Statistical approach to determine the salinized ground water flow path and hydrogeochemical features around the underground LPG cavern,Korea     

Jeongho Lee  Ji‐Hoon Kim  Hun‐Mi Kim  Ho‐Wan Chang 《水文研究》2007,21(26):3615-3626

The ground water flow path of the coastal area in the Yellow Sea, Korea, was interpreted using both the cross‐correlation analysis of hydraulic properties and the principal component analysis (PCA) of ground water chemistry. Data was obtained from observation wells in the underground liquefied petroleum gas (LPG) cavern constructed in the coastal area of Pyeongtaek. Cross‐correlation results showed that the operating pressure became more influenced on artificial factors for the variation of the groundwater level of the study area (45–66% of correlation coefficient) even though its affecting area was limited to the region with fractures or faults, and also showed that the delay time from the variation of operating pressure to the fluctuation of ground water level were relatively long periods (28–31 days). Three hydrogeochemical events (encrusted cement dissolution, host rock dissolution, and seawater intrusion), which were dominantly influenced on ground water quality, could be induced from the result of PCA. Quantitative evaluation for these events using the mixed equation with principal component scores suggest that the dissolution of encrusted cement materials was the predominant factor (39·0% of the total mixed proportion) to change the chemical composition of the seepage water during the ground water flow from the observation wells to the cavern. Integration of the statistical results also imply that ground water flow and hydrogeochemistry were predominantly affected by artificial factors such as cavern operation pressure and dissolution of encrusted cement materials, which were interdependent factors on the observation wells with high cross‐correlation coefficients and pH. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

Kinetics of phosphate adsorption by iron oxyhydroxides in aqueous systems     

S.A. Crosby  G.E. Millward  E.I. Butler  D.R. Turner  M. Whitfield 《Estuarine, Coastal and Shelf Science》1984,19(2):257-270

The rate of uptake of phosphate onto synthetic Fe(III)- and Fe(II)-derived oxyhydroxides has been studied using reaction conditions similar to those encountered in natural waters. Kinetic analyses were carried out on the adsorption profiles and both first-order and second-order conditional rate constants were obtained. The temperature dependence of some of the rate constants was investigated and corresponding apparent activation energies calculated. Similar experiments and analyses were undertaken using Fe from natural sources and in general the conditional rate constants obtained in seawater were in agreement with the synthetic ones. The results of this study are of value when comparing the time scales of adsorption processes in natural waters with the time scales of mixing and advection.  相似文献   

细基江篱繁枝变种在不同水层中的栽培试验     

刘思俭  揭振英  黄天文  邹东嬰  吴镜河 《广东海洋大学学报》1989,(Z1)

本文报道了为改变我国华南沿海目前在半咸淡水塘中进行地播式裁培细基江篱繁枝变种单产低的状况而进行的不同水层夹苗栽培和施肥增产试验,证明了越靠近水面江篱藻体生长越快,越接近底部藻钵生长越差,提出如果在水塘中单纯裁培江篱则水塘深度应保持20～30厘米,如果水深超过1米以上,则应采用浮筏式夹苗栽培,并在水中混养鱼虾等。浸泡施肥试验证明,在短短的40天裁培过程施肥藻体比不施肥藻体增产23％,说明了施肥的重要性。  相似文献   

Sudden enhancement of sedimentation flux of <Superscript>210</Superscript>Pb<Subscript>ex</Subscript> as an indicator of lake productivity as exemplified by Lake Chenghai   总被引：1，自引：0，他引：1  

Guojiang?WanEmail author  Jing’an?Chen  Siqin?Xu  Fengchang?Wu  P.?H.?Santschi 《中国科学D辑(英文版)》2005,48(4):484-496

