Sorption of carbon dioxide–methane mixtures     

Grayna Ceglarska-Stefa&#x;ska  Katarzyna Zar&#x;bska 《International Journal of Coal Geology》2005,62(4):211-222

The paper reports the results of experiments concerning the sorption/desorption processes, observed under laboratory conditions, in two types of coal extracted from operational coal-mines in Poland, using CH₄ and CO₂ to observe their relative inter-reaction with the coal samples when introduced in varying proportions and conditions. Numerous studies concerning the sorption/desorption phenomena have described the operational mechanisms and the relationship of mine gases to the organically-created coal-body in mines. The differences in the behaviour of certain gases is twofold: firstly the essentially different characteristics of CO₂ and CH₄, and secondly the structure of the coal-bed itself: its degree of metamorphism and content of macerals. From the results yielded, it was observed that the divergence of the isotherms of sorption of CH₄ and other gases in comparison with the isotherms of sorption of CO₂ and a CO₂/CH₄ mixture differed and that the curve on the sorption isotherm was more clearly distinct after the introduction of CO₂ molecules to the system: coal with a higher degree of metamorphism—CH₄, which is closely related to the rigidity of the structure according to the level of metamorphism. Since coals with higher carbon content exhibit lower molecular bonding than low-carbonised coals, the characteristic feature of the bonds in the first case is their mobility. Knowledge of the physical and chemical properties of hard coals, as well as their interaction with mining gases, is of great use in solving problems concerned with the extraction of methane from mines or its storage in goafs.  相似文献   

Environmental significance of C/C and O/O ratios of modern land-snail shells from the southern great plains of North America     

Meena Balakrishnan  James L. Theler  Don G. Wyckoff 《Quaternary Research》2005,63(1):15-30

¹³C/¹²C and ¹⁸O/¹⁶O ratios of aragonite shells of modern land snails from the southern Great Plains of North America were measured for samples from twelve localities in a narrow east-west corridor that extended from the Flint Hills in North Central Oklahoma to the foothills of the Sangre de Cristo Mountains in Northern New Mexico, USA. Across the study area, shell δ¹⁸O values (PDB scale) ranged from −4.1‰ to 1.2‰, while δ¹³C values ranged from −13.2‰ to 0.0‰. δ¹⁸O values of the shell aragonite were predicted with a published, steady state, evaporative flux balance model. The predicted values differed (with one exception) by less than 1‰ from locality averages of measured δ¹⁸O values. This similarity suggests that relative humidity at the time of snail activity is an important control on the δ¹⁸O values of the aragonite and emphasizes the seasonal nature of the climatic information preserved in the shells. Correlated δ¹³C values of coexisting Vallonia and Gastrocopta suggest similar feeding habits and imply that these genera can provide information on variations in southern Great Plains plant ecology. Although there is considerable scatter, multispecies, transect average δ¹³C values of the modern aragonite shells are related to variations in the type of photosynthesis (i.e., C₃, C₄) in the local plant communities. The results of this study emphasize the desirability of obtaining isotope ratios representing averages of many shells in a locale to reduce possible biases associated with local variations among individuals, species, etc., and thus better represent the “neighborhood” scale temporal and/or spatial environmental variations of interest in studies of modern and ancient systems.  相似文献   

273.15K下LiCl-Li2B4O7-H2O体系热力学性质的等压研究   总被引：2，自引：0，他引：2       下载免费PDF全文

杨吉民  姚燕  张爱云  宋彭生 《盐湖研究》2005,13(1):19-24

用等压法研究了273 15K下LiCl-Li2B4O7-H2O体系中纯盐水溶液(离子强度范围为LiCl0 2046～2 5055mol·kg-1,Li2B4O70 1295～0 3700mol·kg-1)以及混合盐水溶液(离子强度范围为0 0931～2 4911mol·kg-1)渗透系数和水活度;计算了LiCl-Li2B4O7-H2O体系的饱和蒸汽压,获得饱和蒸汽压、渗透系数随离子强度的变化规律。用实验数据以最小二乘法求取了LiCl和Li2B4O7纯盐参数及体系的混合盐参数,拟合的标准偏差分别为0 0077和0 026。用该模型计算的渗透系数值与实验结果取得合理的一致。同时研究结果与273 15K下LiCl-Li2SO4-H2O体系的渗透系数随离子强度变化的规律作了比较。本研究对完善低温下含锂、硼盐湖卤水体系的热力学模型和盐湖资源的综合开发利用具有重要意义。  相似文献   

浓硫酸钠水溶液中的离子对          下载免费PDF全文

刘元会  房春晖 《盐湖研究》2005,13(4):42-46

不同浓度的Na2SO4水溶液的拉曼光谱显示了SO42-的四个拉曼活性带:980 cm-1处的SO42-的对称伸缩振动模式v1带,1 106 cm-1处的反对称伸缩振动模式v3带,448 cm-1处的变形振动模式v2带和617 cm-1处的变形振动模式v4带。482 cm-1处的肩膀峰是由于NaSO4-离子对的形成对448 cm-1的v2带的影响而形成的SO42-的一个新的振动峰。浓Na2SO4水溶液中,水共享离子对[Na+.H2O.SO42-]-是主要的离子对物种。随着Na2SO4水溶液浓度的增加,Na+和SO42-的相互作用增强,NaSO4-离子对所占的摩尔分数增加。  相似文献   

Pix4Dmapper在无人机航摄应急救灾项目中的应用研究   总被引：2，自引：0，他引：2  

汪雅婕 《测绘与空间地理信息》2016,(9):202-203

无人机由于其独特的航摄优势,在灾害应急处理等特殊事件中,发挥着越来越重要的作用。本文结合一次山体滑坡救灾项目,阐述了使用Pix4Dmapper软件对无人机航摄数据进行快速处理,并获取正射影像图和数字表面模型的方法,通过数据分析和评估,证明了此方法的可行性和有效性。  相似文献   

