胶东黄铁矿显微构造变形与金富集关系：黄铁矿EBSD组构和地球化学约束     

李瑞红  杨立强  恽孟河  安平  邱昆峰  孟银生 《矿床地质》2019,38(2):303-318

载金黄铁矿显微构造变形与金富集关系可以从显微-超显微尺度揭示金成矿作用和地质过程,探讨金的再活化或再聚集作用。在胶东焦家金矿带成矿期识别出4种类型的黄铁矿,文章应用光学显微镜、扫描电镜(SEM)、透射电镜(TEM)、电子背散射衍射(EBSD)和电子探针(EMPA)等技术方法,探讨黄铁矿显微构造特征、超微观结构与金的富集关系。结果显示:载金黄铁矿均不发育环带,其中w(Fe)为45.70%～46.85%,w(S)为52.57%～53.37%;显微构造变形既有脆性变形又有塑性变形;黄铁矿晶体优选方位(CPO)主要表现为平行于晶轴极密和复杂极密;黄铁矿晶格间距为0.58 nm,主要发育刃位错。焦家金矿带在金成矿作用过程中,可见金集合体经历了从复杂的纳米尺度到宏观尺度矿物载体富集的过程,包括成矿流体中金络合物、金-铋-硫族化合物富集等化学结构变化过程和纳米金、载金黄铁矿纳米颗粒、岩矿石显微-超显微构造微环境变化过程。因此,不同类型载金黄铁矿CPO受到化学结构变化和显微-超显微变形微环境变化的联合制约,间接反映出载金黄铁矿中金的富集与黄铁矿内部变形、表面形貌和结构缺陷有密切关系。  相似文献   

伊犁蒙其古尔铀矿床含矿层砂岩中黄铁矿形成机制及对铀成矿的指示意义     

丁波  刘红旭  张宾  李平  蒋宏  张虎军  谢希良  郭春杰 《矿床地质》2019,38(6):1379-1391

蒙其古尔铀矿床为伊犁盆地南缘大型层间氧化带砂岩型铀矿床,为查明该矿床含矿层中黄铁矿成因及其形成机制,探讨微生物参与铀成矿过程。文章对含矿层砂岩中黄铁矿与铀矿物矿物学特征、黄铁矿S同位素与碳酸盐胶结物的C-O同位素开展细致研究。研究表明:①蒙其古尔铀矿床中铀主要以铀矿物与吸附铀形式存在,吸附铀主要为有机质吸附铀,铀矿物以沥青铀矿为主,多与黄铁矿、炭屑共生;②蒙其古尔铀矿床含矿层砂岩中黄铁矿主要以自形晶、草莓状和不规则状集合体产出,多与沥青铀矿、碳酸盐胶结物共生,其中黄铁矿S同位素(δ~(34)S_(V-CDT)=-68.4‰～22.1‰)与碳酸盐胶结物的C-O同位素(δ~(13)C_(V-PDB)=-10.2‰～-7.4‰,δ~(18)O_(V-PDB)=-9.6‰～-5.8‰)分析表明黄铁矿具有细菌硫酸盐还原(BSR)与有机物热解2种成因,并探讨了这2种不同成因黄铁矿的形成机制。③结合前人研究成果,认为硫酸盐还原菌(SRB)参与蒙其古尔铀矿床铀成矿过程,以间接还原方式为主,在有机质、黏土矿物与颗粒表面吸附U(Ⅵ)的基础上,通过硫酸盐还原菌(SRB)还原SO_4~(2-)产生的H_2S将U(Ⅵ)被还原成U(Ⅳ),形成铀矿物。  相似文献   

秦岭地区黄铁矿特征与金矿关系的研究     

涂怀奎 《化工矿产地质》2004,26(3):162-169

根据秦岭地区金矿床中黄铁矿特征,总结出典型的微细浸染型和含金石英脉型两种类型矿床特征。黄铁矿与金矿关系密切,含金黄铁矿多产于成矿的富集地段。通过对该区黄铁矿标型特征(晶形、粒级与热电性和微量元素)的系统研究,认为黄铁矿标型特征的研究,对深部找金矿与远景评价具有指导意义。  相似文献   

广东英德红岩黄铁矿床古水下隆起的控矿作用及矿床成因     

覃功炯  陈元琰 《现代地质》1988,2(2):241

红岩黄铁矿床是产于广东英德盆地中泥盆统东岗岭碳酸盐地层中的一个层控矿床。作者经详细研究之后,认为在含矿地层沉积时就存在着一个古水下隆起,由于古水下隆起控制了古地形,因而表现出不同的沉积作用。在矿区的中部东岗岭组较薄,主要为潮坪一泻湖相,而矿区的东、西部东岗岭组沉积较厚,表现为礁滩相。黄铁矿在东岗岭组沉积期和成岩早期沉积并再富集。 在东岗岭组成岩的晚期发生白云岩化作用。来自下伏地层砂岩、泥岩的富含Mg、Fe的水与孔隙水以及地下淡水发生混合引起了灰岩的白云岩化,以及矿源层中成矿元素的活化,并与来自砂岩和泥岩中的成矿物质叠加在一起。在白云岩中,特别是在古水下隆起之上经白云岩化之后,含矿溶液经过充填和交代作用而形成红岩矿床。显微镜研究,微量元素分析,硫、铅、氧、碳同位素研究的结果都支持这一成岩成矿模式。  相似文献   

