云南磷铝石谱学特征研究   总被引：1，自引：0，他引：1  

魏中枢  狄敬如 《岩石矿物学杂志》2018,37(1):169-174

使用电子探针、X射线粉晶衍射仪、傅里叶变换红外光谱仪、激光拉曼光谱仪、紫外可见分光光度计等仪器,对最近在云南发现的一种达到宝石级别的磷铝石进行了化学成分、矿物组成、红外吸收光谱、拉曼光谱、紫外可见吸收光谱等方面的研究。化学成分分析结果表明,该磷铝石的主要化学成分为P和Al,并含有少量的Fe和V;X射线粉晶衍射结果显示,该磷铝石的矿物成分主要为磷铝石,杂质较少;红外光谱与拉曼光谱分析均检出磷酸根基团的特征峰,红外光谱分析还显示有结晶水与结构水的存在;紫外可见吸收光谱在300和420 nm附近的吸收归属于Fe3+,630 nm附近较宽缓的吸收带由Fe3+和V3+共同产生。并将磷铝石与绿松石进行了谱学方面的对比分析,以便更好地区分两者。  相似文献   

河南产宝石级高温高压合成钻石的谱学特征及电磁性研究     

杨池玉  陆太进  张健  宋中华  陈华  柯捷  何明跃 《岩矿测试》2021,(2):217-226

为快速鉴定高温高压(HPHT)合成钻石,前人已开展了系统的发光特征和谱学特征研究,但对比性分析较少,且对电学性质和磁学性质关注不多。本文结合常规宝石学观察、高精度谱学测试以及导电性和磁性测试,对49粒无色、黄色样品进行了深入研究和对比分析。结果表明:①铁、钴、镍等金属元素的触媒残余是HPHT合成钻石的磁性来源,测试样品均能被磁强达到12000Gs的磁棒吸引。②无色HPHT合成钻石为Ⅱa+Ⅱb型钻石,硼元素的存在导致其具有良好的导电能力,且随着硼含量的增多,导电能力逐渐增强;黄色样品为Ⅰb+ⅠaA型钻石,约三分之一的孤氮转化为A集合体,揭示合成钻石在生长完成后经过了高温退火处理。③硼元素的普遍存在,以及氮元素主要以孤氮原子和A集合体的方式存在,导致了HPHT合成钻石的特征红外光谱;HPHT合成钻石中常含有氮、镍、硅等杂质元素引起的晶格缺陷,导致了特征的光致发光光谱。④无色HPHT合成钻石具有强蓝绿色荧光和磷光,黄色HPHT合成钻石具有绿色荧光,可见明显的立方体-八面体分区现象。本研究表明:谱学特征和发光特征仍然是筛查鉴定HPHT合成钻石的重要依据。现生长技术下合成的HPHT合成钻石在导电性和磁性两方面也与天然钻石存在明显差异,可以作为快速鉴定合成钻石的辅助性依据。  相似文献   

高山区雪堆储雪的实验和模拟计算     

王兴  王飞腾  任贾文  秦大河 《冰川冻土》2021,43(6):1617-1627

随着全球气候变暖,滑雪运动呈现出对气候变化高度的敏感性和依赖性,各地滑雪季将不同程度地缩短。储雪作为一种应对气候变化的方法在雪务保障中逐渐得到研究和应用。在新疆阿勒泰地区吉木乃县开展储雪实验,应用谐波反应法研究了雪堆融化量与外界空气温度、太阳辐射和绝热保温结构热学性能之间的定量关系。实验中,覆盖两层绝热保温材料雪堆1的平均融化量为18.0 kg·d^-1（相当于初始质量的0.85%）,未覆盖绝热保温材料雪堆2的平均融化量为120.8 kg·d^-1（相当于初始质量的6.67%）。模拟期间观测到的雪堆1质量减少了1 438.0 kg,对应的模拟值为1 520.8 kg。谐波反应法可以为评价绝热保温结构的热学性能和提前确定储雪量提供重要的参考依据。由于许多物理过程都未考虑,导致模拟的雪堆融化量与实际融化量之间存在不确定性。雪堆所用绝热保温结构的性能可以用反射率、总传热系数、衰减度和延迟时间来衡量。  相似文献   

微动技术在堤坝渗漏探测中的应用     

贾慧涛  刘杨  盛勇 《江苏地质》2021,45(3):335-340

堤坝是重要的水利工程,其安全性至关重要。坝体渗漏是常见的安全隐患之一,对坝体渗漏位置、程度以及坝体结构变化的探测一直是重要的物探课题。微动勘探作为一种新兴的物探手段,应用范围正逐步拓展,通过某水库大坝渗漏检测实例,展示频率-波数法微动线性点阵剖面测量进行大坝渗漏检测的效果,该技术通过提取频散曲线及视S波速度成像,刻画地层速度结构并圈定异常,可实现对大坝渗漏快速精确的无损探测,具有一定的方法优势和广泛的应用前景。  相似文献   

