西湖茶园茶叶铅污染铅同位素示踪     

郦逸根  路远发 《物探与化探》2008,32(2):180-185

通过对西湖茶园的植物和土壤样品进行一系列的调查,以着力寻找茶叶的铅污染源。利用铅同位素技术对西湖茶园的土壤、茶叶和城区的燃煤、大气气溶胶、汽车尾气进行铅同位素示踪研究。研究表明,茶园土壤铅物质的可溶相具同源性和残查态偏于多源性。清洗后的茶叶铅含量显著降低,但其同位素组成不发生明显改变,显示出茶叶中的铅与叶面空气沉降物中的铅同源。不同介质铅同位素对比值平均值呈现表土、大气(气溶胶)、煤的w(²⁰⁶Pb)/w(²⁰⁷Pb)与茶叶趋于相近,汽油低之;表土、大气(气溶胶)、汽油的w(²⁰⁸Pb)/〔w(²⁰⁶Pb)+w(²⁰⁷Pb)〕与茶叶趋于相近,煤略高之。不同区域茶叶铅物质具同源性,与种植的农业地质背景无关。在煤燃烧、气化过程中,Pb进入大气,通过大气沉降或被茶树吸收或附着在茶叶叶面;汽车尾气的排放是茶树铅污染的重要原因之一。  相似文献   

Carbon and oxygen isotopic composition of car- bonate cements of different phases in terrigenous siliciclastic reservoirs and significance for their origin： A case study from sandstones of the Triassic Yanchang Formation, southwestern Ordos Basin, China     

Qi Wang  Xizhun Zhuo  Guojun Chen  Xiaoyan Li 《中国地球化学学报》2008,27(3):249-256

Early carbonate cements in the Yanchang Formation sandstones are composed mainly of calcite with relatively heavier carbon isotope （their δ^18O values range from -0.3‰- -0.1‰） and lighter oxygen isotope （their δ^18O values range from -22.1‰- -19.5‰）. Generally, they are closely related to the direct precipitation of oversaturated calcium carbonate from alkaline lake water. This kind of cementation plays an important role in enhancing the anti-compaction ability of sandstones, preserving intragranular volume and providing the mass basis for later disso- lution caused by acidic fluid flow to produce secondary porosity. Ferriferous calcites are characterized by relatively light carbon isotope with δ^13C values ranging from -8.02‰ to -3.23‰, and lighter oxygen isotope with δ^18O values ranging from -22.9‰ to -19.7‰, which is obviously related to the decarboxylation of organic matter during the late period of early diagenesis to the early period of late diagenesis. As the mid-late diagenetic products, ferriferous cal- cites in the study area are considered as the characteristic authigenic minerals for indicating large-scaled hydrocarbon influx and migration within the clastic reservoir. The late ankerite is relatively heavy in carbon isotope with δ^13C values ranging from -1.92‰ to -0.84‰, and shows a wide range of variations in oxygen isotopic composition, with δ^18O values ranging from -20.5‰ to -12.6‰. They are believed to have nothing to do with decarboxylation, but the previously formed marine carbonate rock fragments may serve as the chief carbon source for their precipitation, and the alkaline diagenetic environment at the mid-late stage would promote this process.  相似文献   

Geochemical characteristics and source analysis of inflow of mine water in Wang’ershan Gold Mine, Shandong   总被引：1，自引：0，他引：1  

QIAN Jianping  LI Shuangli  and CAO Chao Guilin University of Technology  Guilin  China 《中国地球化学学报》2008,(1)

Through a systematic observation of water level and temperature, and a comprehensive analysis of the data on major/trace elements, nitrite, hydrogen-oxygen isotopes, the conclusion has been drawn that there are two relatively independent groundwater systems (cool water and hot water), and the geochemical indicators of hot/cool waters are described. The cool water system is relatively enriched in Ca2 , Mg2 and HCO3-. Its TDS is relatively low, about 1400–1800 mg/L. The hot water system is relatively enriched in K , Na , Cl- and SO42-. Its TDS is relatively high, about 2200–2300 mg/L. The cool water system is enriched in Ba, Ga, Cd, and the hot water system is enriched in B, Ti, Cr, Ni, Cu, Mo, Rb, and Cs, relatively. Especially, the contents of Rb and Cs in the hot water system are more than five times as high as those in the cool water system. The NO3- contents of cool water discharged from the gold mine are relatively high, and those of hot water are extremely low. The δD and δ18O values follow an increasing order of surface water>mine cool water>mine hot water. The cool water comes mainly from the lateral supply of phreatic water, while the hot water comes mainly from the vertical supply of deeply circulating structure-fracture water. The ratio of cool water over hot water was estimated to be about 1:1 by a water quality model..  相似文献   