川南煤系硫铁矿矿山地质环境现状分析   总被引：1，自引：0，他引：1  

蒋俊 《四川地质学报》1999,(4)

着重分析当前川南煤系硫铁矿的矿山地质环境现状,以及硫铁矿山普遍存在的一些地质环境问题,旨在引起社会各方面对矿山地质环境保护的重视。  相似文献   

宁芜云台山黄铁矿矿床中黄铁矿矿物的初步研究     

熊先孝  姚超美 《化工矿产地质》1999,21(4):215-219

宁芜云台山黄铁矿矿床中黄铁矿矿物以自形晶为主 ,次为他形粒状 ;黄铁矿晶胞参数为 5 .415 2 3～ 5 .41843× 10 -10 m ,晶体化学式为 (Fe0 .9968Co0 .0 0 0 6Ni0 .0 0 2 6) 1.0 0 0 0 S2 .0 597;黄铁矿红外吸收光谱主吸收峰值为 34 8cm-1,最小透过率为 30 .0 0 %～ 48.80 % ,透过率极差为 31.13～ 47.5 1;黄铁矿中Fe平均含量为 45 .44 % ,S平均含量 5 3.91% ,具有富S特征 ;Co/Ni平均值为 0 .2 1;稀土元素总量平均为2 1.84× 10 -6,具有明显负铈异常 (δCe :0 .76～ 0 .93)和负铕异常 (δEu :0 .72～ 0 .90 ) ;硫同位素组成δ3 4S为 7.0 0‰～ 2 3.0 0‰ ,黄铁矿是含矿热液以堆积、充填和交代方式形成 ,黄铁矿床为火山热水沉积矿床。  相似文献   

Metamorphic charnockite in contact aureoles around intrusive enderbite from Natal, South Africa     

Alfons M. van den Kerkhof  Geoffrey H. Grantham 《Contributions to Mineralogy and Petrology》1999,137(1-2):115-132

In the Port Edward area of southern Kwa-Zulu Natal, South Africa, charnockitic aureoles up to 10 m in width in the normally garnetiferous Nicholson's Point Granite, are developed adjacent to intrusive contacts with the Port Edward Enderbite and anhydrous pegmatitic veins. Mineralogical differences between the country rock and charnockitic aureole suggest that the dehydration reaction Bt + Qtz → Opx + Kfs + H₂O and the reaction of Grt + Qtz → Opx + Pl were responsible for the charnockitization. The compositions of fluid inclusions show systematic variation with: (1) the Port Edward Enderbite being dominated by CO₂ and N₂ fluid inclusions; (2) the non-charnockitized granite by saline aqueous inclusions with 18–23 EqWt% NaCl; (3) the charnockitic aureoles by low-salinity and pure water inclusions (<7 EqWt% NaCl); (4) the pegmatites by aqueous inclusions of various salinity with minor CO₂. As a result of the thermal event the homogenization temperatures of the inclusions in charnockite show a much larger range (up to 390 °C) compared to the fluid inclusions in granite (mostly <250 °C). Contrary to fluid-controlled charnockitization (brines, CO₂) which may have taken place along shear zones away from the intrusive body, the present “proximal” charnockitized granite formed directly at the contact with enderbite. The inclusions indicate contact metamorphism induced by the intrusion of “dry” enderbitic magma into “wet” granite resulting in local dehydration. This was confirmed by cathodoluminescence microscopy showing textures indicative for the local reduction of structural water in the charnockite quartz. Two-pyroxene thermometry on the Port Edward Enderbite suggests intrusion at temperatures of ∼1000–1050 °C into country rock with temperature of <700 °C. The temperature of aureole formation must have been between ∼700 °C (breakdown of pyrite to form pyrrhotite) and ∼1000 °C. Charnockitization was probably controlled largely by heat related to anhydrous intrusions causing dehydration reactions and resulting in the release and subsequent trapping of dehydration fluids. The salinity of the metamorphic fluid in the contact zones is supposed to have been higher at an early stage of contact metamorphism, but it has lost its salt content by K-metasomatic reactions and/or the preferential migration of the saline fluids out of the contact zones towards the enderbite. The low water activity inhibited the localized melting of the granite. Mineral thermobarometry suggests that after charnockite aureole genesis, an isobaric cooling path was followed during which reequilibration of most of the aqueous inclusions occurred. Received: 8 November 1998 / Accepted: 21 June 1999  相似文献   

