Prograde metamorphic sequence of REE minerals in pelitic rocks of the Central Alps: implications for allanite–monazite–xenotime phase relations from 250 to 610 °C     

E. JANOTS  M. ENGI  A. BERGER  J. ALLAZ  J.-O. SCHWARZ  C. SPANDLER 《Journal of Metamorphic Geology》2008,26(5):509-526

The distribution of REE minerals in metasedimentary rocks was investigated to gain insight into the stability of allanite, monazite and xenotime in metapelites. Samples were collected in the central Swiss Alps, along a well‐established metamorphic field gradient that record conditions from very low grade metamorphism (250 °C) to the lower amphibolite facies (～600 °C). In the Alpine metapelites investigated, mass balance calculations show that LREE are mainly transferred between monazite and allanite during the course of prograde metamorphism. At very low grade metamorphism, detrital monazite grains (mostly Variscan in age) have two distinct populations in terms of LREE and MREE compositions. Newly formed monazite crystallized during low‐grade metamorphism (<440 °C); these are enriched in La, but depleted in Th and Y, compared with inherited grains. Upon the appearance of chloritoid (～440–450 °C, thermometry based on chlorite–choritoid and carbonaceous material), monazite is consumed, and MREE and LREE are taken up preferentially in two distinct zones of allanite distinguishable by EMPA and X‐ray mapping. Prior to garnet growth, allanite acquires two growth zones of clinozoisite: a first one rich in HREE + Y and a second one containing low REE contents. Following garnet growth, close to the chloritoid–out zone boundary (～556–580 °C, based on phase equilibrium calculations), allanite and its rims are partially to totally replaced by monazite and xenotime, both associated with plagioclase (± biotite ± staurolite ± kyanite ± quartz). In these samples, epidote relics are located in the matrix or as inclusions in garnet, and these preserve their characteristic chemical and textural growth zoning, indicating that they did not experience re‐equilibration following their prograde formation. Hence, the partial breakdown of allanite to monazite offers the attractive possibility to obtain in situ ages, representing two distinct crystallization stages. In addition, the complex REE + Y and Th zoning pattern of allanite and monazite are essential monitors of crystallization conditions at relatively low metamorphic grade.  相似文献   

A Counterexample to a Generalized Saari's Conjecture with a Continuum of Central Configurations   总被引：1，自引：1，他引：0  

Manuele Santoprete 《Celestial Mechanics and Dynamical Astronomy》2004,89(4):357-364

In this paper we show that in the n-body problem with harmonic potential one can find a continuum of central configurations for n= 3. Moreover we show a counterexample to an interpretation of Jerry Marsden Generalized Saari's conjecture. This will help to refine our understanding and formulation of the Generalized Saari's conjecture, and in turn it might provide insight in how to solve the classical Saari's conjecture for n≥ 4. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Structural and metamorphic controls on the distribution of zircon in an evolving quartzofeldspathic migmatite: an example from the Reynolds Range, central Australia     

P. DIRKS  M. HAND 《Journal of Metamorphic Geology》1991,9(2):191-201

Three types of zircon occur in a complexly deformed and variably migmatized quartzofeldspathic gneiss from the Reynolds Range, central Australia. The oldest type is inherited from the granitic precursor of the gneiss, and is overgrown by a second group of zircon grains that formed during prograde, granulite facies metamorphism. Partial melting of the gneiss resulted in solution of both the inherited and metamorphic zircon. No new zircon growth accompanied crystallization of the partial melt, suggesting loss of zirconium–rich residual fluids. Hydrous, amphibolite facies retrogression of the gneiss and its migmatized variants during late shearing produced new, idiomorphic zircon in both the shear zone and its wall rocks.
Important implications of this study are that (i) zircon has a tendency to dissolve if it comes into direct contact with a melt produced from anhydrous biotite breakdown in a quartzofeldspathic granulite, (ii) melt crystallization is not necessarily accompanied by zircon growth, and (iii) euhedral zircon can grow from a hydrous fluid phase under subsolidus, amphibolite facies conditions, e.g. within shear zones.  相似文献   

