石为原料进行合成P型沸石的最佳工艺流程及相关技术参数研究，提出了工艺流程为红辉沸石（酸处理）→水热反应→晶化→洗涤、过滤→烘干→P型沸石产品，最佳工艺技术参数为硅铝摩尔比[n(SiO2)/n(Al2O3)]3-4，碱度4－5mol/L NaOH，晶化温度95－100℃，晶化时间6－8h。  相似文献   

Magmatic gas scrubbing: implications for volcano monitoring   总被引：1，自引：0，他引：1  

R. B. Symonds  T. M. Gerlach  M. H. Reed 《Journal of Volcanology and Geothermal Research》2001,108(1-4)

Despite the abundance of SO_2(g) in magmatic gases, precursory increases in magmatic SO_2(g) are not always observed prior to volcanic eruption, probably because many terrestrial volcanoes contain abundant groundwater or surface water that scrubs magmatic gases until a dry pathway to the atmosphere is established. To better understand scrubbing and its implications for volcano monitoring, we model thermochemically the reaction of magmatic gases with water. First, we inject a 915°C magmatic gas from Merapi volcano into 25°C air-saturated water (ASW) over a wide range of gas/water mass ratios from 0.0002 to 100 and at a total pressure of 0.1 MPa. Then we model closed-system cooling of the magmatic gas, magmatic gas-ASW mixing at 5.0 MPa, runs with varied temperature and composition of the ASW, a case with a wide range of magmatic–gas compositions, and a reaction of a magmatic gas–ASW mixture with rock. The modeling predicts gas and water compositions, and, in one case, alteration assemblages for a wide range of scrubbing conditions; these results can be compared directly with samples from degassing volcanoes. The modeling suggests that CO_2(g) is the main species to monitor when scrubbing exists; another candidate is H₂S_(g), but it can be affected by reactions with aqueous ferrous iron. In contrast, scrubbing by water will prevent significant SO_2(g) and most HCl_(g) emissions until dry pathways are established, except for moderate HCl_(g) degassing from pH<0.5 hydrothermal waters. Furthermore, it appears that scrubbing will prevent much, if any, SO_2(g) degassing from long-resident boiling hydrothermal systems. Several processes can also decrease or increase H_2(g) emissions during scrubbing making H_2(g) a poor choice to detect changes in magma degassing.We applied the model results to interpret field observations and emission rate data from four eruptions: (1) Crater Peak on Mount Spurr (1992) where, except for a short post-eruptive period, scrubbing appears to have drastically diminished pre-, inter-, and post-eruptive SO_2(g) emissions, but had much less impact on CO_2(g) emissions. (2) Mount St. Helens where scrubbing of SO_2(g) was important prior to and three weeks after the 18 May 1980 eruption. Scrubbing was also active during a period of unrest in the summer of 1998. (3) Mount Pinatubo where early drying out prevented SO_2(g) scrubbing before the climactic 15 June 1991 eruption. (4) The ongoing eruption at Popocatépetl in an arid region of Mexico where there is little evidence of scrubbing.In most eruptive cycles, the impact of scrubbing will be greater during pre- and post-eruptive periods than during the main eruptive and intense passive degassing stages. Therefore, we recommend monitoring the following gases: CO_2(g) and H₂S_(g) in precursory stages; CO_2(g), H₂S_(g), SO_2(g), HCl_(g), and HF_(g) in eruptive and intense passive degassing stages; and CO_2(g) and H₂S_(g) again in the declining stages. CO_2(g) is clearly the main candidate for early emission rate monitoring, although significant early increases in the intensity and geographic distribution of H₂S_(g) emissions should be taken as an important sign of volcanic unrest and a potential precursor. Owing to the difficulty of extracting SO_2(g) from hydrothermal waters, the emergence of >100 t/d (tons per day) of SO_2(g) in addition to CO_2(g) and H₂S_(g) should be taken as a criterion of magma intrusion. Finally, the modeling suggests that the interpretation of gas-ratio data requires a case-by-case evaluation since ratio changes can often be produced by several mechanisms; nevertheless, several gas ratios may provide useful indices for monitoring the drying out of gas pathways.  相似文献   

Zinc-rich Pyrite from the TAG Active Mound, the TAG Hydrotherma Field, Mid-Atlantic Ridge     

Su Young Lee    Masatsugu Ohnishi    Yasuhiro Shibata    Makoto Wwatanabe    Kenichi Hoshino    Mayumi Jige    Xiangping Gu  Hitoshi Chiba  Tamotsu Oomori    Kantaro Fujioka  Peter A. Rona 《Resource Geology》2001,51(1):63-68

Abstract: Pyrite rich in Zn, up to 3.1 wt%, was found in the TAG active mound of the TAG hydrothermal field, the slow-spreading Mid-Atlantic Ridge at 26°08'N and 44°49'W. The Zn-rich pyrite is characterized by an optical homogeneity, a homogeneous distribution of Zn in the back-scattered electron images, both at a magnification of about 500, a negative correlation between Fe and Zn contents of the pyrite and a rather small unit cell edge (a₀ = 5.4117 ± 0.0008Å), strongly indicating that the detected Zn is present in the pyrite in solid solution. Such Zn concentrations are observed exclusively in dendritic pyrite, suggesting that the Znrich pyrite grew from hydrothermal fluids of a high degree of supersaturation due to quenching on the seafloor.  相似文献   

Tectonic Dynamic Metallization of Silver-GoldHydrothermal Fluids in Proterozoic GneissTerrene Shear Zones, Suichang, Zhejiang, China     

