也谈地壳内第二深度空间石油、天然气的形成及勘探前景     

倪祥龙  张景廉  马新民 《地球物理学进展》2012,27(2):562-574

在当前国内油气供需紧张的严峻形势下,开展"第二深度空间"的油气勘探"势在必行",也是"当务之急"."第二深度空间"的油气勘探需解决3个问题.一是油气无机成因的地球化学证据.原油、沥青、干酪根的Pb,Sr,Nd同位素示踪、原油中异常高含量的金属微量元素、原油中有机硅化合物的发现等均表明原油可以由无机反应而生成.二是油气无机成因论是可以指导油气勘探的.油气的分布与中地壳的低速、高导层的耦合表明有成因关系,中地壳的低速、高导层是油气的发生器,也是初始储层,据此可以对油气田进行预测.柴达木盆地昆北花岗岩油田的发现是一典型案例.三是"第二深度空间"的油气勘探需要地球物理方法和技术的支撑.目前第4代采集处理新理论、新方法业已提出.地球物理学家已经把深部勘探的新方法、新技术提到议事日程.总之,"第二深度空间"的油气勘探是有理论依据的,是可能的,是可操作的.发现大型、超大型油气田指日可待.  相似文献   

秦岭太白山南麓降水中常量无机离子特征及其来源研究   总被引：1，自引：0，他引：1  

卢爱刚  刘晖  康世昌  王少安 《冰川冻土》2017,39(4):771-780

以2011年11月至2014年9月连续采集的74个有效降水样品为研究载体,运用趋势分析法和相关分析法分析太白山南麓黄柏塬地区降水中常量无机离子（NH₄⁺、Ca²⁺、Na⁺、K⁺、Mg²⁺、SO₄^2-、NO₃^-、Cl^-、F^-）的化学特征,并结合富集因子法、端源贡献法及后向气流轨迹模型探究其来源。结果表明：研究区降水中各离子浓度大小顺序为Ca²⁺ > SO₄^2- > NH₄⁺ > NO₃^- > K⁺ > Na⁺ > Mg²⁺ > Cl^- > F^-,主要阳离子是Ca²⁺和NH₄⁺,共占阳离子总量的76.21%,主要阴离子是SO₄^2-和NO₃^-,共占阴离子总量的90.83%。降水总离子年平均浓度为404.64 μeq·L^-1,相对于国内外已研究的其他高山站点偏高,表现出典型的大陆型及人为源干扰的特征。受排放源、气象因子、植被、降水量等因素影响,降水总离子浓度表现出显著的季节差异,依次为冬季 > 春季 > 秋季 > 夏季。源解析结果显示降水中SO₄^2-和NO₃^-95%以上由人为源贡献,Ca²⁺和Mg²⁺主要来源于地壳风化,Na⁺海盐源和非海盐源贡献约各占一半,K⁺主要来自于非海盐贡献,而F^-和NH₄⁺则几乎全部由人为源贡献。不同路径气团影响下的降水离子组分具有明显不同,北方气团途径太原、石家庄、北京、兰州等工业发达城市,工业燃煤交通废气排放量大,降水中SO₄^2-、NO₃^-浓度均偏高,离子总浓度也明显高于南方气团。  相似文献   

Nitrogen and phosphorus intake by phytoplankton in the Xiamen Bay     

林彩  林辉  贺青  许焜灿  吴省三  张元标  陈金民  陈宝红  林力斌  卢美鸾  陈维芬  汤荣坤  暨卫东 《中国海洋湖沼学报》2010,28(1):99-105

This paper describes a time series experiment examining the nitrogen and phosphorus intake of natural phytoplankton communities by a microcosms approach.Seawater samples containing natural phytoplankton communities were collected from waters around Baozhu Islet in inner Xiamen Bay and around Qingyu Islet in the outer bay.The goal was to elucidate the relationship between phytoplankton population enhancement,the biological removal of nitrogen and phosphorus from the seawater,and the phytoplankton nitrogen an...  相似文献   

