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51.
Chunye LIN Mengchang HE Baixing YAN Xiangchun QUAN Yuxiang ZHOU Wei GUO Zhifeng YANG 《中国地球化学学报》2006,25(B08):118-119
The Second Songhua River was subjected to a large amount of untreated effluent from petrochemical industries in Jilin City in the 1960s to the 1970s. The objectives of this study were to investigate the mercury and other heavy metal contamination in the sediment of the river. The river bottom sediment was sampled from the river segment between Jilin City to Haerbin City in 2005. Total concentrations of Hg, Cd, Cu, Cr, Pb, Zn, Ni, As, Sc, and major cations (A1, Fe, Mg, Ca, K, Na) in the sediment were measured by atomic fluorescence spectrometer, ICP-MS, and ICP-OES, respectively, following digestion with various acids. We found the concentrations of most elements in the uncontaminated sediment were significantly correlated to those of Sc. 相似文献
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This paper presents the results of investigation on uptake of radioactive species 90Sr and 137Cs present in the liquid effluents from nuclear processing plants. Chemical precipitation process is adopted to remove radioactivity from the effluents with low and intermediate level of activity. In this process, radioactive 90Sr and 137Cs are co-precipitated along with copper ferrocyanide, ferric hydroxide and either calcium phosphate or barium sulphate. These precipitates being fine in size require flocculation for enhanced settling rate in clarifier/thickener. The flocculation by some selected high molecular weight polyacrylamide based polymers has improved the uptake of radioactive metal ions. The adsorption of these radioactive species has been found to increase in the presence of these flocculants thereby improving the decontamination factor (DF). While flocculating the precipitates, there may be some complex formation with Sr2+/Cs+, flocculant and the substrate. This has enhanced the uptake of the radioactive metal ions from the liquid component. The plant trials have indicated the improvement of DF value due to flocculation by cationic flocculant. 相似文献
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Yue GAO Martine Leermakers Gabriel Billon Baghdad Ouddane Jean-claude Fisher Willy Baeyens 《中国地球化学学报》2006,25(B08):199-199
In polluted aquatic systems, toxic metals are often accumulated in bottom sediments. They are, however, not necessarily stored definitively because diagenetic processs can modify redox, pH and even the amount of complexing ligands, releasing the trace metals back into the pore waters and the water column. Especially the labile metal fraction in the pore waters is important since this is the bioavailable fraction determining the bio-toxicity of the sediments. The goal of our study was therefore to assess, with novel sampling techniques, this bioavailable metal fraction in the pore waters as well as the flux towards the overlying water column. High-resolution profiles of trace metals in pore waters of marine and riverine sediments were assessed by DET (diffusive equilibrium in thin films) and DGT (diffusive gradients in thin films) gel techniques. The DET technique uses a diffusive gel layer that equilibrates with the aquatic system and with this technique the concentrations of total dissolved trace metals are obtained directly. The DGT technique uses an acrylamide diffusive gel backed by a resin gel (Chelex) which binds trace metals. With the DGT technique only labile species of selected metals can be captured. According to the redox potential measurements, the marine sediments were suboxic (200 mV to -220 mV versus Ag/AgCl electrode), while the riverine sediments were completely anoxic (-160 mV to -220 mV versus Ag/AgCl electrode). This redox potential was apparently controlling the trace metals species in the pore waters: for example a strong correlation between Mn and Co was found in the riverine sediments (for DET and DGT sampling), while in the marine sediments trace metals presented various behaviors. 相似文献
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Y.T. John Kwong 《中国地球化学学报》2006,25(B08):229-230