Properties of the aftershocks sequences of the 2000 and 2002 earthquakes in Aksehir-Afyon graben,west-central Anatolia,Turkey     

Naside Ozer  Yildiz Altinok  Savas Ceylan 《Natural Hazards》2007,40(3):553-562

The b-value of the Gutenberg–Richter’s frequency–magnitude relation and the p-value of the modified Omori law, which describes the decay rate of aftershock activity, were investigated for more than 500 aftershocks in the Aksehir-Afyon graben (AAG) following the 15 December 2000 Sultandagi–Aksehir and the 3 February 2002 Çay–Eber and Çobanlar earthquakes. We used the Kandilli Observatory’s catalog, which contains records of aftershocks with magnitudes ≥2.5. For the Çobanlar earthquake, the estimated b-values for three aftershock sequences are in the range 0.34 ≤  b ≤ 2.85, with the exception of the one that occurred during the first hour (4.77), while the obtained p-values are in the range 0.44 ≤ p ≤ 1.77. The aftershocks of the Sultandagi earthquake have a high p-value, indicating fast decay of the aftershock activity. A regular increase of b can be observed, with b < 1.0 after 0.208 days for the Çay–Eber earthquake. A systematic and similar increase and decrease pattern exists for the b- and p-values of the Çobanlar earthquakes during the first 5 days.  相似文献   

A North-South Transect across the Central Mexican Volcanic Belt at ~100{degrees}W: Spatial Distribution, Petrological, Geochemical, and Isotopic Characteristics of Quaternary Volcanism     

Blatter  Dawnika L.; Lang Farmer  G.; Carmichael  Ian S. E. 《Journal of Petrology》2007,48(5):901-950

Within the Zitácuaro–Valle de Bravo (ZVB) regionof the central Mexican Volcanic Belt (MVB), three lava serieshave erupted during the Quaternary: (1) high-K₂O basaltic andesitesand andesites; (2) medium-K₂O basaltic andesites, andesitesand dacites; (3) high-TiO₂ basalts and basaltic andesites. Thedominant feature of the first two groups is the lack of plagioclaseaccompanying the various ferromagnesian phenocrysts (olivine,orthopyroxene, augite, and hornblende) in all but the dacites.This absence of plagioclase in the phenocryst assemblages ofthe high-K₂O and medium-K₂O intermediate lavas is significantbecause it indicates high water contents during the stage ofphenocryst equilibration. In contrast, the high-TiO₂ group ischaracterized by phenocrysts of plagioclase and olivine. Thespatial distribution of these three lava series is systematic.The southern section of the ZVB transect, 280–330 km fromthe Middle America Trench (MAT), is characterized by high-K₂Omelts that are relatively enriched in fluid-mobile elementsand have the highest ⁸⁷Sr/⁸⁶Sr ratios. Medium-K₂O basaltic andesiteand andesite lavas are present throughout the transect, butthose closest to the MAT are MgO-rich (3·5–9·4wt %) and have phenocryst assemblages indicative of high magmaticwater contents (3·5–6·5 wt % water) andrelatively low temperatures (950–1000°C). In markedcontrast, the northern section of the ZVB transect (380–480km from the MAT) has high-TiO₂, high field strength element(HFSE)-enriched magmas that have comparatively dry (< 1·5wt % magmatic water) and hot (1100–1200°C) phenocrystequilibration conditions. The central section of the ZVB transect(330–380 km from the MAT) is a transition zone and producesmoderately light rare earth element (LREE) and large ion lithophileelement (LILE)-enriched, medium-K₂O lavas with phenocryst assemblagesindicative of intermediate (1·5–3·5 wt %)water contents and temperatures. The high-K₂O series compositionsare the most enriched in LILE and LREE, with a narrow rangeof radiogenic ⁸⁷Sr/⁸⁶Sr from 0·704245 to 0·704507,¹⁴³Nd/¹⁴⁴Nd values ranging from 0·512857 to 0·512927(_Nd = 4·27–5·63), and ²⁰⁸Pb/²⁰⁴Pb valuesfrom 38·248 to 38·442, ²⁰⁷Pb/²⁰⁴Pb values from15·563 to 15·585, and ²⁰⁶Pb/²⁰⁴Pb values from18·598 to 18·688. The medium-K₂O series compositionsare only moderately enriched in the LILE and LREE, with a broaderrange of ⁸⁷Sr/⁸⁶Sr, but similar ¹⁴³Nd/¹⁴⁴Nd and ²⁰⁸Pb/²⁰⁴Pbvalues to those of the high-K₂O series. In contrast, the high-TiO₂series compositions have little enrichment in LILE or LREE andinstead are enriched in the HFSE and heavy rare earth elements(HREE). The high-TiO₂ lavas are isotopically distinct in theirlower and narrower range of ¹⁴³Nd/¹⁴⁴Nd. The isotopic variationsare believed to reflect the upper mantle magma source regionsas the low content of phenocrysts in most lavas precludes significantupper crustal assimilation or magma mixing, other than thatrepresented by the presence of quartz xenocrysts (< 2 vol.%) with rhyolitic glass inclusions, which are found in manyof these lavas. The systematic spatial variation in compositionof the three lava series is a reflection of the underlying subduction-modifiedmantle and its evolution. KEY WORDS: central Mexico; geochemistry; isotopes; Quaternary volcanism; hydrous lavas  相似文献   

