Size Distributions and Elemental Compositions of Particulate Matter on Clear, Hazy and Foggy days in Beijing, China   总被引：2，自引：0，他引：2  

YANG Yongjie  WANG Yuesi  HUANG Weiwei  HU Bo  WEN Tianxue  ZHAO Yanan 《大气科学进展》2010,27(3):663-675

Total suspended particulates(TSP)samples were collected using low pressure impactors(Andersen Series 20-800,USA)on typical clear,hazy and foggy days in Beijing in order to investigate the characteristics of size distributions and elemental compositions of particulate matter(PM)in different weather conditions. The concentrations of sixteen elements,including Na,Mg,Al,K,Ca,Mn,Fe,Ni,Cu,Zn,As,Se,Cd,Ba,Tl and Pb were detected using inductively coupled plasma mass spectrometry(ICP-MS).The results showed that Ca,Al,Fe,Mg and Ba on foggy days were 2.0-2.6 times higher than on clear days,and 2.3-2.9 times higher than on hazy days.Concentrations of Cu,Zn,As,Se and Pb on foggy days were 163.5,1186.7,65.9,32.0 and 708.2 ng m-3,respectively,in fine particles,and 68.1,289.5,19.8,1.6 and 103.8 ng m-3,respectively,in coarse particles.This was 1.0-8.4 times higher and 1.4-7.4 times higher than on clear and hazy days,respectively.It is then shown that Mg,Al,Fe,Ca and Ba were mainly associated with coarse particles,peaking at 4.7-5.8μm;that Cd,Se,Zn,As,Tl and Pb were most dominant in fine particles,peaking at 0.43-1.1μm;and that Na,K,Ni,Cu and Mn had a multi-mode distribution,with peaks at 0.43-1.1μm and 4.7-5.8μm.The enrichment factors indicated that coal combustion along with vehicle and industry emissions may be the main sources of pollution elements.  相似文献   

Evidence for microbiological manganese oxidation in the river Tamar Estuary, South West England     

Peter W. L. Vojak  Clive Edwards  Martin V. Jones 《Estuarine, Coastal and Shelf Science》1985,20(6):661-671

Water samples from the Tamar Estuary oxidized manganese when supplemented with Mn²⁺ (2 mgl⁻¹). The rates of oxidation were depressed in the presence of various metabolic inhibitors. The effect of Mn²⁺ and temperature on the rate of manganese oxidation suggested that a biological process was largely responsible for converting Mn²⁺ to Mn⁴⁺. Rates of manganese oxidation were much higher in freshwater (3·32 μgl⁻¹ h⁻¹ in water containing 30 mgl⁻¹ of suspended matter) than in saline water (0·7 μgl⁻¹ h⁻¹ in water of salinity 32‰) containing the same amount of particulate matter. The rate of manganese oxidation was proportional to the particulate load (up to 100 mgl⁻¹ particulates).  相似文献   

From highly polluted inland city of China to “Lanzhou Blue”: The air-pollution characteristics     

SuPing Zhao  Ye Yu  DaHe Qin 《寒旱区科学》2018,10(1):12-26

Air quality was improved considerably and the so-called "Lanzhou Blue" appeared frequently in Lanzhou due to implementation of some strict emission-control measures in recent years. To better understand whether the concentration of each air pollutant had decreased significantly and then give some suggestions as to urban air-quality improvement in the near future, the variations of the Air Quality Index (AQI) and six criterion air pollutants (PM_2.5, PM₁₀, CO, SO₂, NO₂, and O₃) at five state-controlled monitoring sites of Lanzhou were studied from 2013 to 2016. The AQI, PM_2.5, PM₁₀, and SO₂ gradually decreased from 2013 to 2016, while CO and NO₂ concentrations had slightly increasing trends, especially in urban areas, due to the large number of motor vehicles, which had an annual growth rate of 30.87%. The variations of the air pollutants in the no-domestic-heating season were more significant than those in the domestic-heating season. The increase of ozone concentration for the domestic-heating season at a background station was the most significant among the five monitoring sites. The vehicle-exhaust and ozone pollution was increasingly severe with the rapid increase in the number of motor vehicles. The particulate-matter pollution became slight in the formerly highly polluted Lanzhou City. Some synergetic measures in urban and rural areas of Lanzhou should be taken by the local government in the near future to control fine particulate-matter (PM_2.5) and ozone pollution.  相似文献   

The statistics of particle velocities and accelerations under waves with directional spread     

