Investigations on the petroleum generation potential of bituminous coals from the Saar region     

W. Pickel  G.K.E. Gtz 《Organic Geochemistry》1991,17(6)

The Saar basin contains bituminous coals (high volatile A and B). Five coals of Westphalian and Stephanian age with distinctly varying maceral compositions were analysed by Soxhlet extraction and supercritical extraction with different solvents and microscopically. From the data obtained it is concluded that the oldest coals have a potential for oil generation, whereas the younger coals do not. This conclusion is explained by varying liptinite contents and varying adsorption capacities of different vitrinite macerals for bitumen.  相似文献   

Correlations among the reflectances of vitrinite, chitinozoans, graptolites and scolecodonts     

Rudolf Bertrand 《Organic Geochemistry》1990,15(6)

Paleozoic marine sequences sampled in outcrops and wells of northeastern Gaspe Peninsula (Quebec Appalachians) yield kerogen composed in part of vitrinite and zooclasts (chitinozoans, scolecodonts and graptolites) on which reflectance measurements were made.The comparison between means of random measurements show that reflectance of chitinozoans is similar to that of telinite (vitrinite with a cellular texture) and that the reflectance of scolecodonts is significantly lower than that of telinite in the lower range of studied values. At higher reflectivities differences decrease but, at the end of the condensate gas zone reflectancea are not yet identical. As shown by previous studies, reflectance of graptolites is slightly less than that of telinite.Pyrobitumen reflectance is related to the lithology of the host-rock and no generalized correlation can be established between the reflectance of pyrobitumen and that of vitrinite.  相似文献   

Impact of high water pressure on oil generation and maturation in Kimmeridge Clay and Monterey source rocks: Implications for petroleum retention and gas generation in shale gas systems     

《Marine and Petroleum Geology》2016

This study presents results for pyrolysis experiments conducted on immature Type II and IIs source rocks (Kimmeridge Clay, Dorset UK, and Monterey shale, California, USA respectively) to investigate the impact of high water pressure on source rock maturation and petroleum (oil and gas) generation. Using a 25 ml Hastalloy vessel, the source rocks were pyrolysed at low (180 and 245 bar) and high (500, 700 and 900 bar) water pressure hydrous conditions at 350 °C and 380 °C for between 6 and 24 h. For the Kimmeridge Clay (KCF) at 350 °C, Rock Eval HI of the pyrolysed rock residues were 30–44 mg/g higher between 6 h and 12 h at 900 bar than at 180 bar. Also at 350 °C for 24 h the gas, expelled oil, and vitrinite reflectance (VR) were all reduced by 46%, 61%, and 0.25% Ro respectively at 900 bar compared with 180 bar. At 380 °C the retardation effect of pressure on the KCF was less significant for gas generation. However, oil yield and VR were reduced by 47% and 0.3% Ro respectively, and Rock Eval HI was also higher by 28 mg/g at 900 bar compared with 245 bar at 12 h. The huge decrease in gas and oil yields and the VR observed with an increase in water pressure at 350 °C for 24 h and 380 °C for 12 h (maximum oil generation) were also observed for all other times and temperatures investigated for the KCF and the Monterey shale. This shows that high water pressure significantly retards petroleum generation and source rock maturation. The retardation of oil generation and expulsion resulted in significant amounts of bitumen and oil being retained in the rocks pyrolysed at high pressures, suggesting that pressure is a possible mechanism for retaining petroleum (bitumen and oil) in source rocks. This retention of petroleum within the rock provides a mechanism for oil-prone source rocks to become potential shale gas reservoirs. The implications from this study are that in geological basins, pressure, temperature and time will all exert significant control on the extent of petroleum generation and source rock maturation for Type II source rocks, and that the petroleum retained in the rocks at high pressures may explain in part why oil-prone source rocks contain the most prolific shale gas resources.  相似文献   

海面光谱辐射计系统研制及遥感反射比的测量     

王勇  刘智深  张凯临  黄海龙  吴松华 《中国海洋大学学报(自然科学版)》2001,31(5):795-800

本文报道海面光谱辐射计的研制、定标和海上现场实验测量。运用一个 2 5 6元光电二极管列阵传感器件测量海面离水辐亮度和向下辐照度的光谱分布 ,可计算得出遥感反射比。该仪器所测量的数据可以用于海洋方面相关专业的科学研究 ,并给出海上实验测量数据  相似文献   

