http://www.sciencedirect.com/science/article/pii/S1674987113000595   总被引：11，自引：0，他引：11  

Mei-Fu Zhou  Wei Terry Chen  Christina Yan Wang  Stephen A.Prevec  Patricia Pingping Liu  Geoffrey H.Howarth 《地学前缘(英文版)》2013,4(5):481-502

Magmatic oxide deposits in the～260 Ma Emeishan Large Igneous Province(ELIP),SW China and northern Vietnam,are important sources of Fe,Ti and V.Some giant magmatic Fe-Ti-V oxide deposits, such as the Panzhihua,Hongge,and Baima deposits,are well described in the literature and are hosted in layered mafic-ultramafic intrusions in the Panxi region,the central ELIP.The same type of ELIP- related deposits also occur far to the south and include the Anyi deposit,about 130 km south of Panzhihua,and the Mianhuadi deposit in the Red River fault zone.The Anyi deposit is relatively small but is similarly hosted in a layered mafic intrusion.The Mianhuadi deposit has a zircon U-Pb age of～260 Ma and is thus contemporaneous with the ELIP.This deposit was variably metamorphosed during the Indosinian orogeny and Red River faulting.Compositionally,magnetite of the Mianhuadi deposit contains smaller amounts of Ti and V than that of the other deposits,possibly attributable to the later metamorphism.The distribution of the oxide ore deposits is not related to the domal structure of the ELIP.One major feature of all the oxide deposits in the ELIP is the spatial association of oxide-bearing gabbroic intrusions,syenitic plutons and high-Ti flood basalts.Thus,we propose that magmas from a mantle plume were emplaced into a shallow magma chamber where they were evolved into a field of liquid immiscibility to form two silicate liquids,one with an extremely Fe-Ti-rich gabbroic composition and the other syenitic.An immiscible Fe-Ti-(P) oxide melt may then separate from the mafic magmas to form oxide deposits.The parental magmas from which these deposits formed were likely Fe-Ti-rich picritic in composition and were derived from enriched asthenospheric mantle at a greater depth than the magmas that produced sulfide-bearing intrusions of the ELIP.  相似文献   

Hydration vs. oxidation: Modelling implications for Fe–Ti oxide crystallisation in mafic intrusions, with specific reference to the Panzhihua intrusion, SW China     

Geoffrey H.Howarth  Stephen A.Prevec 《地学前缘(英文版)》2013,4(5):555-569

Recent work on the Panzhihua intrusion has produced two separate models for the crystallisation of the intrusion:（1） low-Ti,high CaO and low H₂O（0.5 wt.%） parent magma（equivalent to Emeishan low-Ti basalt） at FMQ;and（2） high-Ti,low CaO and higher H₂O（>1.5 wt.%） parent magma（equivalent to Emeishan high-Ti basalt） at FMQ + 1.5.Modelling of these parent magma compositions produces significantly different results. We present here detailed f（O₂） and H₂O modelling for average compositions of both Emeishan high-Ti and low-Ti ferrobasalts in order to constrain the effects on crystallisation sequences for Emeishan ultra-mafic -mafic layered intrusions.Modelling is consistent with numerous experimental studies on ferro-basaltic magmas from other localities（e.g.Skaergaard intrusion）.Modelling is compared with the geology of the Panzhihua intrusion in order to constrain the crystallisation of the gabbroic rocks and the Fe-Ti oxides ore layers.We suggest that the gabbroic rocks at the Panzhihua intrusion can be best explained by crystallisation from a parent magma similar to that of the high-Ti Emeishan basalt at moderate H₂O contents（0.5-1 wt.%） but at the lower end of TiO₂ content for typical high-Ti basalts（2.5 wt.%TiO₂）. Distinct silicate disequilibrium textures in the Fe-Ti oxide ore layers suggest that an influx of H₂O may be responsible for changing the crystallisation path.An increase in H₂O during crystallisation of gabbroic rocks will result in the depression of silicate liquidus temperatures and resultant disequilibrium with the liquid.Continued cooling of the magma with high H₂O then results in precipitation of Mt-Uv alone. The H₂O content of parent magmas for mafic layered intrusions associated with the ELIP is an important variable.H₂O alters the crystallisation sequence of the basaltic magmas so that at high H₂O and f（O₂） Mt -Uv crystallises earlier than plagioclase and clinopyroxene.Furthermore,the addition of H₂O to an anhydrous magma can explain silicate disequilibrium texture observed in the Fe-Ti oxide ore layers.  相似文献   

