A spectrophotometric measurement of soil cation exchange capacity based on cobaltihexamine chloride absorbance     

Delphine Aran  Armand Maul  Jean-Franois Masfaraud 《Comptes Rendus Geoscience》2008,340(12):865-871

Among numerous methods for cation exchange capacity (CEC) determination for soils and sediments, the cobaltihexamine chloride method is frequently used due to its ability to measure CEC at soil pH. After exchange with Co(NH₃)₆³⁺ ions, CEC is estimated via the measurement of the Co remaining in solution. The modified method proposed allows a more rapid determination of CEC based on the measurement of the absorbance at 472 nm of the cobaltihexamine chloride solution before and after exchange. This method has been applied to various soil's horizons from four sites, selected to cover a wide range of CEC and pH values. The model obtained allows one to calculate CEC from absorbance at 472 nm with 95% confidence intervals. As CEC is of relevant meaning in agronomical and environmental purposes, and more recently in ecotoxicological studies, this modified method can be proposed as a rapid test for CEC evaluation.  相似文献   

The acid neutralizing capacity （ANC） of South Africa＇s freshwater ecosystems     

Stephanie de Villiers 《中国地球化学学报》2006,25(B08):146-146

Acidification is considered the most important one of the primary chemical stress factors that impact on freshwater ecosystems. In unpolluted freshwater systems, the primary controls on the degree of acidification are factors such as the geological substrate of the catchment area, the presence of organic acids secreted by vegetation in the river system, and equilibrium exchange of carbon dioxide with the atmosphere. Anthropogenic factors that can impact on the degree of acidification of freshwater systems include agricultural, mining and industrial activities, either through direct runoff into river systems or through deposition of atmospheric pollutants from these sources. The capacity factors alkalinity and acidity, which represent the acid- and base-neutralizing capacity （ANC and BCN） of an aqueous system, have been used as more reliable measures of the acidic character of freshwater systems than pH. Unlike pH, ANC and BNC are not affected by parameters such as temperature and pressure. Therefore, ANC has been employed as a predictor of biological status in critical load assessments. Freshwater systems with ANC＇s eq/L isμeq/L are considered sensitive to acidification, ANC=0 μbelow 150 commonly used as the predictor for fish species such as trout in lakes, and an eq/L as more realistic for streams. Acid-neutralizing capacity μANC value of 40 （ANC） can be determined by titration with a strong acid to a preselected equivalence point. Alternatively, it can be calculated as the difference between base cations （[BC]） and strong acid anions （[SAA]）： ANC=[BC]- [SAA]=[Ca^2＋]＋[Mg^2＋]＋[Na^＋]＋[K^＋]-[SO4^2-]-[NO3^-]-[Cl^-] To date, there has been no attempt to establish the ANC of South Africa＇s freshwater ecosystems or variability therein, despite the fact that long-term water quality monitoring data exist for all the parameters needed to calculate it according to the above equations. As a result, the relationship between the acid neutralizing capacity of freshwater ecosystems in South Africa and biodiversity factors, such as fish status, is unknown. Results of the first comprehensive （country-wide scale） evaluation of the acid neutralizing capacity of river systems in South Africa will be presented. Long-term monitoring data obtained from the Department of Water Affairs and Forestry （DWAF） from most of South Africa＇s river systems were used to establish geographic and temporal variabilities in ANC. The results show that the Berg and Breede River systems are most susceptible to acidification, and that geological substrate appears to explain most of the geographic variabilities observed.  相似文献   

Nature minéralogique et rôle nutritionnel des argiles de sols céréaliers en région subhumide à semi-aride (Tunisie)     

Habib Ben Hassine 《Comptes Rendus Geoscience》2006,338(5):329-340

The cereal soils of the Northwest of Tunisia derive most of the time, from alluvial deposits or altered remains of carbonated and clayey rocks. Extraction of the clayey fraction permitted to reveal the presence of the following clayey minerals: kaolinite, illite, smectite, chlorite, as well as an illite–smectite interstratified layer, which is present in the deep horizons of the vertisol and in the isohumic soil. The presence of such types of clays shows that the evolution mechanism of soils is weathering of primary minerals inherited from the sedimentary rocks of the Northwest of Tunisia. These clays ensure to soils most of their cationic exchange capacity. Thanks to these clays, which have Ca⁺⁺, Mg⁺⁺ and K⁺ as exchangeable cations, the chemical fertility of these soils is ensured. It may be improved by increasing contents of organic matter, which is naturally few abundant in these soils. To cite this article: H. Ben Hassine, C. R. Geoscience 338 (2006).  相似文献   

