Trace gas exchange at the air/water interface: Measurements of mass accommodation coefficients     

W. Kirchner  F. Welter  A. Bongartz  J. Kames  S. Schweighoefer  U. Schurath 《Journal of Atmospheric Chemistry》1990,10(4):427-449

A liquid jet of 90 m diameter and variable length has been utilized to determine absorption rates and, hence, mass accommodation coefficients , of atmospheric trace gases. The compounds investigated are HCl (0.01), HNO₃ (0.01), N₂O₅ (0.005), peroxyacetyl nitrate (>0.001), and HONO (0.005). It is concluded that the absorption of these trace gases by liquid atmospheric water is not significantly retarded by interfacial mass transport. The strengths and limitations of the liquid jet technique for measuring mass accommodation coefficients are explored.  相似文献   

Pressure effect on Ti- or P-rich accessory mineral saturation in evolved granitic melts with differing K₂O/Na₂O ratios     

Trevor H. Green  John Adam 《Lithos》2002,61(3-4):271-282

The solubility of Ti- and P-rich accessory minerals has been examined as a function of pressure and K₂O/Na₂O ratio in two series of highly evolved silicate systems. These systems correspond to (a) alkaline, varying from alkaline to peralkaline with increasing K₂O/Na₂O ratio; and (b) strongly metaluminous (essentially trondhjemitic at the lowest K₂O/Na₂O ratio) and remaining metaluminous with increasing K₂O/Na₂O ratio (to 3). The experiments were conducted at a fixed temperature of 1000 °C, with water contents varying from 5 wt.% at low pressure (0.5 GPa), increasing through 5–10 wt.% at 1.5–2.5 GPa to 10 wt.% at 3.5 GPa. Pressure was extended outside the normal crustal range, so that the results may also be applied to derivation of hydrous silicic melts from subducted oceanic crust.

For the alkaline composition series, the TiO₂ content of the melt at Ti-rich mineral saturation decreases with increasing pressure but is unchanged with increasing K content (at fixed pressure). The P₂O₅ content of the alkaline melts at apatite saturation increases with increased pressure at 3.5 GPa only, but decreases with increasing K content (and peralkalinity). For the metaluminous composition series (termed as “trondhjemite-based series” (T series)), the TiO₂ content of the melt at Ti-rich mineral saturation decreases with increasing pressure and with increasing K content (at fixed pressure). The P₂O₅ content of the T series melts at apatite saturation is unchanged with increasing pressure, but decreases with increasing K content. The contrasting results for P and Ti saturation levels, as a function of pressure in both compositions, point to contrasting behaviour of Ti and P in the structure of evolved silicate melts. Ti content at Ti-rich mineral saturation is lower in the alkaline compared with the T series at 0.5 GPa, but is similar at higher pressures, whereas P content at apatite saturation is lower in the T series at all pressures studied. The results have application to A-type granite suites that are alkaline to peralkaline, and to I-type metaluminous suites that frequently exhibit differing K₂O/Na₂O ratios from one suite to another.  相似文献   

Seismic analysis of base-isolated liquid storage tanks using the BE–FE–BE coupling technique     

Moon Kyum Kim  Yun Mook Lim  Seong Yong Cho  Kyung Hwan Cho  Kang Won Lee 《Soil Dynamics and Earthquake Engineering》2002,22(9-12):1151-1158

A three-dimensional soil–structure–liquid interaction problem is numerically simulated in order to analyze the dynamic behavior of a base-isolated liquid storage tank subjected to seismic ground motion. A dynamic analysis of a liquid storage tank is carried out using a hybrid formulation, which combines the finite shell elements for structures and the boundary elements for liquid and soil. The system is composed of three parts: the liquid–structure interaction part, the soil–foundation interaction part, and the base-isolation part. In the liquid–structure interaction part, the tank structure is modeled using the finite elements and the liquid is modeled using the internal boundary elements, which satisfy the free surface boundary condition. In the soil–foundation interaction part, the foundation is modeled using the finite elements and the half-space soil media are modeled using the external boundary elements, which satisfy the radiation condition in the infinite domain. Finally, above two parts are connected with the base-isolation system to solve the system's behavior. Numerical examples are presented to demonstrate the accuracy of the developed method, and an earthquake response analysis is carried out to demonstrate the applicability of the developed technique. The properties of a real LNG tank located in the west coast of Korea are used. The effects of the ground and the base-isolation system on the behavior of the tank are analyzed.  相似文献   