晚二叠世峨眉山地幔柱岩浆成矿作用     

汤庆艳  张铭杰  余明  王启立  尚慧 《岩石矿物学杂志》2013,32(5):680-692

晚二叠世峨眉山地幔柱岩浆作用同时形成了Cu-Ni-PGE硫化物矿床和V-Ti-Fe氧化物矿床等不同类型的岩浆矿床。从硫化物矿床的PGE富集型、Cu-Ni-PGE富集型到Cu-Ni富集型,再到钒钛磁铁矿矿床,成矿基性-超基性岩体中基性岩石比例逐渐增加,PGE含量降低。铜镍铂族硫化物矿床具Nb和Ta负异常,岩浆流体组分含量较高,含有较高的H₂;而钒钛磁铁矿矿床具Nb、Ta和Ti正异常,Zr和Hf负异常,岩浆流体组分含量较低,含有较高的H₂O、CO₂和H₂。两类矿床强不相容元素和轻稀土元素(LREE)富集,Sr-Nd同位素组成与峨眉山玄武岩的演化趋势一致。Sr-Nd-Os-C-He同位素组成揭示岩浆上升过程中经历了不同程度的地壳混染,高钛玄武岩和钒钛磁铁矿矿床成矿岩体的地壳混染程度较低,部分低钛玄武岩和铜镍硫化物矿床存在明显的地壳混染。这两类岩浆矿床的形成与峨眉山地幔柱玄武岩浆有关,岩浆介质环境中H₂含量较高,V-Ti-Fe 氧化物矿床的形成与分离结晶、高含量的水和氧逸度的升高有关,Cu-Ni-(PGE)硫化物矿床的形成与还原性流体介质、结晶分异和地壳混染作用有关。  相似文献   

南海沉积物漫反射光谱反映的220ka以来东亚夏季风变迁   总被引：1，自引：0，他引：1  

刘连文  郑洪波  翦知湣 《地球科学》2005,30(5):543-549

对南海越南岸外“太阳号”95航次17954孔220ka以来的沉积样品进行了漫反射光谱分析, 并从中提取F1和F2两个主因子及亮度和红度等漫反射光谱特征值, 发现漫反射光谱F1值和亮度反映了沉积物中的碳酸盐含量, 而漫反射光谱F2值和红度反映了沉积物中的铁氧化物含量, 后者可用作东亚夏季风的替代性指标.17954孔沉积物的漫反射光谱F2值显示, 倒数第二次冰消期东亚夏季风快速增长时间约在129ka; 本次工作还发现东亚夏季风在两次冰消期前的氧同位素2阶段和6阶段晚期各有一个异常强盛的时期.漫反射分析结果显示东亚夏季风主要受控于太阳辐射强度变化, 并明显地受低纬地区气候的影响.   相似文献   

Localization of nitric oxide synthase in the developing gonads of amphioxus Branchiostoma belcheri tsingtauense     

WANG Yongjun  ZHANG Shicui 《海洋学报(英文版)》2005,24(5):120-126

The localization of nitric oxide synthases （NOS） is dealed with in the developing gonads of amphioxus Branchiostoma belcheri tsingtauense. It was found by NADPH-diaphorase staining that （1） NOS activity was present in the nuclear membranes of germinal vesicles during the entire period ofoocyte development; （2） NOS was localized in both the nuclear membranes and the perinuclear region of cytoplasm in the vitellogenetic oocytes; （3） NOS was relocated in the cortical layer in the mature egg; （4） NOS activity was present in spermatocytes, but not in the spermatogonia in the middle of October; （5） NOS was detected in both spermatozoa and spermatids as well as spermatocytes during the breeding season. This is the first report on the distribution pattern of NOS in the developing gonads in protochordates. These results suggest a role for NOS in the functioning of the nuclear membranes and yolk synthesis during oogenesis and in cell division and differentiation during spermatogenesis.  相似文献   

