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31.
游离氧化铁形态转化对红粘土工程性质的影响 总被引:6,自引:5,他引:6
本文通过模拟环境中的有机质使游离氧化铁形态转化对典型红粘土工程性质的影响试验,系统地测试了游离氧化铁的形态分布与物性指标的关系。试验结果表明,在渍水条件下,游离氧化铁的形态转化对红粘土性质的影响不显著,但在渗水条件下,由于游离氧化铁的流失使得胶结作用减弱,它对红粘土工程性质的影响逐渐明显,其潜在的危害仍然是不容忽视的。 相似文献
32.
Measurements of nitrous oxide emission from agricultural lands were conducted. The results show that nitrous oxide fluxes on several soils are at the range of 2-60 μg . N / m2 h. Factors influencing the production rates of nitrous oxide from the soils, such as soil temperature, soil moisture and fertilization, are discussed. The calculated amount of nitrous oxide emission from China farmlands is 9.8 × 107 Kg . N per year, which accounts for about 10% of the total source strength in China areas. 相似文献
33.
以岷江冲积物、黄壤残积物发育成的水稻土为对照,研究了紫色砂岩泥岩母质发育成的紫色水稻土氧化铁的形态及其含量和转化。揭示了紫色水稻土具有无定形铁含量,铁活化度较高,氧化铁的转化作用较弱等独特的发生特性。 相似文献
34.
由MgMn_2O_4制备新型离子筛吸附剂及其对锂的吸附性质 总被引:1,自引:0,他引:1
从Mg、Mn混合溶液制备了镁锰氧化物MgMn_2O_4,并由此制得新型离子筛氧化锰HMnO(Mg)。它在碱金属及碱土金属离子中对Li~+显示了很高的选择性,pH8时分配系数Kd值顺序为Li>>Ca>Mg>K>Na,可以从实际卤水中将Li~+选择性吸附,吸附容量达20.4mg/g,用稀HCI溶液易于将吸附的Lj~+洗脱并使吸附剂再生。经用卤水和HCI五次吸附——洗脱循环,Li~+吸附容量没有降低,洗脱率总是大于90%。 相似文献
35.
Trace gas measurements during aircraft flights in the tropopause region over Europe and North Africa
M. Schmidt R. Borchers P. Fabian G. Flentje W. A. Matthews A. Szabo S. Lal 《Journal of Atmospheric Chemistry》1984,2(2):133-143
During aircraft flights in May 1981 from Munich (40°N) to north of the Spitsbergen Islands (82°N) and to Monrovia, Liberia (6°N), air samples were obtained in the altitude range of 8 to 11 km and during the ascents and descents near the airports. These samples have been analyzed for the trace gas mixing ratios of CH4, CO and N2O. The results of these analyses are presented and discussed.The results provide new evidence of tropospheric-stratospheric exchange events in the vicinity of the subpolar and subtropical tropopause foldings and possibly show a case of transport of CO-enriched air in the upper troposphere above the North Atlantic Ocean. 相似文献
36.
To understand the oxidation state and process of oxidation of lava domes, we carried out magnetic petrological analyses of lava samples obtained from domes and block-and-ash-flow deposits associated with the 1991–1995 eruption of Unzen volcano, Japan. As a result, we recognize three different types of magnetic petrology, each related to deuteric high-temperature oxidation during initial cooling. Type A oxides are characterized by homogenous titanomagnetite and titanohematite, indicating a low oxidation state and high titanomagnetite concentrations. Type B oxides are weakly exsolved and contain titanohematite laths and rutile lenses, indicating a higher oxidation state. Type C oxides, which represent the highest oxidation state, are completely exsolved and composed of Ti-poor titanomagnetite, titanohematite, rutile, and pseudobrookite, indicating high hematite concentrations. Some grains in Types A and B show indications of reduction, which was related to interaction with volcanic gases subsequent to high-temperature oxidation. In terms of geological occurrence, the oxidation processes probably differed for endogenous and exogenous domes. Endogenous dome lavas are oxidized concentrically and are classified into the three types according to their location within the dome: samples from the surface are strongly oxidized and classified as Type C, while the inner part is unoxidized and classified as Type A. Exogenous dome lavas are unoxidized and assigned to Type A. Some samples show signs of reduction, which may have occurred around fumaroles. We propose that location within the dome and the process of dome growth are the factors that control oxidation. 相似文献
37.
太白山土壤特性及氧化铁发生学特征 总被引:16,自引:1,他引:16
随海拔的降低,秦岭北坡中山区森林土壤因温度、降水和植被类型的变化存在很大差异:高海拔地区发育的酸性湿润雏形土酸度较高,有机质含量十分丰富;与之相比,低海拔地区发育的简育湿润淋溶土有机质含量下降,但结构复杂,土壤具有粘化层。较高的有机质含量和特殊的有机质组成促进了纯针叶林土壤中硅酸盐矿物的溶解,释放出氧化铁并使之螯迁至土壤B层富集。环境因素决定了土壤酸度、有机质等特性,也影响土壤氧化铁的组成和分布。土壤粘粒含量与土体游离氧化铁含量显著相关,剖面铁的游离度与氧化铁全量无关,只与土壤发育程度有关。太白山北坡中山区土壤处于脱盐基富硅铝化的风化发育阶段 相似文献
38.
富钴结壳生长过程中铁锰氧化物矿物组合的变化 总被引:3,自引:0,他引:3
富钴结壳的矿物学研究是一个难点,本文运用电子探针微区分析结合X射线衍射和矿相显微镜观察的综合方法对富钴结壳中的铁锰氧化物矿物组合及其组分变化进行了研究,研究发现,富钴结壳是从与胶状粘土类混合共沉积开始生长的,结壳内部的韵律层和柱状构造也是始于粘土层终于粘土层的;铁锰团粒的核心一般是较纯的水羟凶国矿小核心,可能是在生物媒介作用下在水体中形成后沉降叠积的,FM、FPE海山结壳的中层存在一较纯水羟锰矿层,但该层中Co含量FM15比FPE06低得多,可能反映了FM15在该层形成时Co通量较低,而该层在FN12中不存在,反映了区域环境的较大差异,在FN12火焰状构造亚带存在Mn氧化物和Fe氧化物的极度分异现象,可能反映了结壳形成环境的重大变化。 相似文献
39.
Surface NO and NO2 mixing ratios were measured aboard the research vessel Polarstern during the mission ANT VII/1 from 24 September to 5 October 1988. The measurements were taken along the meridian at 30° W in the Atlantic region covering latitudes between 30° N and 30° S. The average mixing ratios were about 12 pptv NO/30 pptv NO2 in the Northern Hemisphere and about 7 pptv NO/22 pptv NO2 in the Southern. Elevated mixing ratios of 20 pptv NO/70 pptv NO2 were found at 12° N (probably due to air masses originating from the surface of West Africa) and in the region of the ITCZ between 8° N and 5° N. Because of probable contamination by the ship, the measured mixing ratios mostly represent upper limits. 相似文献
40.
全球冻融地区土壤是重要的N20释放源的综合分析 总被引:3,自引:0,他引:3
N2O是重要的温室气体之一,它是微生物硝化作用和脱氮化作用过程的产物。有多种释放源,其中土壤圈是重要的释放源之一。在影响N2O释放通量的诸多因素中温度是关键因素之一。本文根据土壤冻融加强有机质矿化作用,以及对微生物群体产生非生物应力的性质,结合冻融地区土壤和冻土带湿地所具有的特征,进行综合分析,论述冻融地区土壤是重要的N2O释放源。 相似文献