The fundamental assumption of ²¹⁰Pb sediment dating is the stable flux of ²¹⁰Pb_ex, which was derived from atmosphere and then transferred into sediments via lake water. When the sedimentation rate is relatively constant, the ²¹⁰Pb_ex activity in sediments will be exponentially reduced with sedimentation age. ²¹⁰Pb_ex in lake water is incorporated into sediments mainly via organic particulates. If the sedimentation flux of organic matter in lake water is suddenly increased, ²¹⁰Pb_ex will be significantly deposited and then transferred into sediments. On the one hand such sudden purification effect is obviously unfit for the fundamental assumption of ²¹⁰Pb dating; on the other hand, the sudden enhancement of ²¹⁰Pb_ex flux would be indicative of the conspicuous variation of primary productivity of lake water. This problem will be discussed in accordance with the variation trend of ²¹⁰Pb_ex in the vertical profile of recent sediments of Lake Chenghai, Yunnan Province. The sediment core was collected from the deep-water area of Lake Chenghai in June 1997. The vertical profile of ¹³⁷Cs activity is characterized by a tree-peak pattern. This profile gave reliable ages, and also showed the stability of sediment accumulation in the recent ten years. The vertical profile of ²¹⁰Pb_ex activity displays a specific distribution of peaks, and is similar to the vertical profile of C_org. This phenomenon seems to be related to the mechanism of constraining the transfer of ²¹⁰Pb_ex into lake sediments. The average atomic ratios of H_org/C_org and C_org/N_org in Lake Chenghai sediments are 5.51 and 7.04, respectively, indicating that the organic matter was predominantly derived from the remains of endogenic algae. In terms of the three-stage evolutionary characteristics of organic matter in sediments, i.e., “deposition-de-composition-accumulation”, the sedimentation fluxes (F(C_org)) of organic carbon (C_org) since 1970 were calculated by modeling. The sedimentation fluxes of ²¹⁰Pb_ex (F(²¹⁰Pb_ex)) in different years display good synchronous relations with the sedimentation flux of organic carbon (F(C_org)), especially in the years of 1972–1974 and 1986–1989. The variation of F(C_org) led to the variation of F(²¹⁰Pb_ex); the variation of F(²¹⁰Pb_ex) reflects, to some extent, the historical variation of lake productivity.  相似文献   

Use of microelectrodes for electrochemical measurement of nitric oxide in natural seawater     

张正斌 邢磊蔡卫君  任春艳姜立庆 《中国海洋湖沼学报》2004,22(4):373-380

In this paper, the application of a homemade Nation and Co(Salen) modified platinum microelectrode and an ISO-NOPMC microsensor (World Precision Instruments, USA ) to measure nitric oxide in natural seawater is reported. These two microelectrodes are suitable for the measurement. In natural seawater, the sensitivity and stability of the ISO-NOPMC microsensor are higher than that of the homemade Nation and Co(Salen) modified platinum microelectrode.  相似文献   

Observations and modelling of the travel time delay and leading negative phase of the 16 September 2015 Illapel,Chile tsunami     

Peitao Wang  Zhiyuan Ren  Lining Sun  Jingming Hou  Zongchen Wang  Ye Yuan  Fujiang Yu 《海洋学报(英文版)》2021,40(11):11-30

The systematic discrepancies in both tsunami arrival time and leading negative phase (LNP) were identified for the recent transoceanic tsunami on 16 September 2015 in Illapel, Chile by examining the wave characteristics from the tsunami records at 21 Deep-ocean Assessment and Reporting of Tsunami (DART) sites and 29 coastal tide gauge stations. The results revealed systematic travel time delay of as much as 22 min (approximately 1.7％ of the total travel time) relative to the simulated long waves from the 2015 Chilean tsunami. The delay discrepancy was found to increase with travel time. It was difficult to identify the LNP from the near-shore observation system due to the strong background noise, but the initial negative phase feature became more obvious as the tsunami propagated away from the source area in the deep ocean. We determined that the LNP for the Chilean tsunami had an average duration of 33 min, which was close to the dominant period of the tsunami source. Most of the amplitude ratios to the first elevation phase were approximately 40％, with the largest equivalent to the first positive phase amplitude. We performed numerical analyses by applying the corrected long wave model, which accounted for the effects of seawater density stratification due to compressibility, self-attraction and loading (SAL) of the earth, and wave dispersion compared with observed tsunami waveforms. We attempted to accurately calculate the arrival time and LNP, and to understand how much of a role the physical mechanism played in the discrepancies for the moderate transoceanic tsunami event. The mainly focus of the study is to quantitatively evaluate the contribution of each secondary physical effect to the systematic discrepancies using the corrected shallow water model. Taking all of these effects into consideration, our results demonstrated good agreement between the observed and simulated waveforms. We can conclude that the corrected shallow water model can reduce the tsunami propagation speed and reproduce the LNP, which is observed for tsunamis that have propagated over long distances frequently. The travel time delay between the observed and corrected simulated waveforms is reduced to <8 min and the amplitude discrepancy between them was also markedly diminished. The incorporated effects amounted to approximately 78％ of the travel time delay correction, with seawater density stratification, SAL, and Boussinesq dispersion contributing approximately 39％, 21％, and 18％, respectively. The simulated results showed that the elastic loading and Boussinesq dispersion not only affected travel time but also changed the simulated waveforms for this event. In contrast, the seawater stratification only reduced the tsunami speed, whereas the earth's elasticity loading was responsible for LNP due to the depression of the seafloor surrounding additional tsunami loading at far-field stations. This study revealed that the traditional shallow water model has inherent defects in estimating tsunami arrival, and the leading negative phase of a tsunami is a typical recognizable feature of a moderately strong transoceanic tsunami. These results also support previous theory and can help to explain the observed discrepancies.  相似文献   