小河金矿的细菌预氧化研究   总被引：2，自引：0，他引：2  

郑存江  熊英 《陕西地质》2000,18(2):93-97

陕西旬阳小河金矿的浮选金精矿含砷（２０－２７％）,采用细菌预氧化时较为困难。采用不同方式对有Ｔ．ｆ菌进行驯化,有效地提高了细菌的氧化活性,金的浸出率从０．６％提高到８５．１２％。  相似文献   

EMISSION OF N2O FROM AGRICULTURAL SOIL UNDER SNOW COVER : A SIGNIFICANT PART OF N BUDGET     

E. VAN BOCHOVE  H. G. JONES  F. PELLETIER  D. PRVOST 《水文研究》1996,10(11):1545-1549

  相似文献   

1999年和2000年夏季南极菲尔德斯半岛N_2O浓度对比          下载免费PDF全文

孙立广  朱仁斌  尹雪斌  赵俊琳  邢光熹  施书莲  杜丽娟 《极地研究》2001,(2)

1999与 2 0 0 0年夏季对南极菲尔德斯半岛不同地点大气中 N2 O浓度进行了监测 ,分析了苔藓植被区 N2 O浓度季节变化特征 ;2 0 0 0年夏季该植被区 N2 O浓度均值为 ( 31 0 .7± 4.4)×1 0 - 9(体积百分比 ) ,比 1 999年的 ( 32 1 .9± 3.3)× 1 0 - 9约低 1 1× 1 0 - 9;阿德雷岛企鹅滩及其沙坝处N2 O浓度变化趋势与苔藓植被区相一致 ,浓度均值分别为 ( 31 2 .4± 5 .1 )× 1 0 - 9和 ( 31 2 .7± 5 .3)× 1 0 - 9,比 1 999年约低 9× 1 0 - 9;另外 ,不同地点大气中 N2 O浓度普遍比 1 999年低 ,但整体变化规律相似 :各考察站区 N2 O浓度普遍高于无人区 ;唯一例外的是企鹅聚集区 N2 O浓度却高于各考察站区 ,暗示了企鹅及其排泄物、人为源是南极大气中 N2 O主要的源。本文初步探讨了 N2 O浓度异常降低的原因  相似文献   

低品位氧化钴矿石钴的赋存状态和浸取实验研究     

徐冬梅  甘树才等 《矿物学报》2001,21(2):144-148

基于我国钴资源分布分散、且多为伴生、品位低的现状，对某铜钴矿化区钴矿石中的钴碳酸盐矿物、含钴铁氧化物和具有吸附态的粘土矿物进行了钴的赋存状态和浸取试验研究，查明了钴的赋存状态，并以此为依据，运用逐一条件试验和正交试验相互验证的办法，确定了最优化的浸取试验方案，该方法对此低品位氧化钴矿石中钴的浸出率达到90%以上。  相似文献   

Immobilization of Cu and As in two contaminated soils with zero-valent iron – Long-term performance and mechanisms     

《Applied Geochemistry》2016

Immobilization of trace elements in contaminated soils by zero-valent iron (ZVI) is a promising remediation method, but questions about its long-term performance remain unanswered. To quantify immobilization and predict possible contaminant remobilization on long timescales detailed knowledge about immobilization mechanisms is needed. This study aimed at assessing the long-term effect of ZVI amendments on dissolved copper and arsenic in contaminated soils, at exploring the immobilization mechanism(s), and at setting up a geochemical model able to estimate dissolved copper and arsenic under different scenarios. Samples from untreated and ZVI-treated plots in two field experiments where ZVI had been added 6 and 15 years ago were investigated by a combination of batch experiments, geochemical modeling and extended X-ray absorption fine structure (EXAFS) spectroscopy. Dissolved copper and arsenic concentrations were described by a multisurface geochemical model with surface complexation reactions, verified by EXAFS. The ZVI remained “reactive” after 6–15 years, i.e. the dissolved concentrations of copper and arsenic were lower in the ZVI-treated than in the untreated soils. There was a shift in copper speciation from organic matter complexes in the untreated soil to surface complexes with iron (hydr)oxides in the ZVI-treated soil. The pH value was important for copper immobilization and ZVI did not have a stabilizing effect if pH was lower than about 6. Immobilization of arsenic was slightly pH-dependent and sensitive to the competition with phosphate. If phosphate was ignored in the modeling, the dissolution of arsenate was greatly underestimated.  相似文献