Direct Current Plasma Emission Spectrometric Determination of Major, Minor and Trace Elements in Microwave Oven Acid Leachates of Powdered Whole Coal Samples     

Sandro Fadda 《Geostandards and Geoanalytical Research》2005,29(1):143-156

Major concentrations of Al₂O₃, Fe₂O₃, MgO, CaO, Na₂O and K₂O, minor levels of TiO₂, P₂O₅ and thirty petrologically, geochemically and environmentally significant trace elements have been determined in microwave oven acid leachates of whole powdered coal samples by direct current plasma‐atomic emission spectrometry (DCP‐AES). A single sample preparation procedure was suitable for all the determinations with no additional dilution step for major elements solution. Dried samples (0.5 g) were treated in low‐pressure PFA digestion vessels with HF/HCl/HNO₃/HClO₄ acids to quantitatively extract the analytes from the bulk material, while leaving the major part of organic matrix as a residue. The major constituents of geological samples, in particular the easily ionised elements (EIEs) such as alkali and alkaline earths, may complicate the instrumental determinations in DCP‐AES because of differential enhancements of elemental emission intensities and stray light interferences. Taking account of these factors, the coal matrix is considered to have very low major oxide totals as compared to many other common geo‐environmental and related materials (rocks, sediments, soil, ashes etc.). The sample size employed here, while yielding a relatively concentrated solution to cover a wide range of elemental determinations, provided a sample matrix that significantly diminished interferences for DCP measurements. The need for closely matching the unknowns and calibrators was eliminated except for overall acidity and an excess quantity of caesium for EIE buffering. Calibration of the spectrometer was accomplished by simple aqueous single element solutions as high concentration calibrators in addition to a reagent blank as a low concentration calibrator. Two point working curves were established to allow for the maximum concentrations of each element expected in the unknowns. The precision of determinations under routine conditions as well as the reproducibility of the leaching and precision of instrumental measurements have been evaluated. Relative standard deviations (RSD) were of 1–2% for those elements whose concentrations in solid samples were well above the limits of quantification. Method detection limits in the buffered solutions were also evaluated. To evaluate the accuracy of the microwave oven‐DCP method a suite of eight certified coal reference materials of differing rank, were analysed with good agreement with the certified and/or available published data. Results are presented for the uncertified major oxides in the AR series reference materials.  相似文献   

工程破坏区植被发育动态过程的研究 --以古尔班通古特沙漠为例     

倪萍  牛博  刘江 《云南地理环境研究》2005,17(3):13-17

通过样方法及植被调查法,从纵向和横向两个不同方向对工程破坏后的沙地植被进行比较研究。在纵向上,由于植被恢复时间的不同,其恢复的程度也不同。植被恢复状况可明显的分3个阶段:定居前期(1～6a)主要以多年生羽叶三芒草和小半灌木绢蒿为主;中期(7～11a)主要以多年生小半灌木青杆沙蒿为主;后期(12～16a)主要生长着多年生麻黄及草本沙苔,地表出现大面积的生物结皮。在横向上,将恢复后期的植被与原始植被进行比较。通过对植被发育不同阶段过程中物种重要值、物种多样性、丰富度及生活型的变化等方面的调查,发现在不同阶段,各物种的重要值发生了不同的变化,物种多样性指数,均匀度指数,丰富度指数到后期均增大。  相似文献   

The lateglacial Quercus expansion in the southern European Alps: rapid vegetation response to a late Allerød climate warming?     

