Laser Ablation ICP-MS Developments and Trends for 2003     

Paul J. Sylvester 《Geostandards and Geoanalytical Research》2005,29(1):41-52

This annual review of laser-ablation inductively coupled plasma-mass spectrometry (LA-ICP-MS) covers the year 2003. Significant advances were made in understanding laser-sample interactions. In particular, research defined the distribution of particle sizes produced by the interplay of laser wavelength, laser pulse width and the gas environment of ablation. A link between particle sizes and elemental and isotopic fractionation at both the ablation site and in the ICP was established. Experimental 15 7 nm and femtosecond laser systems were tested with promising results. The number of applications of LA-ICP-MS in geology and environmental Earth science continued to grow with particular interest in element concentration and isotope ratio profiling of materials, linking composition to time scales. In situ isotopic ratio measurements were increasingly made using multicollector magnetic sector ICP-MS instruments. Other applications of wide interest included bulk sampling of rocks and ores prepared as lithium borate glasses; low level analysis of platinum-group elements, rhenium and gold in sulfides, metal and silicates; in situ uranium-lead zircon geochronology; and melt and fluid inclusion analysis.  相似文献   

GGR Critical Review of Analytical Developments in 2003     

Janet M. Hergt  L. Paul Bédard  Etienne Deloule  Kathryn L. Linge  Paul J. Sylvester  Michael Wiedenbeck  Jon D. Woodhead 《Geostandards and Geoanalytical Research》2005,29(1):5-52

The articles that comprise this critical review serve to draw attention to research papers published in specific fields of interest during 2003, provide critical comment on the relevance and importance of individual publications in these fields, and offer an overview of the comparative importance of advances in particular areas. In this way, these articles aim to assist experts in the field by keeping them informed of relevant recent publications, as well as providing an important resource for students or early career researchers who are embarking on studies in an area new to them. This year, five papers provide summaries of developments in bulk sample determinations employing (1) ICP-AES and ICP-MS (trace elements), (2) XRF and atomic absorption spectrometry and INAA, (3) isotope ratio measurements (TIMS, MC-ICP-MS, ICP-MS, ToF), as well as in situ measurements conducted using (4) secondary ion mass spectrometry and (5) laser ablation ICP-MS (trace element and isotope ratio determinations).  相似文献   

Determination of Lithium, Beryllium and Boron at Trace Levels by Laser Ablation-Inductively Coupled Plasma-Sector Field Mass Spectrometry   总被引：1，自引：2，他引：1  

Massimo Tiepolo  Alberto Zanetti  Riccardo Vannucci 《Geostandards and Geoanalytical Research》2005,29(2):211-224

The analytical capabilities of laser ablation (LA)-ICP-MS in determining Li, Be and B at trace levels in geological samples have been tested on a series of glass reference materials and natural samples. The LA-ICP-MS instrument used consisted of a sector-field ICP-MS coupled with a laser ablation microprobe operating at either 266 or 213 nm wavelength. Reference glasses from NIST (SRM 612, 614 and 616) and MPI-DING (KL2-G, ML3B-G, StHs6/80-G, GOR128-G, GOR132-G, T1-G and ATHO-G) were selected to develop the analytical method and to assess the best instrumental configuration. A series of calcic amphiboles with different Li, Be and B concentrations were also analysed using both LA-ICP-MS and SIMS to test the applicability of the method to natural minerals. Results indicated that with a spot size of 40 μm the agreement between measured and reference values of Li, Be and B is generally better than 10% for NIST SRM 612 and 20% for NIST SRM 614. Average reproducibility at the 2s level was 10% for Li, 20% for Be and 15% for B. Limits of detection were approximately 100 ng g^-1 for Be and B and 200 ng g^-1 for Li. These results were confirmed by analyses carried out on natural amphiboles and compared well in terms of precision and accuracy with those commonly achieved by SIMS.  相似文献   

Preliminary Characterisation of New Glass Reference Materials (GSA-1G, GSC-1G, GSD-1G and GSE-1G) by Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry Using 193 nm, 213 nm and 266 nm Wavelengths   总被引：5，自引：1，他引：5  

Marcel Guillong  Kathrin Hametner  Eric Reusser  Stephen A. Wilson  Detlef Günther 《Geostandards and Geoanalytical Research》2005,29(3):315-331

New glass reference materials GSA-1G, GSC-1G, GSD-1G and GSE-1G have been characterised using a prototype solid state laser ablation system capable of producing wavelengths of 193 nm, 213 nm and 266 nm. This system allowed comparison of the effects of different laser wavelengths under nearly identical ablation and ICP operating conditions. The wavelengths 213 nm and 266 nm were also used at higher energy densities to evaluate the influence of energy density on quantitative analysis. In addition, the glass reference materials were analysed using commercially available 266 nm Nd:YAG and 193 nm ArF excimer lasers. Laser ablation analysis was carried out using both single spot and scanning mode ablation. Using laser ablation ICP-MS, concentrations of fifty-eight elements were determined with external calibration to the NIST SRM 610 glass reference material. Instead of applying the more common internal standardisation procedure, the total concentration of all element oxide concentrations was normalised to 100%. Major element concentrations were compared with those determined by electron microprobe. In addition to NIST SRM 610 for external calibration, USGS BCR-2G was used as a more closely matrix-matched reference material in order to compare the effect of matrix-matched and non matrix-matched calibration on quantitative analysis. The results show that the various laser wavelengths and energy densities applied produced similar results, with the exception of scanning mode ablation at 266 nm without matrix-matched calibration where deviations up to 60% from the average were found. However, results acquired using a scanning mode with a matrix-matched calibration agreed with results obtained by spot analysis. The increased abundance of large particles produced when using a scanning ablation mode with NIST SRM 610, is responsible for elemental fractionation effects caused by incomplete vaporisation of large particles in the ICP.  相似文献   