Environmental Redox Changes of the Ancient Sea in the Yangtze Area during the Ordo-Silurian Transition     

YAN Detian  CHEN Daizhao  WANG Qingchen  WANG Jianguo  CHU Yang 《《地质学报》英文版》2008,82(3):679-689

Extensive organic-matter （OM） rich facies （black shales） occur in the Ordo-Silurian boundary successions in the Yangtze area, South China. To investigate the redox changes of the Yangtze Sea during the Ordo-Silurian transition, two OM sections （Wangjiawan in Yichang, Hubei Province, and Sanjiaguan in Zhangjiajie, Hunan Province） straddling the Ordo-Silurian boundary are studied. The measurements finished in this study include contents of the total organic carbon （TOC）, pyrite sulphur, and different species of Fe, including dithionite-extractable Fe （FED）, pyrite Fe （FeP）, HCl-extractable Fe （FeH）, and total Fe （FeT）, in black shales, as well as other redox proxies, such as the SIC ratio, the ratio between highly reactive Fe （FeHR = FeD ＋ FeP） and FeT, and the FeP/（FeP ＋ FeH） ratio, known as the degree of pyritization （DOP）. In the Wangjiawan section, the Middle Ashgill sediments have high FeHR/FeT ratios （0.20-0.77; avg. 0.45）, high DOP values （0.21-0.72; avg. 0.54）, and a relatively constant sulfur content independent of the organic carbon content. By the contrast, the mid-early Hirnantian deposits generally have low FeHR/FeT ratios （0.10-0.35; avg. 0.21）, low DOP values （0.11- 0.40; avg. 0.28）, and SIC values are clustering on the normal marine value （SIC = 0.36）. The late Hirnantian and early Rhuddanian deposits, similar to those of the Middle Ashgill deposits, are characterized by high FeHR/FeT ratios （0.32-0.49; avg. 0.41）, high DOP values （0.46-0.68; avg. 0.53） and fairly constant sulfur contents. These data suggest the occurrences of marine anoxia on the Yangtze Sea shelf during intervals of the Mid Ashgill, Late Hirnantian and Early Rhuddanian, and ventilated and oxygenated marine conditions during the mid-early Hirnantian time. The mid-early Hirnantian ventilated event was concomitant with the global glacial period, likely resulted from the glacio-eustatic sea-level fall and subsequent circulation of cold, dense oxygenated waters  相似文献   

胶东地区晚中生代岩浆活动及对大地构造的制约   总被引：16，自引：1，他引：15  

邱连贵  任凤楼  曹忠祥  张岳桥 《大地构造与成矿学》2008,32(1):117-123

应用近十几年来胶东地区及其周边岩浆岩体的同位素测年资料,结合几个岩体的新的SHRIMP测年数据(牙山岩体117.7Ma,院格庄岩体113.4Ma,正长斑岩脉115.7Ma),系统研究了该区晚中生代以来的岩浆活动规律,结果表明,该区可分为4个岩浆活动期;(1)晚侏罗世构造-岩浆热事件(150~160Ma),以玲珑-滦家河型岩体为代表,是在区域挤压构造应力作用下侵入的,属同构造或同造山时期的岩浆作用。(2)早白垩世早期构造-岩浆热事件(135~125Ma),以郭家岭岩体为典型,该时期的岩浆活动均具有双峰式岩浆作用特征,反映了伸展动力学背景。(3)早白垩世中晚期构造-岩浆热事件(125~105Ma),以崂山花岗岩为特征,该阶段对应于中国东部岩石圈大规模的减薄时期,是大陆裂谷作用的高峰期。(4)晚白垩世-古新世基性-超基性火山作用。本文还探讨了岩浆活动的地球动力学因素及其对大地构造的制约。  相似文献   

四川省九龙县娃娃沟泥石流运动特征与堵河成灾机制分析     

施蕾蕾  陈宁生  杨成林 《中国地质灾害与防治学报》2008,19(2):16-22

2006年7月16日娃娃沟流域暴发的大规模泥石流,给下游3个电站造成巨大经济损失,是大渡河流域一次典型的灾害性泥石流。分析得出,娃娃沟泥石流重度高、搬运能力强,泥石流固体物质砂、石混杂,粗大砾石含量高;暴发频率低、规模大,流速及峰值流量分别高达10．78m／s及798．5m^3／s;在汇口处,泥石流堆积物堵塞河道是引起下游电站受灾的重要原因,高重度、粗颗粒、大流量的组合是此次泥石流堵江的重要原因。堵河判别计算结果显示在发生百年一遇泥石流时,该断面均有发生堵河的可能。娃娃沟泥石流表明：①在大渡河支流的泥石流沟周边的中小电站极有可能在泥石流暴发时受到破坏。因此,电站建设过程中应加强对周边泥石流沟的防灾减灾工作;②虽然娃娃沟流域植被良好,但仍然发生了大规模泥石流。表明植被不能完全避免泥石流的发生,对于此类泥石流沟不能疏忽大意。  相似文献   