关于赤潮水色研究的探讨   总被引：2，自引：0，他引：2  

周良明  刘玉光  郭佩芳 《海洋湖沼通报》2004,25(4):61-67

赤潮是一种经常爆发的海洋现象，现已成为一种世界性的公害。本文利用地物光谱仪和水面之上测量方法测量所得到赤潮海域水色光谱数据，对赤潮的水色特性进行了有益的研究和探讨。通过研究能够得到赤潮对水色影响的一些显著的特征。  相似文献   

大气粉尘气溶胶中铁氧化物的光谱分析   总被引：3，自引：0，他引：3  

沈振兴  张小曳  季峻峰  曹军骥  王亚强  鹿化煜 《海洋地质与第四纪地质》2003,23(1):103-107

首次利用浸反射光谱装置（DRS）对中国大气粉法气溶胶中铁氧化物进行了研究，结果表明，在可见光范围，粉尘样品反射光谱的一阶导数曲线，在435nm和560nm对样品中的针铁矿和赤铁矿有识别指示意义，样品中铁的含量与赤铁矿和针铁矿的一阶导数峰值相关性良好，同时发现，红、登、黄3种颜色的反射率随样品中铁含量的增加而增加，而紫、绿、蓝3种颜色的反射率随样品中铁含量的增加而减少，这表明铁氧化在粉尘气溶胶对可见光的散射和吸收效应中扮演着重要的角色。  相似文献   

东海海域典型赤潮水体反射光谱模拟研究     

何烁  楼绣林  史爱琴  厉冬玲  王隽  张华国 《海洋与湖沼》2019,50(3):525-531

东海原甲藻(Prorocentrum donghaiense Lu)是我国东海海域的典型赤潮藻种,其在水体中通常呈垂直非均匀分布,并存在季节性和日内的垂直迁移现象。本文通过量化垂直迁移过程中东海原甲藻的分布状态,利用Hydrolight软件数值模拟各状态下的水体反射光谱,研究其光谱特征和变化规律。利用叶绿素浓度高斯垂向模型表征东海原甲藻在水体中的垂直分布,结合东海近岸海域二类水体的生物光学模型,模拟得到垂直迁移过程中东海原甲藻赤潮水体的反射光谱。对比分析叶绿素浓度垂向分布参数(背景叶绿素浓度、甲藻主体水层厚度、水体总生物量和叶绿素浓度峰值深度)对水体反射光谱的影响。研究结果表明,在东海原甲藻从次表层向表层垂直向上迁移过程中,水体反射光谱数值在蓝绿波段(400—570nm)减小,在黄红波段(570—720nm)增大,特别是在叶绿素荧光效应波段(680nm)处的变化尤为明显。  相似文献   

近红外偏振辐射卫星数据的海洋耀光动态检测     

陈震霆  孙晓兵  汪俊锋  李树  黄红莲  陈卫  乔延利 《遥感学报》2019,23(2):215-229

太阳光入射海表特定区域形成海洋耀光,呈强反射和偏振特性。在卫星海洋遥感中,海洋耀光对遥感成像质量有较大影响,尤其对海洋上空云、气溶胶及海色等研究干扰较大,因此剔除海洋耀光是卫星遥感数据处理过程中首先要解决的重要问题。以PARASOL卫星的POLDER3载荷数据为研究对象,获取载荷成像时刻太阳及观测几何、海表风速风向及气溶胶光学厚度等参数,采用海气辐射传输相关理论,结合耀光角和多角度NIR偏振辐射信息(865 nm),构建基于近红外偏振辐射特性规则的OGDD模型,获取耀光角临界值实现耀光动态检测。以印度洋某海区为研究对象,获取实测耀光区NIR通道的大气层顶反射率和偏振反射率,利用OGDD模型将耀光角判别临界值调整为34°。相比MODIS经验临界值(40°),标记耀光像元相对减少了30%。结果表明,该方法不仅能通过动态调整临界值准确识别海洋耀光,为云检测及云物理特性反演提供可靠的源数据,还能为高分五号卫星多角度偏振载荷在轨定标及气溶胶反演提供支持。  相似文献   