Naturally acidic drainage associated with pyritic black shale has been observed in many locations in the Yukon Territory. While not necessarily linked to known mineral deposits, most of these natural acid rock drainage occurrences show elevated dissolved concentrations of trace elements, especially zinc, nickel, copper, cadmium and arsenic. Based on field observations, microbial investigation, chemical analyses and geochemical modeling, the fate and transport of potentially deleterious elements at two natural acid drainage occurrences with slightly different settings are examined. The Macintosh Creek is a small, acidic stream (pH 2.98-3.40), 2 km long, located in the Macmillan Pass area of east-central Yukon amidst known sedimentary exhalative massive sulfide mineralization but remains undisturbed by exploration activities. Its trace metal content is apparently derived from groundwater discharges, which gave as much as 5.0, 2.5, 0.7, 0.13 and 0.03 mg/L ofZn, Ni, Cu and As, respectively. Interaction and sorption reactions with algal mats, biofilms and iron oxyhydroxides appear to be the dominant mechanisms attenuating aqueous contaminant transport along the stream. Cryogenic precipitation further consolidates the ferricrete formation and reduces the mobility of the sorbed metals. The tributaries of the Engineering Creek along the Dempster Highway in northern Yukon drain through a series of dolomite, phyllite, argillite, limestone, black shale, sandstone and conglomerate with no known concentration of mineralization. In this area, the water chemistry fully reflects the local geology with acidic streams invariably associated with black shale occurrences. Groundwater seeps in the headwaters area of the km-180 Creek completely enclosed in black shale gave pH 3.0 and as much as 148, 39, 2.9 and 9.1 mg/L of Zn, Ni, Cu and As, respectively. Sorption with iron oxyhydroxide and organic matter appear to dominate the attenuation of contaminant transport along the stream. However, once entered into carbonate-dominated terrains, secondary carbonate minerals exercise additional geochemical control on the local water chemistry as a result of neutralization. 相似文献
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Wenhong FAN Jun CHEN 《中国地球化学学报》2006,25(B08):261-261
The mimetic ocean environment and chemical method were used to research the bioavailability effect of humic acid on five heavy metals in sediment, including Cd, Cu, Zn, Pb and Ni. The sediment was separated into four containers with artificial seawater, and each of them had different concentrations of humic acid. The values of concentrations covered the whole range found in natural sediment (0.1%-10%). According to the 48 hours LC50 of clam and distribution coefficient, metals were added in artificial seawater, and their speciation was determined at first and then after two days' incubation. It was found the bioavailability of heavy metals was reduced in the presence of humic acid. The obvious negative effect on Zn was observed, but the influence on Cd was not remarkable. In addition, the contents of Pb and Ni increased obviously in organic phase, and they are correlative with the concentrations of humic acid. 相似文献
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Siyue LI Quanfa ZHANG 《中国地球化学学报》2006,25(B08):274-274
As the diversion dike of the Middle Route of the South to North Water Transfer Project (MRSNWTP), the water quality and water quantity of Danjiangkou Reservoir is critical to the project. At present, the rates of industrial wastewater treatment and sewage discharge, which belongs to Chinese State Standard in the districts near the reservoir except Shiyan city, are less than 60% and 40% respectively. The point source pollutants will be controlled because of the project after some time, but the non-point source pollutants caused by vegetation degradation and water-soil erosion will not be controlled effectively in a long time. Water samples were collected from the Danjiangkou Reservoir during 2004 and 2005 and analyzed for trace metals, i.e., silver (Ag), aluminum (Al), arsenic (As), barium (Ba), bismuth (Bi), calcium (Ca), cadmium (Cd), cobalt (Co), chromium (Cr), copper (Cu), iron (Fe), mercury (Hg), potassium (K), lithium (Li), magnesium (Mg), manganese (Mn), molybdenum (Mo), sodium (Na), nickel (Ni), lead (Pb), antimony (Sb), selenium (Se), silicon (Si), strontium (Sr), vanadium (V), zinc (Zn), chemicophysical parameters and nutrients, i.e., temperature (T), pH, dissolved oxygen (DO), turbidity, total suspended solid (TSS), nitrate/ammonia/ammonium-nitrogen (NO3^-/NH3/NH4^+-N), total nitrogen (TN), dissolved inorganic nitrogen (DIN), total phosphorus (TP), potassium permanganate index (IMn), biochemical oxygen demand (BOD), dissolved inorganic carbon (HCO3^-). Our results are water quality belongs to Chinese standard level II, trace metals are low, but they are accumulating, and many of which, i.e., As, Pb, will endanger reservoir water security. 相似文献