远安地堑上白垩统红花套组压实剪切型变形带的微观结构与地层渗透性关系解析          下载免费PDF全文

渠芳  连承波  柴震瀚  任冠雄 《地质论评》2023,69(1):123-132

孔隙性砂岩中形成的压实剪切型变形带及其周围的渗透性特征是变形带研究的重要内容之一,由于变形带宽度常为毫米级别,常规渗透率测试方法因分辨率的限制无法满足研究需求。选取远安地堑上白垩统红花套组中不同规模的单条变形带、小型及中大型簇状变形带样品,在对其微观结构进行详细研究的基础上,采用具有高分辨率测试功能的AUTOSCAN进行密集测试,建立了连续渗透率剖面。结果显示,渗透率低值点与变形带有显著对应关系,在渗透率线扫描曲线中呈下拉尖峰特征;不同变形带渗透率异常低值点存在差异,变形带厚度大则异常程度高;不同微观结构要素的渗透率降低程度不同,渗透率由低至高依次为：大型簇状变形带的核心碎裂带<小型簇状变形带的核心碎裂带<带间区域<单条变形带核心碎裂带<边缘过渡区<围岩。分析认为,虽然变形带的厚度和渗透率探测孔的大小会影响探测结果,但变形带的微观结构才是控制渗透率降低程度不同的本质原因。中大型簇状变形带的核心碎裂带密集发育且连续性好,很可能对流体渗流、油气运移等造成较大影响;而单条变形带由于延续性较差,很难真正阻碍流体渗流,而是会增强岩石整体的各向异性特征。  相似文献   

黔中—渝南石炭纪铝土矿含矿岩系中的海相沉积特征   总被引：2，自引：2，他引：0       下载免费PDF全文

刘 平廖友常  张雅静 《中国地质》2015,(2):641-654

黔中—渝南地区于紫云运动初期的泥盆纪末已准平原化,在石炭纪铝土矿含矿岩系沉积过程中,含矿岩系下段(铁质-粘土岩段)主要为近海湖泊相,含矿岩系上段(铝质岩段)为近海平原相。在这种大环境前提下,经常会受到海泛与强风暴潮的影响与改造,使得主要是陆相环境沉积形成的铝土矿含矿岩系中,含有少量海相大化石(腕足类)和微体生物化石(疑源类和牙形石);另在下段和上段岩矿层间,时夹海相碳酸盐岩透镜体,具明显海相沉积特征。以上表明,黔中—渝南石炭系铝土矿含矿岩系形成环境具有显著的多样性和复杂性,而非单纯的陆相沉积环境所能概括的。  相似文献   