W. Finsinger  C. S. Lane  G. J. van Den Brand  F. Wagner‐Cremer  S. P. E. Blockley  A. F. Lotter 《第四纪科学杂志》2011,26(7):694-702

A pollen‐inferred vegetation shift, from pioneer birch–pine woodland to mixed pine–summergreen oak forests, in the southern Alpine forelands, is commonly attributed to a centennial‐scale warming that occurred between the Gerzensee Oscillation (GO) and the Younger Dryas. Two microtephra layers bracketing the Younger Dryas onset (the Laacher See Tephra and the Vedde Ash) improve the chronology at Lago Piccolo di Avigliana (northern Italy) and allowed accurate correlation with Central European records where the GO is clearly detected. We used pollen percentages, pollen accumulation rates (PARs) and plant macrofossils to assess the population dynamics of Quercus, and leaf‐cuticle analysis for a better taxonomic identification of Quercus. Our results indicate that the species that was locally present was probably Quercus robur. PARs suggest that the population expansion started as early as the Bølling and followed an exponential increase through time. We attribute this gradual shift to increasing summer temperatures and longer growing seasons which contrast with a gradually decreasing temperature trend as recorded in Greenland ice cores and in Central Europe. Breaks or set‐backs in the PAR record may indicate the biotic response to minor Lateglacial cooling events of different life‐history stages in the Quercus population. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Lake Neor reveals how mountain vegetation responded to 7000 years of hydroclimate variability in northwestern Iran     

Khadijeh Alinezhad  Elias Ramezani  Morteza Djamali  Arash Sharifi  Alireza Naqinezhad  Cyril Aubert  Emmanuel Gandouin  Ali Pourmand 《第四纪科学杂志》2021,36(4):598-610

Palynological and geochemical analyses provide valuable information about modern and past climatic regimes and vegetation. The impact of climate and humans on past vegetation in the semi-arid areas of northwestern Iran has received increased interest in the wake of warming temperatures in the Middle East. Palynological and down-core XRF elemental abundances from a peat core from Lake Neor enabled a reconstruction of vegetational changes of the past 7000 years over the highlands of northwestern Iran. Periods of increased arboreal pollen (AP) types and high (Artemisia + Poaceae)/Chenopodiaceae ratios along with low titanium abundances, high percentages of total organic carbon, more negative δD values, and higher carbon accumulation rates suggest a relatively wet climate. These conditions have persisted during the periods 6700–6200, 5200–4450 and 3200–2200 cal a bp. The overall low AP values, substantial rise of Chenopodiaceae, high Ti abundances and low values of palaeo-redox proxies, are all evidences of a drier climate, as has been reconstructed for the periods 6200–5200 and 4030–3150 cal a bp and the last 2200 years. An important feature of the last centuries is the increase of anthropogenic and pastoral indicator pollen types. Our results may provide basic data to predict future trends in vegetation dynamics under future climate change in western Asia.  相似文献   

金沙江干热河谷不同植被坡面土壤水分时空分布特征          下载免费PDF全文

韩姣姣  段旭  赵洋毅 《干旱区地理》2019,42(1):121-129

于2016年7~12月和2017年4月的旱、雨季期间，以金沙江干热河谷苴那小流域内的银合欢（Leucaena Benth）林地、车桑子（Dodonaea angustifolia）灌丛地和扭黄茅（Heteropogon cantortus）草地为研究对象，通过网格法和土钻法采集并测定了（0~100 cm）土层的土壤含水量，应用经典统计法和地统计学方法分析该区域不同林草植被下坡面土壤水分的动态变化特征。结果表明：（1）研究区土壤含水量总体较低，雨季显著大于旱季，旱、雨季均表现为灌丛地>草地>林地，呈中度至强度变异（0.07~0.28之间）。（2）不同林草植被下旱、雨季土壤水分具有相似的空间自相关性，自相关系数均由正向负转变，但由正向负转变的滞后距离有所不同，且雨季大于旱季，呈中等或强等空间自相关性。（3）不同林草植被下的土壤水分空间结构不同，林地、灌丛地和草地旱雨季最佳拟合模型均为球状模型；相同林草植被下各土层旱、雨季土壤水分的空间分布特征相似，但旱季的分布格局差异更显著，不同林草植被下深层土壤水分分布比表层土壤水分的分布更为复杂，土壤水分呈明显的斑块或条带状分布，含水量高值区和低值区位置不固定。总之不同林草植被类型会改变局部地段土壤水分空间分布，降雨会加强这种差异的趋势，但土壤水分仍具一定空间连续性。  相似文献   