M.J Tucker 《Ocean Engineering》1998,25(6):481-496

The statistics of the horizontal component of the water particle velocity vector under random waves are considered. A spread in the directions of travel of the component wave trains does not affect the rms value of the modulus r but it affects the shape of its probability distribution in such a way that the pr3bability of extreme values is reduced. For small and moderate directional spreads the modulus for a given probability of exceedance is reduced by a factor which tends to F_s as the probability of exceedance tends to zero, where F_s is the spread factor (which is typically 0.9 in temperate storms). However, the convergence on this asymptote is not complete for probabilities of engineering importance, particularly for wide directional spreads. The standard deviation of the probability distribution of the direction of the vector is reduced roughly in inverse proportion to r. The same conclusions apply to particle accelerations.  相似文献   

Behaviour of particle-laden flows into the ocean: experimental simulation and geological implications   总被引：3，自引：0，他引：3  

Paul Mcleod  Steven Carey  & R. Stephen J. Sparks 《Sedimentology》1999,46(3):523-536

The behaviour of subaerial particle-laden gravity currents (e.g. pyroclastic flows, lahars, debris flows, sediment-bearing floods and jökulhlaups) flowing into the sea has been simulated with analogue experiments. Flows of either saline solution, simple suspensions of silicon carbide (SiC) in water or complex suspensions of SiC and plastic particles in methanol were released down a slope into a tank of water. The excess momentum between subaerial and subaqueous flow is dissipated by a surface wave. At relatively low density contrasts between the tank water and the saline or simple suspensions, the flow mixture enters the water and forms a turbulent cloud involving extensive entrainment of water. The cloud then collapses gravitationally to form an underwater gravity current, which progresses along the tank floor. At higher density contrasts, the subaerial flow develops directly into a subaqueous flow. The flow slows and thickens in response to the reduced density contrast, which is driving motion, and then continues in the typical gravity current manner. Complex suspensions become dense flows along the tank floor or buoyant flows along the water surface, if the mixtures are sufficiently denser or lighter than water respectively. Flows of initially intermediate density are strongly influenced by the internal stratification of the subaerial flow. Material from the particulate-depleted upper sections of the subaerial flow becomes a buoyant gravity current along the water surface, whereas material from the particulate-enriched lower sections forms a dense flow along the tank floor. Sedimentation from the dense flow results in a reduction in bulk density until the mixture attains buoyancy, lifts off and becomes a secondary buoyant flow along the water surface. Jökulhlaups, lahars and debris flows are typically much denser than seawater and, thus, will usually form dense flows along the seabed. After sufficient sedimentation, the freshwater particulate mixture can lift off to form a buoyant flow at the sea surface, leading to a decoupling of the fine and coarse particles. Flood waters with low particulate concentrations (<2%) may form buoyant flows immediately upon entering the ocean. Subaerial pyroclastic flows develop a pronounced internal stratification during subaerial run-out and, thus, a flow-splitting behaviour is probable, which agrees with evidence for sea surface and underwater flows from historic eruptions of Krakatau and Mont Pelée. A pyroclastic flow with a bulk density closer to that of sea water may form a turbulent cloud, resulting in the deposition of much of the pyroclasts close to the shore. Dense subaqueous pyroclastic flows will eventually lift off and form secondary buoyant flows, either before or after the transformation to a water-supported nature.  相似文献   

太湖流域昆承湖春季颗粒物和有色可溶性有机物吸收特性   总被引：4，自引：1，他引：3  

柳彩霞  郭子祺  张宝钢  雷霞  马茵驰 《湖泊科学》2011,23(5):773-782

利用2010年4月23日在昆承湖采集的水体吸收系数数据,对总悬浮物颗粒物、浮游植物色素颗粒物、非色素颗粒物和有色可溶性有机物的吸收特征进行研究.结果表明,春季昆承湖水体除675 nm附近具有叶绿素吸收峰的红光波段外,非色素颗粒物吸收系数大于浮游植物色素颗粒物吸收系数,总颗粒物吸收系数光谱分布与非色素颗粒物的吸收光谱类似...  相似文献   

