An experimental study of the grain-scale processes of peridotite melting: implications for major and trace element distribution during equilibrium and disequilibrium melting   总被引：1，自引：0，他引：1  

Mauro Lo Cascio  Yan Liang  Nobumichi Shimizu  Paul C. Hess 《Contributions to Mineralogy and Petrology》2008,156(1):87-102

The grain-scale processes of peridotite melting were examined at 1,340°C and 1.5 GPa using reaction couples formed by juxtaposing pre-synthesized clinopyroxenite against pre-synthesized orthopyroxenite or harzburgite in graphite and platinum-lined molybdenum capsules. Reaction between the clinopyroxene and orthopyroxene-rich aggregates produces a melt-enriched, orthopyroxene-free, olivine + clinopyroxene reactive boundary layer. Major and trace element abundance in clinopyroxene vary systematically across the reactive boundary layer with compositional trends similar to the published clinopyroxene core-to-rim compositional variations in the bulk lherzolite partial melting studies conducted at similar P–T conditions. The growth of the reactive boundary layer takes place at the expense of the orthopyroxenite or harzburgite and is consistent with grain-scale processes that involve dissolution, precipitation, reprecipitation, and diffusive exchange between the interstitial melt and surrounding crystals. An important consequence of dissolution–reprecipitation during crystal-melt interaction is the dramatic decrease in diffusive reequilibration time between coexisting minerals and melt. This effect is especially important for high charged, slow diffusing cations during peridotite melting and melt-rock reaction. Apparent clinopyroxene-melt partition coefficients for REE, Sr, Y, Ti, and Zr, measured from reprecipitated clinopyroxene and coexisting melt in the reactive boundary layer, approach their equilibrium values reported in the literature. Disequilibrium melting models based on volume diffusion in solid limited mechanism are likely to significantly underestimate the rates at which major and trace elements in residual minerals reequilibrate with their surrounding melt. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

Depths of Partial Crystallization of H2O-bearing MORB: Phase Equilibria Simulations of Basalts at the MAR near Ascension Island (7 11{degrees}S)     

Almeev  Renat; Holtz  Francois; Koepke  Jurgen; Haase  Karsten; Devey  Colin 《Journal of Petrology》2008,49(1):25-45

Phase equilibria simulations were performed on naturally quenchedbasaltic glasses to determine crystallization conditions priorto eruption of magmas at the Mid-Atlantic Ridge (MAR) east ofAscension Island (7–11°S). The results indicate thatmid-ocean ridge basalt (MORB) magmas beneath different segmentsof the MAR have crystallized over a wide range of pressures(100–900 MPa). However, each segment seems to have a specificcrystallization history. Nearly isobaric crystallization conditions(100–300 MPa) were obtained for the geochemically enrichedMORB magmas of the central segments, whereas normal (N)-MORBmagmas of the bounding segments are characterized by polybariccrystallization conditions (200–900 MPa). In addition,our results demonstrate close to anhydrous crystallization conditionsof N-MORBs, whereas geochemically enriched MORBs were successfullymodeled in the presence of 0·4–1 wt% H₂O in theparental melts. These estimates are in agreement with direct(Fourier transform IR) measurements of H₂O abundances in basalticglasses and melt inclusions for selected samples. Water contentsdetermined in the parental melts are in the range 0·04–0·09and 0·30–0·55 wt% H₂O for depleted and enrichedMORBs, respectively. Our results are in general agreement (within±200 MPa) with previous approaches used to evaluate pressureestimates in MORB. However, the determination of pre-eruptiveconditions of MORBs, including temperature and water contentin addition to pressure, requires the improvement of magma crystallizationmodels to simulate liquid lines of descent in the presence ofsmall amounts of water. KEY WORDS: MORB; Mid-Atlantic Ridge; depth of crystallization; water abundances; phase equilibria calculations; cotectic crystallization; pressure estimates; polybaric fractionation  相似文献   