2000-2015年柴达木盆地植被覆盖度时空变化及其与环境因子的关系          下载免费PDF全文

张斯琦  陈辉  宋明华  付阳  牛慧慧  杨祎  张博雄 《干旱区地理》2019,42(5):1124-1132

基于MODIS-NDVI、DEM和气象数据，分析柴达木盆地2000—2015年植被覆盖度（FVC）时空变化特征，并与降水、温度、日照时数、相对湿度、蒸散量和海拔进行相关、偏相关或叠加分析，探讨FVC与各环境因子的关系。结果表明：FVC整体自东南向西北内陆呈半环状递减，FVC集中在20%以下，人类活动及径流等打破植被地带性规律；2000—2015年FVC明显改善，广泛分布于盆地中西部地区，2001—2002年年际变化最显著；FVC与降水、相对湿度以正相关为主，与温度关系不显著，与日照时数和蒸散量主要为负相关，降水对FVC贡献最大，温度通过影响蒸散量等间接影响FVC，而土壤蒸发对蒸散量的影响大于植物蒸腾；FVC与等高线空间分布较吻合，FVC在2 800~2 900 m和4 600~4 700 m出现两个峰值，4 700 m以上FVC迅速降低。  相似文献   

2001-2015年中国植被覆盖人为影响的时空格局   总被引：3，自引：0，他引：3  

王建邦  赵军  李传华  朱钰  康重阳  高超 《地理学报》2019,74(3):504-519

基于MODIS-NDVI和气温、降水数据,使用基于变异系数的人为影响模型定量计算了2001-2015年中国植被覆盖人为影响,辅以趋势分析、Hurst指数等方法探讨了中国植被覆盖人为影响的时空变化特征及未来演变趋势。研究发现：① 2001-2015年,中国植被覆盖人为影响由南向北空间分异愈发明显,年均值为-0.0102,植被覆盖在人类活动影响下轻微减少,负影响面积占51.59%,略大于正影响面积。② 中国植被覆盖人为影响年际变化特征明显,整体呈负影响波动减少趋势,降速为0.5%/10a,其中正影响、负影响均呈增大趋势,正影响增速（0.3%/10a）远大于负影响（0.02%/10a）。③ 2001-2015年间,中国植被覆盖人为正影响重心向东北方向移动,负影响重心向西南方向移动,东北部植被覆盖在人为影响下不断改善,西南部人类活动对植被破坏程度不断增大。④ 中国植被覆盖人为影响主要呈负影响减少和正影响增大趋势,面积占比分别为28.14%和25.21%,生态环境趋于改善。⑤ Hurst指数分析表明,中国植被覆盖人为影响未来演变趋势的反向特征强于正向特征,主要呈人为负影响先减少后增大趋势,面积占比15.59%。  相似文献   

Nine thousand years of upper montane soil/vegetation dynamics from the summit of Caratuva Peak,Southern Brazil     

《Journal of South American Earth Sciences》2014

Biodiversity loss, climate change, and increased freshwater consumption are some of the main environmental problems on Earth. Mountain ecosystems can reduce these threats by providing several positive influences, such as the maintenance of biodiversity, water regulation, and carbon storage, amongst others. The knowledge of the history of these environments and their response to climate change is very important for management, conservation, and environmental monitoring programs. The genesis of the soil organic matter of the current upper montane vegetation remains unclear and seems to be quite variable depending on location. Some upper montane sites in the very extensive coastal Sea Mountain Range present considerable organic matter from the late Pleistocene and other from only the Holocene. Our study was carried out on three soil profiles (two cores in grassland and one in forest) on the Caratuva Peak of the Serra do Ibitiraquire (a sub-range of Sea Mountain Range – Serra do Mar) in Southern Brazil. The δ¹³C isotopic analyses of organic matter in soil horizons were conducted to detect whether C₃ or C₄ plants dominated the past communities. Complementarily, we performed a pollen analysis and ¹⁴C dating of the humin fraction to obtain the age of the studied horizons. Except for a short and probably drier period (between 6000 and 4500 cal yr BP), C₃ plants, including ombrophilous grasses and trees, have dominated the highlands of the Caratuva Peak (Pico Caratuva), as well as the other uppermost summits of the Serra do Ibitiraquire, since around 9000 cal yr BP. The Caratuva region represents a landscape of high altitude grasslands (campos de altitude altomontanos or campos altomontanos) and upper montane rain/cloud forests with soils that most likely contain some organic matter from the late Pleistocene, as has been reported in Southern and Southeastern Brazil for other sites. However, our results indicate that the studied deposits (near the summit) are from the early to late Holocene, when somewhat wetter and warmer conditions (since around 9000 cal yr BP) enabled a stronger colonization of the ridge of Pico Caratuva by mainly C₃ plants, especially grassland species. However, at the same time, even near the summit, the soil core from the forest site already presented the current physiognomy (or a shrubby/elfin or successional forest), indicating that the colonization of the neighboring uppermost saddles and valleys were probably populated mainly by upper montane forest species.  相似文献   