杭州苕溪滩涂湿地水质净化技术     

沈士华  胡健敏  陈日泉  严文豪 《湿地科学与管理》2012,8(2):31-32

苕溪位于杭州市余杭区,是区域内的一、二类饮用水源重要保护地,余杭区及杭州部分城区数百万居民的饮用水以及西溪湿地的水源都来自苕溪。阐明了苕溪水质污染原因,分析了利用湿地滩涂净化苕溪水质的可行性及方法。  相似文献   

四川盆地震旦系灯影组白云岩成因   总被引：3，自引：1，他引：2  

金民东  谭秀成  李毕松  朱祥  曾伟  连承波 《沉积学报》2019,37(3):443-454

基于岩芯观察、薄片鉴定、地球化学分析,结合区域地质背景,系统研究了四川盆地震旦系灯影组白云岩成因。岩石学特征分析发现,灯影组白云岩可分为泥粉晶云岩、粒屑云岩、微生物云岩、岩溶角砾云岩4类,其结构类型一般为泥晶—粉晶,说明白云岩化时间较早,为准同生期。地球化学分析表明,灯影组白云岩δ^13C平均值与震旦纪原始海水较为接近,δ^18O值呈现中—高负偏的特征,有序度和Fe、Mn含量相对偏低,Na含量相对较高,稀土元素配分模式则与海水配分曲线类似,表明白云岩化主要受到海源流体的影响。盆地周缘的古陆和水下隆起使盆内海水极易封隔浓缩,盆内发育的富Ca^2+菌藻类可间接提高海水的Mg^2+/Ca^2+比值,加之灯影期干旱炎热的古气候让盆内蒸发作用强烈,可伴生石膏等蒸发性矿物,促进白云石化。综合上述特征,四川盆地灯影组白云岩成因为微生物参与的蒸发海水回流渗透白云石化。  相似文献   

海水冷冻预淡化系统的试验研究     

孙朋元  袁瀚  张继  孙坤元  庞海林 《中国海洋大学学报(自然科学版)》2021,(3)

本文提出了一种基于冷冻脱盐的海水双级冷冻预淡化系统。该系统利用蒸发结晶器对海水进行冷冻,并通过振动分离与洗涤实现冰晶与卤水的分离,以此实现海水的初步脱盐,可作为反渗透淡化的预处理系统。同时,海水冷冻淡化过程中消耗的冷量可重新回收用于空调制冷,淡化成本得以有效降低。本文建立了海水双级冷冻预淡化系统的数学模型,获得了试验系统的关键设计参数,以此搭建了试验平台并完成了试验测试,并对海水双级冷冻预淡化系统进行了经济性分析。试验结果表明:经过海水冷冻预淡化系统,预淡化海水产量可维持在21~27 L/h之间;预淡化海水盐度可从35降低到约11;预淡化过程可回收总冷量7.91 kW;反渗透淡化总成本可降低约33%。  相似文献   

Sea‐level rise impact on fresh groundwater lenses in two‐layer small islands          下载免费PDF全文

Hamed Ketabchi  Davood Mahmoodzadeh  Behzad Ataie‐Ashtiani  Adrian D. Werner  Craig T. Simmons 《水文研究》2014,28(24):5938-5953

The fresh groundwater lenses (FGLs) of small islands can be highly vulnerable to climate change impacts, including sea‐level rise (SLR). Many real cases of atoll or sandy islands involve two‐layer hydrogeological conceptualizations. In this paper, the influential factors that affect FGLs in two‐layer small islands subject to SLR are investigated. An analytical solution describing FGLs in circular islands, composed of two geological layers, is developed for the simplified case of steady‐state and sharp‐interface conditions. An application of the developed model is demonstrated to estimate the FGL thickness of some real‐world islands by comparison with existing FGL thickness data. Furthermore, numerical modelling is applied to extend the analysis to consider dispersion effects and to confirm comparable results for both cases. Sensitivity analyses are used to assess the importance of land‐surface inundation caused by SLR, relative to other parameters (i.e. thickness of aquifer layers, hydraulic conductivity, recharge rate and land‐surface slope) that influence the FGL. Dimensionless parameters are used to generalize the findings. The results demonstrate that land‐surface inundation has a considerable impact on a FGL influenced by SLR, as expected, although the FGL volume is more sensitive to recharge, aquifer thickness and hydraulic conductivity than SLR impacts, considering typical parameter ranges. The methodology presented in this study provides water resource managers with a rapid‐assessment tool for evaluating the likely impacts of SLR and accompanying LSI on FGLs.  相似文献