Preparation of adsorbent with magnesium sulfate and straw pulp black liquor and its phenol adsorption properties     

GUO Lugang）  ））    WANG Haizeng）  * ） Key Laboratory of Marine Chemistry Theory  Technology  Ministry of Education  Ocean University of China  Qingdao  P. R. China ） Institute of Automation of the Chinese Academy of Sciences  Beijing  P. R. China ） Beijing Municipal Institute of Science  Technology Information  Beijing  P. R. China 《中国海洋大学学报(英文版)》2009,8(3):229-232

A magnesia adsorbent was prepared from straw pulp black liquor and magnesium sulfate for the first time, and its adsorption of phenol from aqueous solution was examined. The characteristics of the adsorbent were tested through chemical analysis, surface analysis, X-ray diffraction and FT-IR spectroscopy. The effects of various factors, such as dose, adsorption time and adsorption temperature, on phenol adsorption behavior were studied. The results show that the adsorption processes can be fitted to the isotherm Langmuir model very well. It was found that the adsorption process was strongly influenced by temperature and the optimal temperature for phenol removal was 40 °C. The optimum adsorption time was 10 min, and desorption would happen afterwards. Between the models of Langmuir and Freundlich, the adsorption process of phenol onto magnesia fitted the Langmuir equation better.  相似文献   

Characteristics of heavy metal accumulation on fly ash- and sewage sludge-amended calcific soil     

Huapeng Niu  Shengrong Li  Junfeng Shen  Meijuan Yao 《中国地球化学学报》2012,31(2):181-186

Land disposal of fly ash(FA)and sewage sludge(SS)is a major problem due largely to their potentially harmful constituents.In this paper,a potting experiment was performed to evaluate the effects on the plant growth and to discuss in particular the potential hazard to soils and plants according to the characteristics of heavy metal accumulation and migration when FA and SS are used as the amendments of calcific soil in a limestone mining area. The results showed that the application of FA-SS mixture is capable of accelerating the growth of plants and improving the biomass production at either 1:1 or 1:2 FA-SS mixture:soil(w/w).The highest yields were obtained at 1:1(w/w)mixing ratio.When compared with the Element Background Values of Soils in China,the analysis on heavy metals indicated that the contents of Pb,Cr,Hg,Cd,As,Ni,Cu and Zn in the amended soils came up to the second-class environmental quality standards,only Hg and Cd showed significant accumulation.At the same time, though the metal concentrations in roots were higher than those for the control,the concentrations except Cu,Zn in shoots were lower.And all the heavy metal contents in the plants were substantially lower than the toxicity limits. The results indicated that the combined use of FA and SS at a rational rate of application should pose no danger to both soil and food chain based on the characteristics of the FS and SS,heavy metals and calcific soil.  相似文献   

JSCORS系统在太湖底泥勘探测量中的应用          下载免费PDF全文

朱前维  秦建国 《江苏地质》2010,34(1):41-45

从分析JSCORS系统技术特点入手,阐述了JSCORS系统的使用流程,并以竺山湖及西沿岸区北段底泥勘探测量为例叙述了在此工程中的使用过程,从使用过程中体会到JSCORS的系统在勘探测量中的巨大作用,因其覆盖范围广、效率高、劳动强度底、使用简便等特点在勘探测量单位广泛推广,JSCORS系统的使用是对勘探测量技术的又一次提升。  相似文献   

Mercury speciation in sediments at a municipal sewage sludge marine disposal site   总被引：3，自引：0，他引：3  

Shoham-Frider E  Shelef G  Kress N 《Marine environmental research》2007,64(5):601-615

Mercury speciation was performed in excess activated sewage sludge (ASS) and in marine sediments collected at the AAS disposal site off the Mediterranean coast of Israel in order to characterize the spatial and vertical distribution of different mercury species and assess their environmental impact. Total Hg (HgT) concentrations ranged between 0.19 and 1003ng/g at the polluted stations and 5.7 and 72.8ng/g at the background station, while the average concentration in ASS was 1181+/-273ng/g. Only at the polluted stations did HgT concentrations decrease exponentially with sediment depth, reaching background values at 16-20cm, the vertical distribution resulting from mixing of natural sediment with ASS solids and bioturbation by large populations of polycheates. Average Methyl Hg (MeHg) concentration in ASS was 39.7+/-7.1ng/g, ca. 3% of the HgT concentration, while the background concentrations ranged between 0.1 and 0.61ng/g. MeHg concentrations in surficial polluted sediments were 0.7-5.9ng/g (ca. 0.5% of the HgT) and decreased vertically, similar to HgT. A positive correlation between MeHg and Hg only at the polluted stations, higher MeHg concentrations at the surface of the sediment and not below the redoxline, and no seasonality in the concentrations suggest that the MeHg originated from the ASS and not from in situ methylation. By doing selective extractions, we found that ca. 80% of the total Hg in ASS and polluted sediments was strongly bound to amorphous organo-sulfur and to inorganic sulfide species that are not bioavailable. The fractions with potential bioaccessible Hg had maximal concentrations in the range in which biotic effects should be expected. Therefore, although no bioaccumulation was found in the biota in the area, the concentration in the polluted sediments are not negligible and should be carefully monitored.  相似文献   

