甲醛标准储备液浓度的不确定度评定     

陈志清  辛运菊  梅祖明 《岩矿测试》2008,27(1):45-48

讨论了影响甲醛标准溶液浓度标定值不确定的各种因素,并评定了甲醛标准溶液浓度标定值的不确定度。当甲醛标准溶液浓度为1058 mg/L时,它的相对标准不确定度为0.70%(K=2)。  相似文献   

气相色谱法测定地下水中六六六结果的不确定度评定   总被引：7，自引：4，他引：3  

李松  饶竹 《岩矿测试》2008,27(4):295-298

依照《测量不确定度评定与表示》,对气相色谱法测定地下水中六六六(HCH)四种单体结果进行了不确定度评定。分析了测量过程中引入的不确定度来源,包括提取液体积的量取、样品提取溶液的定容体积、分析仪器的进样量、标准系列溶液的测量以及仪器重复测定等分量引入不确定度及其各参数的采集和计算方法,最后合成标准不确定度,通过乘以95%概率下的扩展因子2,获得测量结果的扩展不确定度。  相似文献   

火试金法测定铜精矿中金含量结果的不确定度评定   总被引：2，自引：0，他引：2  

江水英  肖化云  吴声东  吴波  秦云和 《岩矿测试》2008,27(4):299-301

对火试金法测定铜精矿中金含量的结果进行不确定度评定。分析了铜精矿样品称量、铜精矿样品的不均匀性和配料处理,以及金粒称量等因素对金含量测量结果不确定度的影响,并得出火试金法测量铜精矿中金含量的扩展不确定度。  相似文献   

碱消解-高效液相色谱-电感耦合等离子体质谱法测定生物样品中的甲基汞和乙基汞   总被引：7，自引：2，他引：5  

杨红霞  刘崴  李冰 《岩矿测试》2008,27(6):405-408

建立了碱消解-高效液相色谱-电感耦合等离子体质谱联用系统测定生物样品中甲基汞(MeHg)与乙基汞(EtHg)的分析方法。为提高灵敏度,选用微流量的PFA雾化器,在优化的检测条件下,MeHg及EtHg检出限可达到0.036μg/L和0.03μg/L;线性范围达到4个数量级,两条工作曲线线性相关系数为1。对1.78μg/L MeHg、1.65μg/L EtHg的混合标准溶液重复测定7次,色谱峰面积的相对标准偏差(RSD)分别为1.79%和1.44%。对标准物质BCR 464(金枪鱼)的分析结果表明,测定值与标准值基本吻合,但略低于标准值;甲基汞和乙基汞的加标回收率分别为85.9%和84.5%。高效液相色谱与质谱联用技术的高灵敏度和低检出限能够满足生物样品中汞形态定量分析的要求。  相似文献   

Neural network prediction of nitrate in groundwater of Harran Plain, Turkey   总被引：2，自引：0，他引：2  

M. Irfan Yesilnacar  Erkan Sahinkaya  Muhsin Naz  Bestamin Ozkaya 《Environmental Geology》2008,56(1):19-25

Monitoring groundwater quality by cost-effective techniques is important as the aquifers are vulnerable to contamination from the uncontrolled discharge of sewage, agricultural and industrial activities. Faulty planning and mismanagement of irrigation schemes are the principle reasons of groundwater quality deterioration. This study presents an artificial neural network (ANN) model predicting concentration of nitrate, the most common pollutant in shallow aquifers, in groundwater of Harran Plain. The samples from 24 observation wells were monthly analysed for 1 year. Nitrate was found in almost all groundwater samples to be significantly above the maximum allowable concentration of 50 mg/L, probably due to the excessive use of artificial fertilizers in intensive agricultural activities. Easily measurable parameters such as temperature, electrical conductivity, groundwater level and pH were used as input parameters in the ANN-based nitrate prediction. The best back-propagation (BP) algorithm and neuron numbers were determined for optimization of the model architecture. The Levenberg–Marquardt algorithm was selected as the best of 12 BP algorithms and optimal neuron number was determined as 25. The model tracked the experimental data very closely (R = 0.93). Hence, it is possible to manage groundwater resources in a more cost-effective and easier way with the proposed model application.  相似文献   

