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21.
新疆阿克陶红蓝宝石矿床矿物学研究   总被引:3,自引:0,他引:3  
王礼胜  何明跃 《现代地质》1997,11(1):36-43,T001
新疆阿克陶红蓝宝石矿床含矿岩石具有典型的眼球状、条带状混合岩化构造。浅色脉体中的钾长石有序度很低,属单斜正长石,其中部分发育钠长石出溶条纹。基体中出现富铝矿物矽线石和电气石,黑云母中Al2O3含量高;斜长石An值低,为钠长石。含矿岩石为富铝贫硅低钙质岩石。脉体中的红蓝宝石晶体中发现大量流体熔融包裹体。红蓝宝石矿床为混合岩化作用成因,形成于高温低压条件下  相似文献   
22.
熔体及其活动在造山带的演化中发挥了重要作用。熔体活动发迹了地壳应力作用方式而诱发形成剪切带或断层;熔体活动调整块体间的位移而影响造山带的变形;  相似文献   
23.
Quartz-rich xenoliths in lavas and pyroclastic rocks from VulcanoIsland, part of the Aeolian arc, Italy, contain silicic meltinclusions with high SiO2 (73–80 wt %) and K2O (3–6wt %) contents. Two types of inclusions can be distinguishedbased on their time of entrapment and incompatible trace element(ITE) concentrations. One type (late, ITE-enriched inclusions)has trace element characteristics that resemble those of themetamorphic rocks of the Calabro-Peloritano basement of theadjacent mainland. Other inclusions (early, ITE-depleted) havevariable Ba, Rb, Sr and Cs, and low Nb, Zr and rare earth element(REE) contents. Their REE patterns are unfractionated, witha marked positive Eu anomaly. Geochemical modelling suggeststhat the ITE-depleted inclusions cannot be derived from equilibriummelting of Calabro-Peloritano metamorphic rocks. ITE-enrichedinclusions can be modelled by large degrees (>80%) of meltingof basement gneisses and schists, leaving a quartz-rich residuerepresented by the quartz-rich xenoliths. Glass inclusions inquartz-rich xenoliths represent potential contaminants of Aeolianarc magmas. Interaction between calc-alkaline magmas and crustalanatectic melts with a composition similar to the analysed inclusionsmay generate significant enrichment in potassium in the magmas.However, ITE contents of the melt inclusions are comparablewith or lower than those of Vulcano calc-alkaline and potassicrocks. This precludes the possibility that potassic magmas inthe Aeolian arc may originate from calc-alkaline parents throughdifferent degrees of incorporation of crustal melts. KEY WORDS: melt inclusions; crustal anatexis; magma assimilation; xenoliths; Vulcano Island  相似文献   
24.
We report compositions of homogenized quartz-hosted melt inclusions from a layered sequence of Li-, F-rich granites in the Khangilay complex that document the range of melt evolution from barren biotite granites to Ta-rich, lepidolite–amazonite–albite granites. The melt inclusions are crystalline at room temperature and were homogenized in a rapid-quench hydrothermal apparatus at 200 MPa before analysis. Homogenization runs determined solidus temperatures near 550 °C and full homogenization between 650 and 750 °C. The compositions of inclusions, determined by electron microprobe and Raman spectroscopy (for H2O), show regular overall trends of increasing differentiation from the least-evolved Khangilay units to apical units in the Orlovka intrusion. Total volatile contents in the most-evolved melts reach over 11 wt.% (H2O: 8.6 wt.%, F: 1.6 wt.%, B2O3: 1.5 wt.%). Concentrations of Rb range from about 1000 to 3600 ppm but other trace elements could not be measured reliably by electron microprobe. The resulting trends of melt evolution are similar to those described by the whole-rock samples, despite petrographic evidence for albite- and mica-rich segregations previously taken as evidence for post-magmatic metasomatism.

Melt variation trends in most samples are consistent with fractional crystallization as the main process of magma evolution and residual melt compositions plot at the granite minimum in the normative Qz–Ab–Or system. However, melts trapped in the highly evolved pegmatitic samples from Orlovka deviate from the minimum melt composition and show compositional variations in Al, Na and K that requires a different explanation. We suggest that unmixing of the late-stage residual melt into an aluminosilicate melt and a salt-rich dense aqueous fluid (hydrosaline melt) occurred. Experimental data show the effectiveness of this process to separate K (aluminosilicate melt) from Na (hydrosaline melt) and high mobility of the latter due to its low viscosity and relatively low density may explain local zones of albitization in the upper parts of the granite.  相似文献   

25.
26.