等截面单桩抗拔承载性状试验研究     

王之军  管志新  刘建平  吴喜江 《探矿工程》2006,33(4):1-4

在基坑中对等截面单桩进行了抗拔静载试验，在桩身设置应变式钢筋计，成功测得桩身各截面的应变数据。分析试验所得数据，对试验抗拔桩抗拔系数的取值、侧摩阻力的发挥、混凝土桩身的开裂等进行了探讨，相应给出了抗拔桩的设计建议。  相似文献   

CFG桩复合地基褥垫层的合理厚度确定方法研究          下载免费PDF全文

贾瑞杰  隆威  於法明 《探矿工程》2006,33(4):5-7

在CFG桩复合地基设计中，褥垫层的厚度设计是一个重点，它是复合地基承载力能否全部发挥的关键因素之一。但其设计上基本是靠经验取值，缺少理论根据。从理论方面入手，推导了褥垫层厚度的理论计算方法，给出了最佳垫层厚度、桩土应力比的解析表达式。  相似文献   

基于RS和GIS的青藏高原草地生态系统土壤水分保持功能及其经济价值评估——以生长季为例   总被引：2，自引：0，他引：2  

于格  鲁春霞  谢高地  郭广猛 《山地学报》2006,24(4):498-503

根据生态系统服务功能理论,利用RS和G IS技术,以土壤含水量为基础因子,对青藏高原区草地生态系统的土壤水分保持功能及其价值的动态变化过程进行有效评价,以直接的货币形式反映出青藏高原主要草地类型的土壤水分保持功能的大小。通过计算和分析发现:(1)由于草地类型分布面积、单位面积保持量的影响,各种类型草地提供的土壤水分保持功能及其价值贡献率有较大差异,按照大小依次为:高寒草原类、高寒草甸类,高寒荒漠类、高寒草甸草原类和温性山地草甸类;(2)草地对土壤水分保持量及其价值呈现出较强的阶段性变化过程;(3)由于各种草地类型所处地理区域不同、草地本身各种自然特点和整体生态功能的不同,青藏高原草地生态系统提供的土壤水分保持功能及其经济价值呈现出明显的地域分布规律:自西北至东南逐渐降低。应该说,由于青藏高原地域、地理和独特气候等原因所致,本文计算得出的青藏高原草地生态系统土壤水分保持功能及其价值的具体数值不一定十分准确,但是能在一定程度上反映出土壤水分保持功能的强大及其在生长季中随时间变化的动态过程和基本规律(这种规律性结论与前人研究结论一致),这是一种在区域尺度上揭示草地生态系统土壤水分保持功能及其价值动态变化过程的方法尝试,这也是对动态评估生态服务功能的一种有益尝试。  相似文献   

Study on the Fragility of Building Structures in Taiwan     

Wen-I Liao  Chin-Hsiung Loh  Keh-Chyuan Tsai 《Natural Hazards》2006,37(1-2):55-69

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大吨位基桩抗压载荷试验中的锚桩预应力保护技术     

陈雅琴  张宏光  冯忠居  谢永利 《工程地质学报》2006,14(4):531-536

竖轴向承载力是桩基础设计的重要参数,现场静载试验是目前确定桩基承载力的主要手段之一。本文依托黄陵延安段高速公路洛河特大桥试桩工程,通过对原有工程桩施加预应力,形成了以工程桩为锚桩的锚拔体系。加载过程中试桩应力、锚桩应力及桩顶位移测试,结果表明,结合预应力技术,以工程桩作为锚桩构成桩基础静载试验的锚拔体系是可行的,同时提出了施加预应力大小的原则、方法以及确保后期曾作为锚桩的工程桩有足够承载能力应采取的必要措施。  相似文献   

新近沉积粉细砂层地基的试验与评价     

赵本肖  游占军 《中国煤田地质》2006,18(4):45-46,48

通过对邯郸市某车间地基的勘察．分析和探讨了新近沉积粉细砂地层的勘察手段、其物理力学性质，及其利用载荷试验确定承载力的标准取得了较为满意的结果，提出的一些分析方法，对新近沉积的粉细砂地层的勘察具有一定的借鉴作用。  相似文献   

皖中泥质岩工程性质探讨     

兰中平  许军才  董业才 《华东地质学院学报》2006,29(1):62-65

历来对半胶结泥质岩风化等级划分都带有许多主观性,从而影响提承载力,有的规范要求可不对半胶结岩石进行风化程度划分,但有时要对这些岩石进行工程地质细分,从而准确确定各分层的承载力与摩阻力。统计了合肥、六安、淮南、安庆地区等大量实践资料,用标准贯入击数、重型圆锥触探实验击数等原位测试手段来划分泥质岩风化等级,并对泥质岩的承载力与摩阻力等工程地质性质做出了评价。  相似文献