A neutron diffraction study of alkali cation migration in montmorillonites     

D. Gournis  A. Lappas  M. A. Karakassides  D. Többens  A. Moukarika 《Physics and Chemistry of Minerals》2008,35(1):49-58

Neutron powder diffraction measurements on lithium and cesium saturated montmorillonite samples before and after heat treatment at 300°C are studied, in order to undertake a complete refinement of crystal structure and unravel the migration mechanism for the interlayer cations of Li or Cs. Rietveld analysis of the corresponding diffraction patterns finds that montmorillonite crystallizes in the C2/m space group with unit cell dimensions consistent with the size of the specific interlayer cation. We show that thermal treatment affects the two types of samples in a different way. This is with respect to their unit cell dimensions and the migration of Li from the 2b to the 2c clay lattice site, in constrast to the Cs positioning which remains effectively unchanged.  相似文献   

陆面过程中稳定水同位素逐日变化的数学模拟——引入稳定同位素效应的CLM实例分析     

章新平  王晓云  牛国跃  杨宗良  黄一民  张剑明 《冰川冻土》2008,30(1):100-107

将稳定同位素效应引入CLM(Community Land Model),并对巴西马瑙斯站在平衡年的稳定水同位素的逐日变化进行模拟和分析.结果表明: 降水、水汽和地表径流中δ18O存在明显的季节变化,并与相应的水量存在显著的负相关关系,但凝结物中δ18O与地面凝结量存在显著的正相关关系,蒸发水汽中δ18O与蒸发量之间无显著的相关关系.受土壤贮水削峰功能的影响,表层土壤和根区水中δ18O的季节变化全无.植被层蒸发水汽中稳定同位素的丰度与大气的干湿程度存在密切联系: 当降水量少时,大气干燥,植被层的蒸发较少,植被蒸发中δ18O较高;当降水量较大时,空气湿润,植被层的蒸发量较大,蒸发中δ18O则较低.植被蒸腾中δ18O的变化与源区水体中δ18O的变化保持一致,尤其是与根区水中的δ18O.由于地下径流直接源自根区水的补充,因此,地下径流中δ18O等于根区水中的δ18O.模拟结果还显示,降水MWL (大气水线)的梯度项和常数项均比全球平均MWL略偏小.尽管主要来自降水的贡献,但地表径流和植被层水体的MWLs与降水MWL存在较大的差异,这一方面与两类水体在蒸发过程中的稳定同位素的富集作用有关,另一方面与CLM模拟的水量有关.大气水汽线与降水的MWL的梯度值相近,说明大气水汽与降水近似处于稳定同位素平衡状态.另外,模拟的地面的凝结线与植被层的凝结线均与全球大气水线相近,且具有非常高相关程度,说明CLM的模拟是合理的.  相似文献   

三肇凹陷青山口组源岩生成油向下“倒灌”运移层位及其研究意义   总被引：14，自引：1，他引：13  

付广  王有功 《沉积学报》2008,26(2):355-360

为了研究三肇凹陷青山口组源岩生成的油向下“倒灌”运移层位,对油向下“倒灌”运移机制及条件进行了研究,得到三肇凹陷扶杨油层同时具备①青山口组源岩目前应具有足够大的超压;②存在连通青山口组源岩和扶杨油层的T2断裂2个条件,青山口组源岩生成的油能够在超压的作用下在嫩江组沉积末期、明水组沉积末期和古近系沉积末期通过T2断裂向下伏扶杨油层中“倒灌”运移。利用压力封闭原理,对三肇凹陷青山口组源岩生成的油向下“倒灌”运移距离进行了研究,得到三肇凹陷青山口组源岩生成的油向下“倒灌”运移距离一般大于500 m,而三肇凹陷扶杨油层地层厚度最大只有500 m,表明三肇凹陷青山口组源岩生成的油可以向下“倒灌”运移至整个扶杨油层的任何部位。目前三肇凹陷扶杨油层从上至下均含油,且已找到的油藏均分布于青山口组源岩生成的油能够向下“倒灌”运移分布范围内或附近,这表明青山口组源岩生成的油向下“倒灌”运移层位控制着油气富集层位,青山口组源岩生成的油向下“倒灌”运移分布范围控制着三肇凹陷扶杨油层油藏形成与分布范围。青山口组源岩生成的油向下“倒灌”运移分布范围及其附近应是三肇凹陷扶杨油层油下一步勘探的有利地区。  相似文献   