Numerical estimation of REV and permeability tensor for fractured rock masses by composite element method   总被引：2，自引：0，他引：2  

S.‐H. Chen  X.‐M. Feng  S. Isam 《国际地质力学数值与分析法杂志》2008,32(12):1459-1477

The Monte Carlo method is used to generate parent stochastic discrete fracture network, from which a series of fractured rock samples of different sizes and orientations are extracted. The fracture network combined with a regular grid forms composite element mesh of the fractured rock sample, in which each composite element is composed of sub‐elements incised by fracture segments. The composite element method (CEM) for the seepage is implemented to obtain the nodal hydraulic potential as well as the seepage flow rates through the fractured rock samples. The application of CEM enables a large quantity of stochastic tests for the fractured rock samples because the pre‐process is facilitated greatly. By changing the sizes and orientations of the samples, the analysis of the seepage characteristics is realized to evaluate the variation of the permeability components, the existence of the permeability tensor and the representative element volume. The feasibility and effectiveness are illustrated in a numerical example. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

矿物数字博物馆的建设构想与实现     

周燕  朱杰勇  王雷 《岩石矿物学杂志》2008,27(1):81-86

在基于互联网的应用、信息数字化、多种技术发展较为成熟及适应公众需求的基础上,对矿物数字博物馆的建设做了简要的分析,将矿物按矿物一结晶学分类方案将馆藏矿物进行合理的分类,设计了七大功能结构和相应的子结构,并对矿物所要展示的内容设定了标准.建设矿物数字博物馆旨在利用三维技术、多媒体技术、文字信息等,将矿物从宏观的外形到抽象的晶体形态和微观的晶体结构及其最小单位结构通过网络的形式具体展现给观众.矿物数字博物馆的建设可以为人们认知整个矿物世界搭建一个良好的平台,在科研教学、推动国民科学普及教育、培养创新人才方面发挥重要作用.  相似文献   

钢筋混凝土梁结构断裂损伤诊断方法     

周尚志  王丽华刘瑛 《海洋工程》2005,23(4):47-51

提出一种基于BP神经网络的结构破损诊断方法,该方法以结构破损前后柔度的变化作为破损诊断网络输入,为了解决由于系统响应样本数据空间分布不均匀对网络收敛速度及网络诊断影响问题,对网络训练样本采用广义空间格点进行了交换,模拟算例及应用实例均表明,本文方法能准确诊断结构破损位置与破坏程度,是一种有效的结构破损诊断方法.  相似文献   

Modeling of Multi-Freedom Ship Motions in Irregular Waves with Fuzzy Neural Networks     

余建星  陆培毅  高喜峰  夏锦祝 《中国海洋工程》2003,17(2)

1 .IntroductionAshiptravelingatseaundergoesundesirablewave inducedmotions ,namely ,surge ,sway ,heav ing ,rolling ,pitchingandyaw .Thesemotionsoftencauseproblemstothecrew ,theonboardequip mentand ,intheworstcase ,thesafetyofthevessel.Tominimizethewave inducedshipmotions ,controlsystemsmaybeapplied .Theaccuratemodelingofshipmotionsisthereforeveryimportantforshipdesignanddesignofmotioncontrolsystems .Manyresearchershavedevelopedshipmotionpredictionmethodsbasedonthepotentialflowtheo ries (Dong ,…  相似文献   

Neural Network-Based Active Control for Offshore Platforms     

周亚军  赵德有 《中国海洋工程》2003,17(3)

1 .IntroductionWiththedevelopmentofoceantechnology ,moreandmoreextremelylargeandlongflexibleoff shoreplatformsusedforoilexplorationanddrillingoperationarebuiltinhostileoceanenvironments .Ingeneral,thiskindofplatformsisanonlineardistributedparametersystemanditsnaturalfrequencyfallsclosertothedominantwavefrequencieswiththeincreaseofwaterdepth .Besides ,itsstructureisverycomplexandtheexternalwaveforceontheplatformisuncertain .Thus ,theseplatformsarepronetoexcessivewave inducedoscillationsunderbot…  相似文献