河北中南部平原土壤重金属元素存在形态及生物有效性分析   总被引：9，自引：3，他引：6       下载免费PDF全文

崔邢涛  王学求  栾文楼 《中国地质》2015,(2):655-663

本文以河北省中南部平原农田表层土壤为研究对象,对表层土壤中7种重金属元素的形态含量进行了统计和分析,对重金属元素的生物有效性进行了评价,并运用相关分析法,对影响重金属元素生物有效性的因素进行了研究。结果表明,研究区表层土壤7种重金属元素的有效态含量以Cd最高,达36.83%,潜在生态危害性较大;其次为Pb,达13.37%,其中碳酸盐结合态达到12.38%,由于土壤呈中性或偏碱性,Pb元素的迁移能力较弱,其潜在危害性较小;Cu、Hg、Cr、As、Zn重金属元素含量均以稳定态的含量存在,之和均在90%以上,表明其潜在危害性较小;研究区土壤重金属元素的活性系数和迁移系数大小顺序为:CdPbHgCuZnAsCr和CdHgAsCuPbZnCr,其中Cd的活性系数和迁移系数平均值分别达到0.330和0.160,展现出较强的生物活性、不稳定性和迁移能力,其他重金属元素在土壤中活性系数(Pb除外)和迁移系数均较小,生物活性较弱,在土壤中稳定存在,由土壤中向植物中的迁移能力弱;研究区不同的重金属的生物有效性与其影响因素的关系不尽相同,其主要因素是土壤重金属元素全量,其次为p H、TOC、CEC、粘粒含量等,二者关系复杂。  相似文献   

中南部非洲的地质构造演化与矿产分布规律          下载免费PDF全文

刘晓阳  王杰  余金杰  王丽瑛  修群业  贺福清  任军平 《地质找矿论丛》2015,30(S1):1-12

中南部非洲优势矿产资源有金、铜、铁、铬、金刚石,锰、铀、镍、钒、钴、铂、锑的储量也居世界前列。主要的矿产集中分布于前寒武纪地体内,中南部非洲前寒武纪地体的形成演化决定了矿产的种类和主要成矿类型。文章总结了中南部非洲的地质构造演化以及其主要矿产资源的成矿类型和分布规律,并划分成矿区带至三级。探讨了部分主要成矿区带的成矿规律:太古宙的矿产主要与花岗-绿岩地体有关;古元古代的矿产主要分布于陆缘盆地,与岩浆作用有关;中元古代的矿产主要与岩浆作用有关,次为沉积变质作用;新元古代的矿产主要与沉积变质作用有关,次为岩浆作用。  相似文献   

浙中后山店花岗斑岩体的LA-ICP-MS锆石U-Pb定年、锆石Hf同位素及其地质意义     

王对兴  李春麟  高万里  王宗秀  朱骥 《矿物岩石》2015,35(1)

针对浙中地区后山店花岗斑岩体进行高精度LA-ICP-MS锆石U-Pb测年和锆石Lu-Hf同位素的测定。测年结果显示其加权平均年龄值为148.5 Ma±1.2 Ma(MSWD=1.4),说明浙中地区有晚侏罗世侵入岩的存在,属于燕山早期晚阶段岩浆活动的产物,其成岩时代可能代表了古太平洋构造域下的板内岩浆活动和陆缘弧间的过渡阶段。锆石的εHf(t)值为-10.3~-3.5,均为负值,二阶段模式年龄tHf2(Ma)变化范围主要集中于1 400 Ma~1 829 Ma之间,反映其物质来源可能为中元古代下地壳基底物质,并在成岩过程中有幔源组分的参与。  相似文献