两次强降水过程雨滴谱特征及差异     

李侠丽  潘先洁  童应祥  倪婷  黄国贵  李景安  陶杰  姚祎  凌新锋 《气象科技》2019,47(2):322-328

利用寿县观测站内的Parsivel激光雨滴谱仪结合观测站雨量数据及雷达基数据,分析了发生在2015年6月26—30日梅雨期间和2015年8月7—10日超强台风"苏迪罗"影响期间2次强降水过程的雨滴谱结构特征及其差异,拟合了雨强与雷达反射率因子之间的关系。结果表明:雨强的大小直接影响雨滴谱的特征参量,且随着雨强增大而增大;梅雨锋暴雨中1.0mm直径≤1.5mm的粒子所占比例最多,雨强贡献率最大;台风雨中0.75mm直径≤1.0mm的粒子所占比例最多,但1.0mm直径≤1.25mm的粒子对雨强的贡献最大,说明较大粒子对强降水的贡献较大。  相似文献   

基于光谱复原的NMF遥感图像融合改进算法          下载免费PDF全文

马一薇  冯伍法  祝鹏飞  张斌 《海洋测绘》2010,30(1):41-43

在研究了非负矩阵分解(NMF)用于遥感图像融合技术的基础上,改进了一种基于光谱复原的NMF遥感图像融合算法,首先利用矩阵非负性分解求取图像的基向量矩阵,然后综合考虑图像融合后的光谱特性和波形变化情况,对基向量矩阵进行直方图规则化处理,最后得到融合后的图像。实验结果表明,该方法具有较好保持原始图像的光谱信息和空间信息的优点。  相似文献   

Effect of slow-solvent-vapour treatment on performance of polymer photovoltaic devices     

冯志慧  侯延冰  师全民  刘小君  滕枫 《海洋学报(英文版)》2010,29(9)

In this work, enhanced poly(3-hexylthiophene):[6,6]-phenyl-C61-butyric acid methyl ester (P3HT:PCBM) bulk-heterojunction photovoltaic devices are achieved via slow-solvent-vapour treatment. The correlations between the morphology of the active layer and the photovoltaic performance of polymer-based solar cell are investigated. The active layers are characterized by atomic force microscopy and optical absorption. The results show that slow-solvent-vapour treatment can induce P3HT self-organization into an ordered structure, leading to the enhanced absorption and efficient charge transport.  相似文献   

A generalized conditional intensity measure approach and holistic ground‐motion selection     

Brendon A. Bradley 《地震工程与结构动力学》2010,39(12):1321-1342

A generalized conditional intensity measure (GCIM) approach is proposed for use in the holistic selection of ground motions for any form of seismic response analysis. The essence of the method is the construction of the multivariate distribution of any set of ground‐motion intensity measures conditioned on the occurrence of a specific ground‐motion intensity measure (commonly obtained from probabilistic seismic hazard analysis). The approach therefore allows any number of ground‐motion intensity measures identified as important in a particular seismic response problem to be considered. A holistic method of ground‐motion selection is also proposed based on the statistical comparison, for each intensity measure, of the empirical distribution of the ground‐motion suite with the ‘target’ GCIM distribution. A simple procedure to estimate the magnitude of potential bias in the results of seismic response analyses when the ground‐motion suite does not conform to the GCIM distribution is also demonstrated. The combination of these three features of the approach make it entirely holistic in that: any level of complexity in ground‐motion selection for any seismic response analysis can be exercised; users explicitly understand the simplifications made in the selected suite of ground motions; and an approximate estimate of any bias associated with such simplifications is obtained. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

The form of the asymptotic depth-limited wind-wave spectrum: Part III — Directional spreading     

I.R. Young 《Coastal Engineering》2010

The directional spreading of both the wavenumber and frequency spectra of finite-depth wind generated waves at the asymptotic depth limit are examined. The analysis uses the Wavelet Directional Method, removing the need to assume a form for the dispersion relationship. The paper shows that both the wavenumber and frequency forms are narrowest at the spectral peak and broaden at wavenumbers (frequencies) both above and below the peak. The directional spreading of the wavenumber spectrum is bi-modal above the spectral peak. In contrast, the frequency spectrum is uni-modal. This difference is shown to be the result of energy in the wind direction being displaced from the linear dispersion shell. A full parametric relationship for the directional spreading of the wavenumber spectrum is developed. The analysis clearly shows that typical dispersion relationships are questionable at high frequencies and that such effects can be significant. This result supports greater attention being focussed on the routine recording of wavenumber spectra, rather than frequency spectra.  相似文献   

On the magnetic field diffusion in mhd modeling of the inner coma of comet halley     

M. D. Kartalev  V. I. Nikolova 《地球物理与天体物理流体动力学》2013,107(1-2):145-168

Abstract

Some approaches of one-dimensional time-dependent magneto-hydrodynamic modeling of the structure of the inner coma of comet Halley are considered. The influence of the magnetic field diffusion on this structure is studied. The solution of Cravens (1989) approach containing classic magnetic diffusion is compared with an approach containing a specific diffusion, caused by non-instantaneous mass-loading of new ions. A case with no magnetic field is also considered. Common features of all the solutions are obtained. Special attention is paid to the sharp velocity jump, synchronized with a local density pick. Some differences between two types of magnetic field diffusion are discussed. A possible connection is supposed between this consideration and the large-scale shock fitting modeling of the solar plasma-comet interaction.  相似文献