长江中下游浅水湖泊悬浮颗粒物吸收系数测定方法探讨     

时志强  张运林  蔡同锋 《湖泊科学》2015,27(3):519-526

对两种水体悬浮颗粒物吸收系数测定方法及相关计算进行对比研究.通过长江中下游湖泊典型藻类的实验室培养,利用T方法和T-R方法分别对藻类颗粒物、藻类泥沙混合悬浊液进行吸收系数测定.通过颗粒物光谱吸收系数与叶绿素a之间的相关性关系,对比了两种方法的测量稳定性.通过对不同比例的藻类和无机悬浮颗粒物(ISS)的混合悬浊液进行分析,获得了不同浊度水体悬浮物吸收光谱的变化情况.结果表明,在纯藻或者泥沙含量较少的水体进行颗粒物吸收系数光谱测定时,T方法和T-R方法均可以采用,并且均具有较高的测定精度.然而,在泥沙含量相对较高的浑浊水体,应尽量选取T-R方法进行颗粒物吸收光谱的测定,以提高测定精度.长江中下游浅水湖泊由于底泥易受风浪影响发生再悬浮,因此在颗粒物吸收系数光谱测定中,当水体中ISS含量超过30 mg/L时,应选择T-R方法.  相似文献   

南沙渚碧礁生态系有机碳的分布及周日变化特征   总被引：4，自引：0，他引：4  

郑佩如  郭卫东  胡明辉  杨逸萍  吴林兴  王汉奎 《海洋通报》2004,23(2):13-18

1999 年 4 月对我国南沙群岛渚碧礁海水中溶解有机碳的分布及礁坪区颗粒有机碳 (POC) 和溶解有机碳 (DOC) 的周日变化特征进行了观测。结果表明,渚碧礁表层海水 DOC 变化范围为 1.43~3.62 mg/L,平均为 2.16 mg/L,含量分布大致表现为礁坪区>潟湖>礁外。潟湖 DOC 的垂直分布大致表现为表层高于底层,可能与表层浮游植物的光合作用有关。礁坪区 POC 及 DOC 都呈现显著的周日变化特征,POC 呈现夜晚高,白天低的特点,浮游植物的昼夜垂直移动可能是产生该现象的主要原因。DOC 的周日变化则主要受浮游动物昼夜垂直移动及细菌等生物活动的影响。  相似文献   

The composition of nutrient fluxes from contrasting UK river basins     

M. A. Russell  D. E. Walling  B. W. Webb  R. Bearne 《水文研究》1998,12(9):1461-1482

Accurate estimates of N and P loads were obtained for four contrasting UK river basins over a complete annual cycle. The fractionation of these loads into dissolved and particulate, and inorganic and organic components allowed a detailed examination of the nutrient load composition and of the factors influencing both the relative and absolute magnitude of these components. The particulate phosphorus (TPP) loads account for 26–75% of the annual total phosphorus (TP) transport and are predominantly inorganic. The inorganic (PIP) and organic (POP) fractions of the TPP loads represent 20–47% and 6–28% of the annual TP transport, respectively. In contrast, the particulate nitrogen loads (TPN) represent 8% or less of the annual total nitrogen (TN) loads and are predominately organic. For dissolved P transport, the dissolved inorganic fraction (DIP) is more important, representing 15–70% of the TP loads, whereas the dissolved organic fraction (DOP) represents only 3–9% of the TP loads. The TN loads are dominated by the dissolved component and more particularly the total oxidized fraction (TON), which is composed of nitrate and nitrite and represents 76–82% of the annual TN transport. The remaining dissolved N species, ammonium (NH₄-N) and organic N (DON) account for 0·3–1·2% and 13–16% of the annual TN transport, respectively. The TPN and TPP fluxes closely reflect the suspended sediment dynamics of the study basins, which are in turn controlled by basin size and morphology. The dissolved inorganic nutrient fluxes are influenced by point source inputs to the study basins, especially for P, although the TON flux is primarily influenced by diffuse source contributions and the hydrological connectivity between the river and its catchment area. The dissolved organic fractions are closely related to the dissolved organic carbon (DOC) dynamics, which are in turn influenced by land use and basin size. The magnitude of the NH₄-N fraction was dependent on the proximity of the monitoring station to point source discharges, because of rapid nitrification within the water column. However, during storm events, desorption from suspended sediment may be temporarily important. Both the magnitude and relative contribution of the different nutrient fractions exhibit significant seasonal variability in response to the hydrological regime, sediment mobilization, the degree of dilution of point source inputs and biological processes. © 1998 John Wiley & Sons, Ltd.  相似文献   

Effects of Solid Organic Wastes on Soil Particulate Organic Carbon Structure Under Different Water Conditions     

Xiaojing Qu  Jinggui Wu  Jinghong Zhao  Jianming Li  Juan Hu  Opoku‐Kwanowaa Yaa 《洁净——土壤、空气、水》2019,47(8)

  相似文献