X射线荧光光谱法分析不同类型岩石中10种主量元素的测试能力验证   总被引：4，自引：3，他引：1  

王建其  柳小明 《岩矿测试》2016,35(2):145-151

以28个不同类型岩石标样作外标,用玻璃熔片法制样,采用经验系数法进行基体校正,建立了X射线荧光光谱法(XRF)测定不同类型岩石中硅铝钙镁等10种主量元素的分析方法。该方法被用于参与GeoPT分析测试能力验证,15年来分析了23个不同类型的岩石验证样品。经验证该方法对SiO_2、Al_2O_3、K_2O和CaO具有非常好的分析效果(所有测定结果的|Z|2);对于MgO、MnO、TiO_2和Na_2O四个元素,尽管各有一个样品的分析结果的|Z|2,这主要是样品与标样的基体差异较大造成了低含量样品测定结果超差,但依然可获得好的分析效果;当TFe_2O_31.0%,P_2O_5含量在0.08%~0.80%区间时,分析结果的|Z|2,满足分析期望。总体上所建立的XRF分析方法稳定,可满足应用地球化学实验室测试不同类型岩石中10种主量元素的分析期望。  相似文献   

内蒙古老国营子金铜矿床地质-地球物理勘查与研究     

陈伟军 《地质与勘探》2016,52(2):246-250

内蒙古老国营子金铜矿床是近年来利用地质与地球物理相互结合手段新发现的一个矿床。本次研究利用基于电磁原理的地球物理手段进行了找矿测试,结果表明:甚低频(VLF)地球物理扫面发现了近EW向和NW向的高阻带,分别对应了两条相应的矿化蚀变带。音频大地电磁法(EH4)测深影像显示矿化蚀变带表现为高阻异常带,与VLF的测量结果相一致。激电(IP)中梯测量显示矿化蚀变带具有高阻、高充电率和高金属因子异常特征。结合具体的地质特征,在老国营子金铜矿区综合运用这三种地球物理方法,取得了较好的找矿效果。  相似文献   

Influence of internal decadal variability on the summer rainfall in Eastern China as simulated by CCSM4     

Yali Zhu  Tao Wang  Jiehua Ma 《大气科学进展》2016,33(6):706-714

The combined impact of the Pacific Decadal Oscillation(PDO) and Atlantic Multidecadal Oscillation(AMO) on the summer rainfall in eastern China was investigated using CCSM4. The strongest signals occur with the combination of a positive PDO and a negative AMO(+PDO- AMO), as well as a negative PDO and a positive AMO(-PDO + AMO). For the +PDO- AMO set, significant positive rainfall anomalies occur over the lower reaches of the Yangtze River valley(YR),when the East Asian summer monsoon becomes weaker, while the East Asian westerly jet stream becomes stronger, and ascending motion over the YR becomes enhanced due to the jet-related secondary circulation. Contrary anomalies occur over East Asia for the-PDO + AMO set. The influence of these two combinations of PDO and AMO on the summer rainfall in eastern China can also be observed in the two interdecadal rainfall changes in eastern China in the late 1970 s and late 1990 s.  相似文献   

基于雷达资料四维变分同化及云模式的中尺度对流系统数值临近预报试验          下载免费PDF全文

刘莲  陈明轩  王迎春 《Acta Meteorologica Sinica》2016,74(2):213-228

基于雷达资料快速刷新四维变分同化(RR4DVar)初始化的三维数值云模式,利用京津冀6部新一代多普勒天气雷达和区域自动气象站观测资料,针对2013年7月4日出现在京津冀平原地区的中尺度对流系统(MCS),开展了数值临近预报试验。研究结果表明,充分考虑雷达观测信息的对流尺度数值临近预报具有很大的优势,但也存在不足:(1)模式能够较好地把握中尺度对流系统的组织发展和移动演变特征,对风暴回波带的走向和尺度特征有较好的预报,但对强回波的强度和位置预报存在一定偏差;(2)模式预报可以反映风暴系统的中小尺度扰动特征,对风暴冷池和出流边界(阵风锋)的发展变化均有较为合理的预报;(3)模式对强降水中心和雨带位置的预报有很大优势,能较好地预报弱降水雨带的分布形势和雨量,但对强降水落区的预报偏大;(4)模式对风暴造成的对流性强降水的预报准确率较高,对0.5—10 mm阈值的降水范围预报偏差比较合理,对10 mm以上降水范围的预报偏大,但是对弱降水风暴的弱回波较强回波的预报性能要好;(5)由于三维数值云模式对京津冀复杂地形的处理不够完善,对山前风场预报偏差较大,造成对山前风暴的发展演变和山前降水的预报偏差较大。  相似文献   

基于有理多项式模型的GF4卫星区域影像平差处理方法及精度验证     

皮英冬  杨博  李欣 《测绘学报》2016,45(12):1448-1454

分析了我国首颗静止轨道光学遥感卫星高分四号(GF4)特有的区域成像模式的几何特性,基于静止轨道成像基高比较小的几何特性提出一种利用平均高程面的区域网平差方法。该方法针对GF4卫星影像构建了基于有理多项式模型RFM的区域网平差模型,并在无控制条件下,对GF4卫星区域影像进行区域网平差处理,解决了GF4号区域影像由于定轨误差、定姿误差、大气折光以及镜头畸变等因素导致的拼接精度较低的问题。最后,通过两组真实数据试验对本文方法的精度及有效性进行了验证,同时分析了采用不同的误差补偿模型对于平差结果精度的影响。  相似文献