Mo稳定同位素研究进展     

张羽旭  温汉捷  樊海峰 《岩石矿物学杂志》2008,27(5):457-464

随着表面热离子质谱(TIMS)和多接收器电感耦合等离子体质谱(MC-ICP-MS)的广泛应用以及同位素分析方法的改进,近10年来非传统稳定同位素(Cu、Zn、Fe、Se、Mo、Cr、Hg等)的研究得到迅速发展.其中,由于Mo同位素的分馏明显受氧化还原条件的控制,使其在指示古环境及古气候的变化方面有独特的地球化学指示意义.同时,Mo同位素在指示成矿物质来源和海洋Mo循环等方面也取得较大成果.因此,Mo同位素地球化学研究已成为国际地学领域的一个前沿和热点.本文综合前人的研究成果,结合近期自己的工作,论述了Mo同位素地球化学研究领域的一些重要进展,详细介绍了Mo同位素的化学分离、提纯和质谱分析技术,并对其应用前景进行了展望.  相似文献   

绿片岩-低角闪岩相变质条件下磁铁铁矿与黄铁矿间的Fe同位素分馏   总被引：3，自引：0，他引：3  

李志红  朱祥坤  唐索寒  李延河 《岩石矿物学杂志》2008,27(4):292-297

对辽宁省鞍山一本溪地区经历了绿片岩一低角闪岩相变质的新太古代条带状铁建造中磁铁矿和黄铁矿矿物对的Fe同位素分析结果显示:相对于标准IRMM-014,所有样品的磁铁矿和黄铁矿均显示Fe的重同位素富集;且黄铁矿的Fe同位素比值均大于磁铁矿的Fe同位素比值(ε57Fe黄铁矿ε57Fe磁铁矿),两种矿物的Fe同位素比值之差为△57Fe黄铁矿-磁铁矿=2.23～5.13.黄铁矿富集铁的重同位素表明矿物的Fe同位素组成并不代表其原始沉积的特征,而是在区域变质作用过程中Fe同位素发生了交换的结果.由同位素平衡判别图解可知,在绿片岩一低角闪岩相变质作用中,磁铁矿-黄铁矿间的Fe同位素基本达到了平衡,且在平衡条件下黄铁矿比磁铁矿更富集Fe的重同位素,二者之间的Fe同位素平衡分馏系数α黄铁矿-磁铁矿≈1.000 4‰±0.06‰(2σ).这一研究成果是对变质作用过程中Fe同位素的地球化学行为认识的重要进展.  相似文献   

Transplantation-tagging-experiments in preliminary studies of migration of cod off Norway   总被引：1，自引：2，他引：1  

Godo  Olav Rune 《ICES Journal of Marine Science》1995,52(6):955-962

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Fluid flow equations governing primary oil migration as a separate phase     

Ismail Ozkaya 《Marine and Petroleum Geology》1989,6(4)

A mathematical model of primary oil migration as a separate phase out of compacting shales is presented. During burial and oil generation, source rock porosity decreases and oil saturation increases until residual oil saturation is reached. At this stage oil is expelled out by capillary and excess fluid pressure gradients. The model is a system of differential equations which relate changes in oil and water saturation in time to water and oil flow out of the source rock during burial. An additional set of equations for periods of erosion of overburden are also provided. The equations can be numerically solved by finite difference method. If oil and water flow is to be simulated during oil generation, then at each time step, changes by oil generation in oil and water saturations and porosity must be calculated. The solution procedure is briefly outlined.  相似文献   

A computer simulation model for predicting rates and scales of movement of demersal fish on the European continental shelf   总被引：1，自引：1，他引：1  

Arnold  G. P.; Holford  B. H. 《ICES Journal of Marine Science》1995,52(6):981-990

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