秦岭煎茶岭金矿床含金富砷黄铁矿增生环带研究   总被引：4，自引：1，他引：3  

马建秦  李朝阳  张复新 《矿物学报》1999,19(2):139-147

在秦岭剪茶岭金矿床中发现了含金富砷黄铁矿增生环带。其产状,结构构造和成分特征共同显示了,金成矿主期金与砷有密切的地球化学相关性,在富砷增生环带发育时,金与砷共沉淀并可能在其中发育了不可见金。这种环带包含有重要的成矿作用信息,至少在矿区范围内可用于判别是否有主期矿化发育。  相似文献   

Spheroidal weathering of granite porphyry with well‐developed columnar joints by oxidation,iron precipitation,and rindlet exfoliation          下载免费PDF全文

Yasuto Hirata  Masahiro Chigira  Youqing Chen 《地球表面变化过程与地形》2017,42(4):657-669

Spheroidal weathering, one of the important rock weathering styles, has been attributed to chemical weathering by the water from joint surfaces, and mechanical aspects of the weathering have not been well addressed. We made an investigation on spheroidal weathering of Miocene granite porphyry with well‐developed columnar joints and found that this spheroidal weathering proceeds through chemical processes and accompanying mechanical processes. The investigation of the textures, physical properties, mineralogy, and chemistry of the porphyry revealed the presence of a brown band on the surface margins of corestones, representing the oxidation of pyrite and chlorite, and the precipitation of iron hydroxides, and the consequent generation of micro‐cracks within the band. During weathering, oxidation progresses inwards from joints that surround the rindlets, including both high‐angle columnar and low‐angle planar joints, and causes rounding of the unweathered interior portion of the rock. Microscopic observations of the brown band embedded with fluorescent resin show that pores are first filled with iron hydroxides, and that micro‐cracks then form parallel to the oxidation front in the outer portion of the brown band. Iron hydroxide precipitation increases the P‐wave velocity in the brown band, while micro‐crack formation decreases the tensile strength of the rock. Where the brown band has thickened to ~6 cm, the micro‐cracks are connected to one another to create continuous cracks, which separate the rindlets from the corestone. Micro‐crack formation parallel to the corestone surface may be attributed to compressive stresses generated by small amounts of volumetric expansion due to the precipitation of iron hydroxides in the brown band. Earth surface is under oxidizing environments so that precipitation of iron hydroxides commonly occurs; the spheroidal weathering in this paper is a typical example of the combination of chemical and mechanical processes under such environments. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

南海北部西沙海槽沉积物管状黄铁矿特征及其形成机理^*          下载免费PDF全文

石思思  吴朝东  梁金强  王熠哲  叶云涛  方允鑫  马健  翟俪娜 《古地理学报》2020,22(1):175-192

南海北部西沙海槽S1站位的岩心柱沉积物中广泛发育自生矿物黄铁矿,其形态以管状为主,且具有内部中空的圈层结构。使用扫描电镜、电子探针、LA-ICP-MS、SIMS等测试方法研究了管状黄铁矿的形态及圈层结构,结果显示: (1)管状黄铁矿发育内部中空的圈层结构,其中内圈层(I_py)由莓球状黄铁矿呈五角十二面体紧密堆积组成,外圈层(O_py)由晶形较好晶粒较大的八面体黄铁矿组成,并混有沉积碎屑及钙质生物壳体;(2)内圈层和外圈层分别呈现出贫S富Fe和富S贫Fe的特征,其成因是甲烷渗漏造成的局部还原环境使得As进入黄铁矿中导致晶格空缺或被扭曲,从而促进Ni、Co、Cu、Zn、Pb等微量元素的掺入;(3)内圈层、外圈层发生了明显的硫同位素分馏现象,内圈层中 δ³⁴S 平均为-37.8‰,外圈层中 δ³⁴S 平均为-29.3‰。研究认为,管状黄铁矿作为曾经甲烷渗漏的通道,其生长机制可分为3个阶段: (1)气水通道形成阶段: 向上运移的甲烷流体在沉积物孔隙中逐渐形成气水通道;(2)外圈层形成阶段: 当向上运移的甲烷与硫酸盐发生甲烷厌氧氧化时,逐渐形成晶体较大、晶形较好的八面体黄铁矿外圈层;(3)内圈层形成阶段: 随着甲烷浓度逐渐降低,在气水通道中的微生物作用下,剩余甲烷与向下运移的硫酸盐继续反应形成莓球状黄铁矿内圈层。因此,南海北部的泥岩中大量发育的管状黄铁矿常常与地层中甲烷水合物的存在有关。  相似文献