陕西凤县八卦庙金矿床成矿地质特征及外围找矿前景分析   总被引：3，自引：0，他引：3  

张万业  刘方杰  黄长青 《矿产与地质》2003,17(2):136-139

阐述了八卦庙金矿床经历了长期、复杂的非线性成矿过程，着重分析了：含矿建造为与同生伸展断裂伴生的海底喷流热水沉积岩、热水浊积碎屑岩；脆-韧性剪切构造控制着主成矿过程；后期幔源岩浆气液叠加富集使其成为超大型金矿床。指出矿床成因为热水同生沉积细碎屑岩-剪切蚀变岩-幔源岩浆气液叠加富集型。八卦庙金矿床外围仍有巨大的找矿前景。  相似文献   

锡铁山铅锌矿地质特征、矿床成因及找矿标志   总被引：4，自引：1，他引：4  

李如满  汪树栋 《矿产与地质》2003,17(3):218-221

通过找矿工作的实践，认为锡铁山铅锌矿床是由火山喷流沉积—后期热液叠加改造富集的块状硫化物多金属矿床。区域上NW—SE向早古生代形成的裂谷带，三级盆地内沉积的晚奥陶世滩间山群的大理岩与绿片岩系是表区找矿的最佳区段。而绢云绿泥斜长片岩、含碳质绢云绿泥片岩、白色大理岩、条带状大理岩是铅锌矿的最重要的找矿标志。  相似文献   

中国东部苏鲁榴辉岩超基性岩褶皱带的演化及其与大别(中国)和柯切塔夫(哈萨克斯坦)杂岩的对比(英文)     

A.A.Marakushev  SANG Long-kang  A.V.Bobrov  ZHOU Han-wen  Liu Fu 《地学前缘》2003,10(3):277-289

苏鲁褶皱带形成于元古宙 (2 2 33～ 185 5Ma)典型优地槽构造环境 ,主要由石榴橄榄岩、石榴辉石岩、榴辉岩等侵入岩 (柯石英深度相地幔岩浆房中形成 )和它们的火山沉积建造围岩一起经褶皱、变质而形成。变质作用经历了先蓝片岩相 (前花岗岩 )后片麻岩混合岩相过程。由于变质作用的不规律性 ,苏鲁褶皱带可分为 2个构造带 :(1)东部构造带 (蓝片岩 )和 (2 )西部构造带 (片麻岩混合岩 )。根据A·都城秋穗所识别的变质带系统 ,可将其作为一个双变质带。东部构造带以出现许多块状、条带状榴辉岩辉石岩橄榄岩组合的残余岩块为特征 ,其中还残留着高压的矿物 (石榴石、绿辉石、柯石英 ) ,而且有被混合岩和各种交代岩替代的显著标志。在中生代 ,苏鲁元古褶皱带受造山作用的影响活化 ,导致许多花岗岩体的侵入 ,使交代岩广泛发育。  相似文献   

降水云中液水含量的空基遥感   总被引：4，自引：0，他引：4  

刘锦丽  吕达仁  张凌  段树 《遥感学报》2003,7(3):227-232

在建立不同降水云垂直结构模式的基础上，利用矢量微波辐射传扬模式进行空基云雨遥感的数值试验。结果表明：星载微波辐射计6．9GHz通道对降水云的冰层很不敏感，而对降水云校总液水含量(LWC)非常敏感；辐射亮温(Tb)随LWC呈单调变化关系；进一步考查这个频率下b的两个极化分量差△Tb(＝Tbv—Tbh)和LWC的关系发现，不同云结构(对流云和层状云)对△Tb-LWC关系影响较小。研究分析表明，6．9GHz的v,h两个通道有可能用于遥感降水云的液水总量。  相似文献