叠合盆地油气成藏体系研究思路与方法——以准噶尔盆地中部地区油气藏为例     

金之钧 《高校地质学报》2011,17(2):161-169

以准噶尔盆地中部地区油气藏为例,阐述了叠合盆地油气成藏体系研究的基本思路和方法,归纳为“一个中心,两 条途径”。一个中心是指以油气藏为中心进行剖析研究,两条途径是指采用有机和无机地球化学相结合的研究方法。在准噶 尔盆地中部地区的实例研究结果表明,根据原油的有机（生物标志物）地球化学分析,研究区至少存在2大油气成藏体系, 即盆1井西凹陷东环带地区二叠系成藏体系、莫索湾中东部地区二叠系和侏罗系成藏体系。再通过无机地球化学（储层成 岩方解石）分析,发现研究区还存在另外2个成藏体系,即东道海子凹陷周边地区二叠系和侏罗系成藏体系、石东地区二 叠系成藏体系。在此基础上,进一步评价了各成藏体系中的油气潜力,以为区域油气勘探提供参考。因此,油气成藏体系 的研究有助于加强对勘探的指导;有机和无机地球化学相结合的研究方法相互补充,是对过去通常主要根据有机地球化学 方法进行分析的拓展与补充完善,形成了新认识,值得在今后的油气成藏体系研究中加强深入探索。  相似文献   

Ecological significance of alkaline phosphatase activity and phosphatase-hydrolyzed phosphorus in the northern part of Gamak Bay, Korea   总被引：1，自引：0，他引：1  

Kwon HK  Oh SJ  Yang HS 《Marine pollution bulletin》2011,62(11):2476-2482

We investigated the ecological significance of alkaline phsophatase (APase) and alkaline phosphatase-hydrolyzable phosphorus (APHP) in the northern part of Gamak Bay, Korea. APase activity was detectable throughout the year, and dissolved inorganic phosphorus (DIP) concentration and APase activity are highly correlated and can be regarded as an indicator of DIP-limiting conditions. Also, a strong linear positive correlation between APase activity and Chl a concentration indicated that the major part of APase activity may have been induced by phytoplanktons. The APHP proportion in dissolved organic phosphorus (DOP) was above ca. 30% from winter to spring and below ca. 15% from summer to autumn due to freshwater discharge and uptake by phytoplankton. APHP may play an important role in species competition in coastal area such as northern part of Gamak Bay where DIP is limiting. Thus, APase induction by phytoplanktons may be ecologically significant, allowing dominance by these organisms under DIP-limiting conditions.  相似文献   

Mixing of magmatic CO₂ into volcano groundwater flow at Aso volcano assessed combining carbon and water stable isotopes     

Makoto Yamada  Shinji Ohsawa  Kohei Kazahaya  Masaya Yasuhara  Hiroshi Takahashi  Kazuhiro Amita  Hideo Mawatari  Shin Yoshikawa 《Journal of Geochemical Exploration》2011

To understand deep groundwater flow systems and their interaction with CO₂ emanated from magma at depth in a volcanic edifice, deep groundwater samples were collected from hot spring wells in the Aso volcanic area for hydrogen, oxygen and carbon isotope analyses and measurements of the stable carbon isotope ratios and concentrations of dissolved inorganic carbon (DIC). Relations between the stable carbon isotope ratio (δ¹³C_DIC) and DIC concentrations of the sampled waters show that magma-derived CO₂ mixed into the deep groundwater. Furthermore, groundwaters of deeper areas, except samples from fumarolic areas, show higher δ¹³C_DIC values. The waters' stable hydrogen and oxygen isotope ratios (δD and δ¹⁸O) reflect the meteoric-water origin of that region's deep groundwater. A negative correlation was found between the altitude of the well bottom and the altitude of groundwater recharge as calculated using the equation of the recharge-water line and δD value. This applies especially in the Aso-dani area, where deeper groundwater correlates with higher recharge. Groundwater recharged at high altitude has higher δ¹³C_DIC of than groundwater recharged at low altitude, strongly suggesting that magmatic CO₂ is present to a much greater degree in deeper groundwater. These results indicate that magmatic CO₂ mixes into deeper groundwater flowing nearer the magma conduit or chamber.  相似文献   