断层带常用钻进施工工艺     

黄会 《城市地质》2013,(4):57-59

某矿区主要以辉钼矿为主,同时伴生有黄铁矿和少许铅锌矿。该矿区地层复杂,断层较多,主要施工难点是粉碎型破碎带和含断层泥与角砾的断层带。针对该复杂地层,选择合适的钻进施工工艺,能够有效的减少事故率和提高钻进效率。  相似文献   

高含水率淤泥生石灰材料化土击实方法初探   总被引：3，自引：0，他引：3  

桂跃  杜国庆  张勤羽  宋文智  蔡超 《岩土力学》2010,31(Z1):127-137

为了击实高含水率淤泥生石灰材料化土,通过改进标准击实仪,设计了4种不同击实冲量的击实情形,对不同掺灰比的材料化土在不同闷料期进行击实试验,分析了击实冲量及击实功与淤泥生石灰材料化土干密度的关系,提出了材料化土的击实方法及击实评价方法。建议根据材料化土的含水比 选择击实冲量适宜的击实方法,通过土的干密度随击次变化规律判断材料化土是否击实。特别从工程角度出发,测试了击实材料化土不同龄期的无侧限抗压强度,初步探讨了高含水率疏浚淤泥生石灰材料化土作为工程填料的可行性。  相似文献   

Statistical Optimization of Anaerobic Biological Processes for Dye Treatment     

Zahra Khalili  Babak Bonakdarpour 《洁净——土壤、空气、水》2010,38(10):942-950

In the present study both the synthetic media composition as well as some process parameters in the anaerobic decolorization of Reactive Black 5 (RB5) by activated sludge were studied and optimized using statistical design of experiments (DOEs). Statistical analysis of the results of Plackett–Burman DOE showed that the addition of Mn or Fe, or increase in concentration of Mg, had a positive effect on the anaerobic decolorization efficiency whereas the effect of increase in concentration of glucose, ammonium chloride, and calcium chloride was negative. The effect of change in the concentration of glucose, mixed liquor suspended solid (MLSS), and RB5 on the anaerobic decolorization efficiency and rate and chemical oxygen demand (COD) removal was studied using central composite design methodology. Statistical analysis of the data showed that all the factors had significant effect on both the dye decolorization efficiency and rate. The interaction of glucose with MLSS and with dye and the interaction of MLSS with glucose and with dye were significant when the response was decolorization efficiency and rate, respectively. When COD removal was the response, the effect of change in glucose and MLSS concentration and the interaction between these two factors had statistically significant effect on the response.  相似文献   

改性污泥复合材料时间效应三轴力学特性试验研究     

徐正明  薛强  赵颖 《岩土力学》2011,32(6):1713-1718

采用水玻璃、生石灰和絮状木质纤维作为污泥改性剂对城市污泥改性后,在不同养护龄期和不同改性剂配比下对改性污泥复合材料开展三轴固结不排水力学强度和破坏特征试验研究。改性剂设置3种配比5%、10%和15%,在相同围压下,养护5 d改性污泥复合材料破坏强度相对于原污泥相应地提高到1.25～1.426、1.12～1.33、1.2～1.5;养护10 d分别提高到1.33～1.45、1.154～1.35、1.56～1.67,改性剂配比5%和10%试验比15%硬化速度较快。养护10 d改性污泥在主应力差为20 kPa时,初始切线模量发生很大的突变,并且10%和15% 组有3%～5%应变延时期。养护10 d时5%和10%配比的试样内摩擦角 值大于15%配比的试样,而黏聚力 值明显小于15%配比的试样。基于Konder应力-应变双曲线方程,利用主应力差渐近值作为归一化因子,建立改性污泥在三轴固结不排水条件下的主应力差-应变关系方程  相似文献   

Influence of Soil Aging and Stabilization with Compost on Zn and Cu Fractionation,Stability, and Mobility          下载免费PDF全文

Zygmunt Mariusz Gusiatin  Dorota Kulikowska 《洁净——土壤、空气、水》2016,44(3):272-283

  相似文献   

Assessing Environmental Impacts of Wastewater Treatment Alternatives for Small‐Scale Communities     

Mustafa Yıldırım  Bülent Topkaya 《洁净——土壤、空气、水》2012,40(2):171-178

The effluents of wastewater treatment plants in small sized communities of less than 2000 population equivalent (PE), which are discharged into sensitive receiving water environments, must receive “appropriate treatment” according to the EU Urban Wastewater Treatment Directive. Appropriate treatment depends on the quality objectives of the receiving waters as well as the relevant provisions of the member states. In this study, wastewater treatment options, such as vegetated land treatment (VLT), constructed wetlands (CW), and activated sludge treatment (AST), by which effluents are discharged to sensitive and less sensitive areas are evaluated by the life cycle assessment (LCA) approach. For this purpose, data related to energy usage, land requirement, raw material consumption, and released emissions from the life phases were collected with an inventory study and the environmental impacts were assessed by using SimaPro 7.1 LCA software. The results obtained from the assessments were compared with each other, which indicated that for small‐scale communities VLT and CW are the most environmentally friendly wastewater treatment option.  相似文献