The viscosity of synthetic peridotite liquid has been investigated at high pressures using in-situ falling sphere viscometry by combining a multi-anvil technique with synchrotron radiation. We used a newly designed capsule containing a small recessed reservoir outside of the hot spot of the heater, in which a viscosity marker sphere is embedded in a forsterite + enstatite mixture having a higher solidus temperature than the peridotite. This experimental setup prevents spheres from falling before a stable temperature above the liquidus is established and thus avoids difficulties in evaluating viscosities from velocities of spheres falling through a partially molten sample.

Experiments have been performed between 2.8 and 13 GPa at temperatures ranging from 2043 to 2523 K. Measured viscosities range from 0.019 (± 0.004) to 0.13 (± 0.02) Pa s. At constant temperature, viscosity increases with increasing pressure up to  8.5 GPa but then decreases between  8.5 and 13 GPa. The change in the pressure dependence of viscosity is likely associated with structural changes of the liquid that occur upon compression. By combining our results with recently published 0.1 MPa peridotite liquid viscosities [D.B. Dingwell, C. Courtial, D. Giordano, A. Nichols, Viscosity of peridotite liquid, Earth Planet. Sci. Lett. 226 (2004) 127–138.], the experimental data can be described by a non-Arrhenian, empirical Vogel-Fulcher-Tamman equation, which has been modified by adding a term to account for the observed pressure dependence of viscosity. This equation reproduces measured viscosities to within 0.08 log10-units on average. We use this model to calculate viscosities of a peridotitic magma ocean along a liquid adiabat to a depth of  400 km and discuss possible effects on viscosity at greater pressures and temperatures than experimentally investigated.  相似文献   

27.
The Mont Collon mafic complex is one of the best preserved examples of the Early Permian magmatism in the Central Alps, related to the intra-continental collapse of the Variscan belt. It mostly consists (> 95 vol.%) of ol + hy-normative plagioclase-wehrlites, olivine- and cpx-gabbros with cumulitic structures, crosscut by acid dikes. Pegmatitic gabbros, troctolites and anorthosites outcrop locally. A well-preserved cumulative sequence is exposed in the Dents de Bertol area (center of intrusion). PT calculations indicate that this layered magma chamber emplaced at mid-crustal levels at about 0.5 GPa and 1100 °C. The Mont Collon cumulitic rocks record little magmatic differentiation, as illustrated by the restricted range of clinopyroxene mg-number (Mg#cpx = 83–89). Whole-rock incompatible trace-element contents (e.g. Nb, Zr, Ba) vary largely and without correlation with major-element composition. These features are characteristic of an in-situ crystallization process with variable amounts of interstitial liquid L trapped between the cumulus mineral phases. LA-ICPMS measurements show that trace-element distribution in the latter is homogeneous, pointing to subsolidus re-equilibration between crystals and interstitial melts. A quantitative modeling based on Langmuir's in-situ crystallization equation successfully duplicated the REE concentrations in cumulitic minerals of all rock facies of the intrusion. The calculated amounts of interstitial liquid L vary between 0 and 35% for degrees of differentiation F of 0 to 20%, relative to the least evolved facies of the intrusion. L values are well correlated with the modal proportions of interstitial amphibole and whole-rock incompatible trace-element concentrations (e.g. Zr, Nb) of the tested samples. However, the in-situ crystallization model reaches its limitations with rock containing high modal content of REE-bearing minerals (i.e. zircon), such as pegmatitic gabbros. Dikes of anorthositic composition, locally crosscutting the layered lithologies, evidence that the Mont Collon rocks evolved in open system with mixing of intercumulus liquids of different origins and possibly contrasting compositions. The proposed model is not able to resolve these complex open systems, but migrating liquids could be partly responsible for the observed dispersion of points in some correlation diagrams. Absence of significant differentiation with recurrent lithologies in the cumulitic pile of Dents de Bertol points to an efficiently convective magma chamber, with possible periodic replenishment.  相似文献   
28.
Mechanisms of fractional crystallization with simultaneous crustalassimilation (AFC) are examined for the Kutsugata and Tanetomilavas, an alkali basalt–dacite suite erupted sequentiallyfrom Rishiri Volcano, northern Japan. The major element variationswithin the suite can be explained by boundary layer fractionation;that is, mixing of a magma in the main part of the magma bodywith a fractionated interstitial melt transported from the mushyboundary layer at the floor. Systematic variations in SiO2 correlatewith variations in the Pb, Sr and Nd isotopic compositions ofthe lavas. The geochemical variations of the lavas are explainedby a constant and relatively low ratio of assimilated mass tocrystallized mass (‘r value’). In the magma chamberin which the Kutsugata and Tanetomi magmas evolved, a strongthermal gradient was present and it is suggested that the marginalpart of the reservoir was completely solidified. The assimilantwas transported by crack flow from the partially fused floorcrust to the partially crystallized floor mush zone throughfractures in the solidified margin, formed mainly by thermalstresses resulting from cooling of the solidified margin andheating of the crust. The crustal melt was then mixed with thefractionated interstitial melt in the mushy zone, and the mixedmelt was further transported by compositional convection tothe main magma, causing its geochemical evolution to be characteristicof AFC. The volume flux of the assimilant from the crust tothe magma chamber is suggested to have decreased progressivelywith time (proportional to t–1/2), and was about 3 x 10–2m/year at t = 10 years and 1 x 10–2 m/year at t = 100years. It has been commonly considered that the heat balancebetween magmas and the surrounding crust controls the couplingof assimilation and fractional crystallization processes (i.e.absolute value of r). However, it is inferred from this studythat the ratio of assimilated mass to crystallized mass canbe controlled by the transport process of the assimilant fromthe crust to magma chambers. KEY WORDS: assimilation and fractional crystallization; mass balance model; magma chamber; melt transport; Pb isotope  相似文献   
29.