Variation of bacteria biomass and its possible controlling factors in the East China Sea     

Wenjuan Xia  Jiangtao Wang  Liju Tan  Qiulu Wang 《中国海洋大学学报(英文版)》2011,10(2):135-141

Two surveys were performed for determining bacteria biomass (BB), temperature, salinity, chlorophyll a (chl-a) and nutrient concentrations at 11 stations with three sampling depths in the high-incidence regions of red tide in the East China Sea (ECS) in the spring of 2006. Temperature and salinity increased from nearshore to offshore region and from high latitude to low latitude in the two cruises of 2006. BB were between 0.3–5.2 mgC m⁻³ (about 2.1 mgC m⁻³ on average) and 0.2–6.0 mgC m⁻³ (about 2.7 mgC m⁻³ on average) respectively in the two cruises. BB in the surface layer decreased from the Changjiang River estuary to high sea and from low latitude to high latitude. The results showed that bacterial growth was regulated by temperature, primary production and inorganic nutrient concentrations depending on different hydrographic conditions. In the surface and middle layers where the primary production can supply enough organic substrate, temperature was the main factor to control bacteria biomass. BB showed a good correlation between the surface and middle layers in both cruises. The distribution of nutrients during both cruises showed a similar decreasing trend from nearshore region and high latitude to offshore region and low latitude. High BB values were mainly recorded from samples in the middle layer where chl-a concentrations were also high, indicating primary production being strongly correlated with temperature over the ECS shelf. In the offshore area, phosphate and silicate became limiting factors for phytoplankton growth with indirect influence on BB. Bacteria played an important role in nitrogen regeneration process turning organic nitrogen to inorganic forms such as NH₄ ⁺. The increasing ratio of NH₄ ⁺/DIN could be a proof of that.  相似文献   

Deep-water carbonate concentrations in the southwest Pacific     

Helen C. Bostock  Bruce W. HaywardHelen L. Neil  Kim I. CurrieGavin B. Dunbar 《Deep Sea Research Part I: Oceanographic Research Papers》2011,58(1):72-85

We have compiled carbonate chemistry and sedimentary CaCO₃% data for the deep-waters (>1500 m water depth) of the southwest (SW) Pacific region. The complex topography in the SW Pacific influences the deep-water circulation and affects the carbonate ion concentration ([CO₃2−]), and the associated calcite saturation horizon (CSH, where ??_calcite=1). The Tasman Basin and the southeast (SE) New Zealand region have the deepest CSH at ∼3100 m, primarily influenced by middle and lower Circumpolar Deep Waters (m or lCPDW), while to the northeast of New Zealand the CSH is ∼2800 m, due to the corrosive influence of the old North Pacific deep waters (NPDW) on the upper CPDW (uCPDW). The carbonate compensation depth (CCD; defined by a sedimentary CaCO₃ content of <20%), also varies between the basins in the SW Pacific. The CCD is ∼4600 m to the SE New Zealand, but only ∼4000 m to the NE New Zealand. The CaCO₃ content of the sediment, however, can be influenced by a number of different factors other than dissolution; therefore, we suggest using the water chemistry to estimate the CCD. The depth difference between the CSH and CCD (??Z_CSH−CCD), however, varies considerably in this region and globally. The global ??Z_CSH−CCD appears to expand with increase in age of the deep-water, resulting from a shoaling of the CSH. In contrast the depth of the chemical lysocline (??_calcite=0.8) is less variable globally and is relatively similar, or close, to the CCD determined from the sedimentary CaCO₃%. Geochemical definitions of the CCD, however, cannot be used to determine changes in the paleo-CCD. For the given range of factors that influence the sedimentary CaCO₃%, an independent dissolution proxy, such as the foraminifera fragmentation % (>40%=foraminiferal lysocline) is required to define a depth where significant CaCO₃ dissolution has occurred back through time. The current foraminiferal lysocline for the SW Pacific region ranges from 3100-3500 m, which is predictably just slightly deeper than the CSH. This compilation of sediment and water chemistry data provides a CaCO₃ dataset for the present SW Pacific for comparison with glacial/interglacial CaCO₃ variations in deep-water sediment cores, and to monitor future changes in [CO₃2−] and dissolution of sedimentary CaCO₃ resulting from increasing anthropogenic CO₂.  相似文献   