泥石流调查遥感解译新方法研究   总被引：5，自引：2，他引：3  

冯杭建  唐小明  游省易 《中国地质灾害与防治学报》2008,19(3):124-129

文章在分析总结近年来遥感技术在地质灾害调查评价工作应用的基础上,针对存在的不足,就区域小流域泥石流地质灾害调查评价的遥感解译应用,提出了基于虚拟GIS和水文空间分析的遥感解译方法（RSVH）。该方法综合利用虚拟GIS、遥感图像数字处理技术和空间分析技术,将大尺度区域降级为较小尺度的空间逻辑单元。针对各单元应用遥感影像和高精度DEM数据创建三维虚拟场景。同时叠加地形、地质、岩性、土壤、灾害等具有丰富属性信息的图层,较好地解决了大尺度区域范围内遥感解译工作面临的困难。为小流域地质灾害的调查工作提供了新思路。  相似文献   

生物气CO_2还原途径中碳同位素分馏作用研究及应用   总被引：2，自引：0，他引：2  

李谨  胡国艺  张英  杨贵芳  崔会英  曹宏明  胡须龙 《地学前缘》2008,15(5):357

地质历史中,CO2/H2还原产甲烷作用对生物气的形成具有十分重要的意义。中国柴达木盆地第四系生物气主要为CO2/H2还原型生物气。笔者以CO2/H2还原生气理论为指导,进行不同初始碳同位素值和不同赋存状态碳源的生物模拟实验,研究CO2/H2还原产气过程中发生的碳同位素分馏作用。实验结果表明,产物中δ13CH4值与底物的δ13C值呈很好的正相关关系;在反应母质过量的情况下,碳源的赋存状态可以影响产物甲烷的碳同位素组成。以游离形式CO2还原产生的甲烷δ13C值,相对于以HCO3-、CO23-离子形式产生的甲烷δ13C值轻。通过柴达木盆地东部第四系生物气田实例分析,探讨了该区生物气的主要底物CO2的来源及赋存状态,对评价盆地生物气资源和有利勘探区预测有重要的参考价值。  相似文献   

太湖入湖河道沉积物中生物利用磷和营养水平分析   总被引：7，自引：0，他引：7  

袁旭音  李兵  许薇薇  陈颖 《地学前缘》2008,15(5):212

为了解太湖入湖河道的营养状况,研究了太湖西部河流沉积物生物利用磷的组成与分布。研究结果显示,北部沉积物中营养元素较高,南部较低;沉积物中生物利用磷的含量次序为藻类可利用磷(AAP)>NaHCO3提取磷(OLP)>水溶性磷(WSP)>易解吸磷(RDP),其中AAP是重要的生物利用磷,AAP的比例越高,富营养化程度越高。AAP与营养元素的相关性在不同区域河道有所不同,北部河道与总氮(TN)、总磷(TP)相关性较好,中部和南部河道与沉积物有机质总量(TOM)相关性较好。沉积物的生物利用磷受不同污染源影响较大。对比河道沉积物与湖泊沉积物的特征,发现湖泊沉积物中生物利用磷(BAP)/总磷(TP)、藻类可利用磷(AAP)/总磷(TP)都高于河道沉积物,表明湖泊沉积物中的磷更容易被植物吸收。  相似文献   

南堡凹陷周边古生界油气藏形成条件及成藏模式   总被引：1，自引：0，他引：1       下载免费PDF全文

成永生  陈松岭  王海  藏锋 《沉积与特提斯地质》2008,28(1):76-81

为深入分析南堡凹陷周边地区碳酸盐岩油气成藏机理,笔者通过对区内碳酸盐岩的薄片鉴定、化学分析、烃源岩分析、物性分析、铸体压汞等实验测试和分析.结果表明,区内碳酸盐岩不具备生油能力,其油源为南堡凹陷古近系生油岩,且古近系生油岩生油母质较好、成熟度高、厚度大;碳酸盐岩基质孔隙度差,晶间孔欠发育,早期裂缝基本被充填完全,晚期构造裂缝为油气运移和聚集的主要空间;岩溶发育垂向分带不明显,溶蚀孔洞孤立且连通性差;区内主要发育有4类盖层,且储盖组合良好,发育有不整合油藏和构造块状油藏两种油气藏类型.  相似文献