Multianvil melting experiments in the system CaO–MgO–Al2O3–SiO2–CO2(CMAS–CO2) at 3–8 GPa, 1340–1800°C, involvingthe garnet lherzolite phase assemblage in equilibrium with CO2-bearingmelts, yield continuous gradations in melt composition betweencarbonatite, kimberlite, melilitite, komatiite, picrite, andbasalt melts. The phase relations encompass a divariant surfacein PT space. Comparison of the carbonatitic melts producedat the low-temperature side of this surface with naturally occurringcarbonatites indicates that natural magnesiocarbonatites couldbe generated over a wide range of pressures >2·5 GPa.Melts analogous to kimberlites form at higher temperatures alongthe divariant surface, which suggests that kimberlite genesisrequires more elevated geotherms. However, the amount of waterfound in some kimberlites has the potential to lower temperaturesfor the generation of kimberlitic melts by up to 150°C,provided no hydrous phases are present. Compositions resemblinggroup IB and IA kimberlites are produced at pressures around5–6 GPa and 10 GPa, respectively, whereas the compositionsof some other kimberlites suggest generation at higher pressuresstill. At pressures <4 GPa, an elevated geotherm producesmelilitite-like melt in the CMAS–CO2 system rather thankimberlite. Even when a relatively CO2-rich mantle compositioncontaining 0·15 wt % CO2 is assumed, kimberlites andmelilitites are produced by <1% melting and carbonatitesare generated by even smaller degrees of melting of <0·5%. KEY WORDS: carbonatite; CO2; kimberlite; melilitite; melt generation  相似文献   
30.
The argon solubility of 38 liquids in the system Na2O-CaO-MgO-Al2O3-SiO2 (NCMAS) has been determined at 1873 K and 1 bar, the argon concentration of presaturated glasses being measured using a static mass spectrometer. For compositions in the subsystem diopside (CaMgSi2O6), nepheline (NaAlSiO4), albite (NaAlSi3O8), anorthite (CaAl2Si2O8), argon solubility is generally a linear function of the relative proportion of each end member, solubility being lowest in diopside melt (1.53 10−5 cm3 STP · g−1 · bar−1) and highest in albite melt (2.88 10−4 cm3 STP · g−1 · bar−1). For the tectosilicate joins studied (SiO2-Na2Al2O4, SiO2-CaAl2O4, SiO2-MgAl2O4) solubility decreases with decreasing silica content in all cases, being highest for Na-bearing liquids and lowest for Mg-bearing liquids at constant molar silica content. Where comparison is possible our results are in good agreement with data from the literature. When our data are considered in isolation we find that argon solubility shows an excellent correlation with calculated ionic porosity. The covariation of argon solubility and liquid density is also reasonable, that with molar volume less convincing and that with polymerization state (as defined by the ratio of the number of nonbridging oxygens and tetrahedral network forming cations; NBO/T) nonexistent. However, when our data are combined with those from the literature no well constrained correlation between argon solubility and ionic porosity is apparent. Based upon this observation and consideration of the temperature dependence of noble gas solubility it is concluded that ionic porosity is not a universally applicable parameter which may be used to predict noble gas solubility as a function of composition, temperature and pressure. Two new models for calculating argon solubility are proposed, both employing the notion of partial molar argon solubilities. The first uses oxide components, for which partial molar argon solubility is directly proportional to partial molar ionic porosity calculated at 1873 K, irrespective of the temperature of experimental equilibration. The second model, which offers the best fit to the available data, employs tetrahedral units rather than oxides as the proposed melt components. This latter model successfully accounts for reported argon solubilities in simple Al-free systems, in simple Al-bearing systems and in natural liquids. This is interpreted to infer that argon is incorporated in large sites in the liquid structure (such as the space within rings of n-tetrahedra) although further work is required to understand the quantitative links between melt structure and noble gas solubility.  相似文献   
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