土壤碳循环研究进展及干旱区土壤碳循环研究展望   总被引：5，自引：1，他引：4  

许文强  陈曦  罗格平  蔺卿 《干旱区地理》2011,(4)

土壤碳库动态及其驱动机制是陆地生态系统碳循环与全球变化研究的热点问题之一。随着各国对《京都议定书》的重视,农业土壤碳库变化及其源汇效应研究不断加强,但以往研究土壤碳循环主要是针对有机碳,较少考虑无机碳的作用和地位,干旱区土壤无机碳储量巨大,其在区域碳循环过程中的贡献日益显著,这使得干旱区土壤碳循环研究必须同时考虑土壤有机碳和无机碳的行为。国内外关于农业土壤有机碳动态的研究主要围绕农业土壤有机碳储量、固碳潜力等问题展开,研究区多为湿润、半湿润地区;国际上对农业土壤无机碳动态的研究主要集中在干旱区土地管理措施对土壤发生性碳酸盐碳的形成与转化方面,研究方法以稳定同位素技术为主,但目前关于中国干旱区农业土壤无机碳动态的研究还较为薄弱。因此,应加强干旱区绿洲土壤碳循环研究,深入分析干旱区绿洲土壤碳的源/汇效应;探讨土壤无机碳动态变化的机理。  相似文献   

植物样品中无机元素分析的样品前处理方法和测定技术   总被引：11，自引：5，他引：6  

刘亚轩  李晓静  白金峰  马娜  张勤 《岩矿测试》2013,32(5):681-693

植物样品中无机元素的分析测定在环境地球化学和生物地球化学的研究中起着重要作用。植物样品中元素含量一般较低,须选用科学合理的前处理技术和灵敏度高、精密度好、检出限低的测定方法。本文针对植物样品前处理方法和无机元素分析测定技术的研究进展、优势与不足进行评述。前处理方法主要根据样品和待测元素的性质进行选择:干法灰化所用试剂少、空白值低,但组织致密型的样品不易灰化完全、高温下易造成元素挥发损失;湿法消解样品消解较为完全,但试剂消耗大、空白值高、操作繁琐;微波消解可以防止部分易挥发元素损失,用酸量少、消解速度快,但称样量相对较小,不适于需要大称样量的样品分析。几乎所有针对元素分析的仪器分析技术都可以用于植物样品分析,主要根据仪器适用的元素、必要的干扰校正以及基体改进等方面进行选择:电感耦合等离子体质谱法可同时测定植物样品中40种以上的元素,高分辨质谱的检出限可达fg/mL;电感耦合等离子体发射光谱法适用于某些植物样品中含量较高的P、K、Na等元素的测定;原子吸收光谱法可分析元素达70余种,是普及程度最高的仪器分析技术之一;原子荧光光谱法与氢化物发生技术的联用,在元素含量较低的植物样品分析中技术优势更加明显;新兴的激光诱导击穿光谱技术已被应用于植物样品分析,无需复杂的样品前处理,操作简单快速,可实现原位、在线、实时、多元素同时检测;其他选择性强、灵敏度高的分析技术,满足了一些特定元素不能用常规分析技术测定的需求。当前主流分析技术的样品前处理方法都存在着缺陷,固体进样技术将成为植物样品分析领域的发展方向之一。  相似文献