Microcrack networks in granite affected by a fault zone: Visualization by confocal laser scanning microscopy     

Celia T. Onishi  Ichiko Shimizu   《Journal of Structural Geology》2005,27(12):170

Microcracks in the Cretaceous Ryoke-type granite in Japan were investigated by using deep drilling core samples collected in the Mizunami Underground Research Project of the Japan Nuclear Cycle Development Institute (JNC). The granite body suffered brittle deformation associated with Tertiary thrust movement. Based on core-scale and microscopic deformation features, the drill core from a depth of 300 to 700 m is divided into four domains, i.e. (A) undeformed granite, (B) granite intruded by cataclastic seams, (C) fractured granite in the fault damage zone, and (D) foliated cataclasite at the fault center. To characterize microcrack geometries in each domain, we employed the impregnation method using a low-viscous acrylic resin doped with fluorescent agents and captured the microcrack images by confocal laser scanning microscopy (CLSM). The CLSM image in the fault damage zone revealed anisotropic development of microcrack networks related to the fault movement. Both CLSM observation and porosity measurements reveal a drastic increase of micro-pores in the foliated cataclasite, possibly caused by fragmentation, and granulation and crack sealing in the fault zone.  相似文献   

徕卡RTC360三维激光扫描仪在竣工测量中的应用     

汪晓慧  吴晓培 《测绘通报》2019,(10):150-154,159

徕卡RTC360不仅操作简单、扫描速度快，而且非常智能。可以实时跟踪计算两个连续站点间的相对位置，点云实时预拼接。后期搭配Register360智能拼接软件，点云智能拼接处理，无需人工干预，简单高效。  相似文献   

利用GLAS激光测高数据评估DSM产品质量及精度优化   总被引：2，自引：0，他引：2  

胡柳茹  唐新明  李国元  付冬暇  窦显辉  赵世湖 《测绘通报》2019,(11):39-43

提出了一种利用卫星激光测高数据直接优化提升数字表面模型（DSM）产品精度的方法。选取境外中亚地区的资源三号DSM开展试验，通过采用多准则约束方法提取激光高程控制点，分别利用偏度、中值、线性、二次多项式等进行DSM误差修正，发现4种模型均能有效消除DSM系统误差，其中基于二次多项式的方法更适用于平地和丘陵地貌，线性模型更适用于高山地貌。试验验证了采用卫星激光测高数据优化境外DSM技术流程的可行性，最终可提高DSM的绝对高程精度。  相似文献   

Tensionless–frictionless interaction of flexible annular foundation with a transversely isotropic multi‐layered half‐space          下载免费PDF全文

Morteza Eskandari‐Ghadi  Ghasem Gorji‐Bandpey  Azizollah Ardeshir‐Behrestaghi  Seyed Masoud Nabizadeh 《国际地质力学数值与分析法杂志》2015,39(2):155-174

A transversely isotropic multi‐layered half‐space, with axis of material symmetry perpendicular to the free surface, supports a flexible either annular or solid circle foundation. The contact area of the foundation and the half‐space is considered to be both frictionless and tensionless. The foundation is assumed to be affected by a vertical static axisymmetric load. Detailed analysis of the interaction of these two systems with different thickness of layers is the target of this paper. With the use of ring load Green's functions for both the foundation and the continuum half‐space, an integral equation accompanied with some inequalities is introduced to model the complex BVP. With the incorporation of ring‐shape FEM, we are capable of capturing both regular and singular solution smoothly. The validity of the combination of the analytical and numerical method is proved with comparing the results of this paper with a number of benchmark cases of both linear and nonlinear interaction of circular and annular foundation with half‐space. Some new illustrations are presented to portray the aspect of the anisotropy and layering of the half‐space. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

三维激光扫描技术下的规划验收测量数据处理及成果获取     

王芬  徐炳前  郝旦 《测绘通报》2019,(4):159-161

三维激光扫描技术由于可快速获取高精度、高密度点云数据，可将拟验收建筑及周边情况几乎完全无差地复制到电脑中，是规划验收测量特别是复杂建筑规划验收测量的理想方法，但是其数据处理一直是影响甚至制约其应用的瓶颈。本文简述了规划验收测量要点，以及三维激光扫描点云数据初步处理流程，并针对制作规划验收测量各类图件的不同需求，提出了分别通过直接取线、切片、投影等方法制作成果图件的工作思路及各方法的特点。但是还需研究和解决海量点云的数据处理，以及根据验收测量特点获得测量成果图件的问题。  相似文献   

基于三维激光扫描技术的钢结构扰度检测及应用     

宋云记  王晓民  王智 《测绘通报》2020,(12):160-163

钢结构在长期荷载及不均匀受力的作用下会产生空间变形，其中扰度是其重要的衡量指标。通常采用全站仪采集钢结构轴线上若干特征点进行分析、计算，由于钢结构特征点难以捕捉，测量存在误差，并且有限的空间离散点难以全面反应钢结构空间变形。本文采用徕卡RTC360三维激光扫描进行钢结构扰度测量；介绍了其作业流程及数据处理方法；利用标靶将各个测站的三维点云拼接成一个整体；采用拟合的方法提取空间特征点及轴线；利用三维点云构建空间模型，并与设计模型进行碰撞分析；可全面地反映钢结构的空间变形情况。  相似文献