Wang Siyuan Xiao Qibing Zeng Jianguo Faculty of Earth Resources  China University of Geosciences  Wuhan 《中国地质大学学报(英文版)》2001,12(1)

-,The well-known Suichang silvengold field is located inZhejiang Province of SOutheast China. It is the largest silver-gold deposit associated with copper and zinc in the Cathaysianmetallogenic province.There are a series of silver-gold dePOsits in the shear zonesof Proterozoic gneiss terrene, Suichang region. The volcanicapparatus at Mesozoic has complicated rpineralization. Respectively, there are two pieces of understanding on the origin ofore-formigg nuid: (l ) metamorphic fluid (Lia…  相似文献   

东安牛头寨地区锑矿床控制因素及成因探讨   总被引：1，自引：0，他引：1  

郭爱民  罗小亚等 《湖南地质》2001,20(4):267-271

锑矿床严格受构造控制，表现出逐级控矿特征：区域性F1断裂、牛头寨复式背斜及北北东、北北西、北西向次级断裂，分别控制着锑矿带、锑矿床的空间展布及锑矿脉的形态、产状与规模。地层岩石建造对成矿的控制，主要表现在赋矿地层中的白云岩、硅质岩等易碎裂，为矿液的运移提供了有利的通道。部分含矿地层的Sb高丰度，还可能成为矿提供了矿源。已有的研究表明，锑矿床的硫同位素组成具有岩浆硫特征，并混入了部分围岩沉积硫。石英的氢氧同位素组成反映出岩浆流体与变质水混入溶液特征。矿物包裹体的爆裂温度平均为157℃。石英的包裹体成分测试结果，揭示了矿液为K－Na-Ca-Cl型富硅的弱碱性溶液。矿床成因厘定为岩浆期后中低温热液脉状充填矿床。  相似文献   

Application of short-wave infrared spectroscopy to define alteration zones associated with the Elura zinc–lead–silver deposit, NSW, Australia     

Yanyan Sun  Philip K. Seccombe  Kai Yang   《Journal of Geochemical Exploration》2001,73(1):63

Short-wave infrared reflectance spectra obtained from a Portable Infrared Mineral Analyser (PIMA) have been used to define alteration zones adjacent to base metal sulfide ore bodies at the Elura Mine, Cobar, Australia. The spectroscopic work identified white mica (sericite), chlorite and carbonates of hydrothermal origin in the alteration zones associated with the ore bodies. Weathering, alteration and ore zones can be discriminated by variations in the intensity and wavelength of relevant absorption features. Hydrothermal alteration is classified into four principal types, namely sericitic, silicic, chloritic and carbonate alteration. The first three types comprise overprinting hydrothermal assemblages of quartz, sericite, chlorite, ankerite, siderite, calcite and sulfides developed in strongly altered metasiltstone and slate of Early Devonian age, adjacent to the zinc–lead–silver mineralisation. An extensive zone of carbonate alteration, manifested as porphyroblasts of siderite in the host metasediments, is recognised beyond the zones of strong alteration. Spectral analysis is consistent with the mineralogical data obtained from XRD and XRF analyses and defines the limits of the alteration zones to distances of about 80 m around the ore bodies. The study demonstrates the potential for spectral analysis to assist with drill hole logging and the identification of alteration zones as part of mineral exploration and development programs.  相似文献   

湖南中生代岩浆活动与晚二叠世煤变质特征   总被引：2，自引：0，他引：2  

周春光  龚玉红 《现代地质》1996,10(4):470-477

岩体同位素年龄和空间展布分析表明，中生代岩浆活动受多期活动的深大断裂控制且具有多阶段和多期次演化特征。根据Ｘ 射线衍射分析、包体测温、热液矿点的分布以及煤质参数等特征可以证明，除了深成变质作用外，岩浆热变质作用是该区主要的煤变质作用类型。岩浆热变质作用可进一步划分为区域岩浆热变质作用和接触变质作用。通过对湖南的煤类、岩浆活动、构造特征及地球物理特征的比较，可划分出４个煤变质区，其变质程度自北西向南东逐渐增高，这是中、新生代太平洋板块与欧亚板块长期相互作用的结果  相似文献   

人造气液包裹体方法及其在研究热液性质中的应用   总被引：3，自引：0，他引：3       下载免费PDF全文

张毅刚 《地质科学》1992,(2):141-148

人造气液包裹体方法在研究热液的物理化学性质方面较传统方法简便、易行。它可用于研究热液的等容线、不混溶性质及矿物在热液中的溶解度。本文解释了人造气液包裹体的合成方法和人造气液包裹体方法的原理,分述了应用此方法研究热液所取得的最新成果。此法不仅能用于研究热液的性质,也能用于其它方面的研究,具有广阔的前景。  相似文献   

滇黔桂三角区微细浸染型金矿床成矿热液一种可能的演化途径:年代学证据   总被引：24，自引：1，他引：24  

胡瑞忠  苏文超  毕献武  李泽琴 《矿物学报》1995,(2)

本文主要根据年代学资料和金活化迁移的地球化学属性，探讨了滇黔桂三角区微细浸染型金矿床成矿热液的演化途径。多种定年方法揭示，该区金成矿初始流体（古流体）的年龄为260Ma左右；金成矿年龄约为140～75Ma。考虑到该区燕山晚期岩浆岩富含Cl，本文认为古流体（260～140Ma）向成矿流体（140～75Ma）的转化，可能主要是通过燕山晚期岩浆活动产生的富氯流体加入原已存在的贫氯古流体，从而使这种新的混合流体具有浸取金的能力来实现的。  相似文献