Greenness Index from Phenocams Performs Well in Linking Climatic Factors and Monitoring Grass Phenology in a Temperate Prairie Ecosystem     

ZHOU Yuke 《资源与生态学报(英文版)》2019,10(5):481-493

Near-surface remote sensing (e.g., digital cameras) has played an important role in capturing plant phenological metrics at either a focal or landscape scale. Exploring the relationship of the digital image-based greenness index (e.g., Gcc, green chromatic coordinate) with that derived from satellites is critical for land surface process research. Moreover, our understanding of how well Gcc time series associate with environmental variables at field stations in North American prairies remains limited. This paper investigated the response of grass Gcc to daily environmental factors in 2018, such as soil moisture (temperature), air temperature, and solar radiation. Thereafter, using a derivative-based phenology extraction method, we evaluated the correspondence between key phenological events (mainly including start, end and length of growing season, and date with maximum greenness value) derived from Gcc, MODIS and VIIRS NDVI (EVI) for the period 2015-2018. The results showed that daily Gcc was in good agreement with ground-level environmental variables. Additionally, multivariate regression analysis identified that the grass growth in the study area was mainly affected by soil temperature and solar radiation, but not by air temperature. High frequency Gcc time series can respond immediately to precipitation events. In the same year, the phenological metrics retrieved from digital cameras and multiple satellites are similar, with spring phenology having a larger relative difference. There are distinct divergences between changing rates in the greenup and senescence stages. Gcc also shows a close relationship with growing degree days (GDD) derived from air temperature. This study evaluated the performance of a digital camera for monitoring vegetation phenological metrics and related climatic factors. This research will enable multiscale modeling of plant phenology and grassland resource management of temperate prairie ecosystems.  相似文献   

Vegetation history of the penultimate glacial period (Marine isotope stage 6) at Ioannina,north‐west Greece     

K. H. Roucoux  P. C. Tzedakis  I. T. Lawson  V. Margari 《第四纪科学杂志》2011,26(6):616-626

The vegetational history of the penultimate glacial period, Marine Isotope Stage (MIS) 6 (c. 185–135 ka), has remained relatively unexplored. Here we present a new record from the Ioannina basin, north‐west Greece, which constitutes the highest‐resolution terrestrial pollen record for this interval produced to date. It shows that the vegetation history of MIS 6 in this region can be divided into two parts: an early period (185–155 ka) with pronounced oscillations in tree population extent, and a later period (155–135 ka) with much smaller tree populations and subdued oscillations. This pattern is analogous to the MIS 3/MIS 2 division during the last glacial in the same sequence, although the early part of MIS 6 had larger Pinus populations and fewer temperate trees relative to the equivalent interval in MIS 3. This implies cooler and wetter conditions, which is somewhat counterintuitive given the high summer insolation during MIS 6e, but is in line with other palaeoclimatic evidence from the Mediterranean. Comparison with North Atlantic records suggests that despite the absence of pronounced iceberg discharges during MIS 6, North Atlantic millennial‐scale variability had a significant downstream impact on tree populations in north‐west Greece. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献