Reflectance variation in boreal landscape during the snow melting period using airborne imaging spectroscopy     

《International Journal of Applied Earth Observation and Geoinformation》2019

We aim a better understanding of the effect of spring-time snow melt on the remotely sensed scene reflectance by using an extensive amount of optical spectral data obtained from an airborne hyperspectral campaign in Northern Finland. We investigate the behaviour of thin snow reflectance for different land cover types, such as open areas, boreal forests and treeless fells. Our results not only confirm the generally known fact that the reflectance of a melting thin snow layer is considerably lower than that of a thick snow layer, but we also present analyses of the reflectance variation over different land covers and in boreal forests as a function of canopy coverage. According to common knowledge, the highly variating reflectance spectra of partially transparent, most likely also contaminated thin snow pack weakens the performance of snow detection algorithms, in particular in the mapping of Fractional Snow Cover (FSC) during the end of the melting period. The obtained results directly support further development of the SCAmod algorithm for FSC retrieval, and can be likewise applied to develop other algorithms for optical satellite data (e.g. spectral unmixing methods), and to perform accuracy assessments for snow detection algorithms.A useful part of this work is the investigation of the competence of Normalized Difference Snow Index (NDSI) in snow detection in late spring, since it is widely used in snow mapping. We conclude, based on the spectral data analysis, that the NDSI -based snow mapping is more accurate in open areas than in forests. However, at the very end of the snow melting period the behavior of the NDSI becomes more unstable and unpredictable in non-forests with shallow snow, increasing the inaccuracy also in non-forested areas. For instance in peatbogs covered by melting snow layer (snow depth < 30 cm) the mean NDSI -0.6 was observed, having coefficient of variation as high as 70%, whereas for deeper snow packs the mean NDSI shows positive values.  相似文献   

Stormwater plume detection by MODIS imagery in the southern California coastal ocean     

Nikolay P. Nezlin  Paul M. DiGiacomo  Dario W. Diehl  Burton H. Jones  Scott C. Johnson  Michael J. Mengel  Kristen M. Reifel  Jonathan A. Warrick  Menghua Wang 《Estuarine, Coastal and Shelf Science》2008

Stormwater plumes in the southern California coastal ocean were detected by MODIS-Aqua satellite imagery and compared to ship-based data on surface salinity and fecal indicator bacterial (FIB) counts collected during the Bight'03 Regional Water Quality Program surveys in February–March of 2004 and 2005. MODIS imagery was processed using a combined near-infrared/shortwave-infrared (NIR-SWIR) atmospheric correction method, which substantially improved normalized water-leaving radiation (nLw) optical spectra in coastal waters with high turbidity. Plumes were detected using a minimum-distance supervised classification method based on nLw spectra averaged within the training areas, defined as circular zones of 1.5–5.0-km radii around field stations with a surface salinity of S < 32.0 (“plume”) and S > 33.0 (“ocean”). The plume optical signatures (i.e., the nLw differences between “plume” and “ocean”) were most evident during the first 2 days after the rainstorms. To assess the accuracy of plume detection, stations were classified into “plume” and “ocean” using two criteria: (1) “plume” included the stations with salinity below a certain threshold estimated from the maximum accuracy of plume detection; and (2) FIB counts in “plume” exceeded the California State Water Board standards. The salinity threshold between “plume” and “ocean” was estimated as 32.2. The total accuracy of plume detection in terms of surface salinity was not high (68% on average), seemingly because of imperfect correlation between plume salinity and ocean color. The accuracy of plume detection in terms of FIB exceedances was even lower (64% on average), resulting from low correlation between ocean color and bacterial contamination. Nevertheless, satellite imagery was shown to be a useful tool for the estimation of the extent of potentially polluted plumes, which was hardly achievable by direct sampling methods (in particular, because the grids of ship-based stations covered only small parts of the plumes detected via synoptic MODIS imagery). In most southern California coastal areas, the zones of bacterial contamination were much smaller than the areas of turbid plumes; an exception was the plume of the Tijuana River, where the zone of bacterial contamination was comparable with the zone of plume detected by ocean color.  相似文献