Elevated curing temperature-associated strength and mechanisms of reactive MgO-activated industrial by-products solidified soils     

Dongxing Wang  Xiangyun Gao  Ruihong Wang  Stefan Larsson  Mahfoud Benzerzour 《Marine Georesources & Geotechnology》2020,38(6):659-671

Abstract

Alkali-activated industrial by-products (granulated blast furnace slag, Class F fly ash) by traditional alkali activator (such as NaOH and Na₂SiO₃) serves as a partial replacement for Portland cement in soil stabilization projects and suffers from environmental and technical problems. Reactive MgO – a greener and more practical alternative has recently emerged as a potential activator for slag and fly ash, but its micromechanisms of alkaline activation still need to be deeply investigated for strength improvement of soils. Hence, this study focuses on the strength and hydration properties of reactive MgO-slag and MgO-fly ash solidified soils, especially incorporating the impact of elevated curing temperature. Reactive MgO is proved to be excellent as a novel activator for activation of slag and fly ash, and their activating efficiency increases with elevated curing temperature that helps to remarkably enhance the compressive strength of soils. The major hydration products for reactive MgO-slag solidified soils, detected jointly by X-ray diffraction, scanning electron microscopy and thermogravimetric/differential thermogravimetric tests, are calcium silicate hydrate gels and hydrotalcite-like phases. The primary hydration products for MgO-fly ash solidified soils are magnesium silicate hydrate gels and Mg(OH)₂. That is just the intrinsic reason why the microstructure of solidified soils becomes much denser and the mechanical behavior is significantly improved. The minor carbonate phases such as magnesium carbonate and/or calcite are also observed in reactive MgO-slag and MgO-fly ash solidified soils, depending on the period of exposure to air. The curing temperature and binder amount are proved to be the two major factors governing the hydration process of reactive MgO-slag and MgO-fly ash blends. A higher curing temperature and binder amount can generate more hydration products, but their chemical compositions such as accurate element ratios need to be investigated in the future study.  相似文献   

台风暴雨矿渣型泥石流形成机制与动力特征——以兴宁乌石坑沟泥石流为例     

黄家华  冯文凯 《地质论评》2023,69(4):1387-1397

受台风“尤特”登陆影响,台风暴雨直接激发兴宁乌石坑沟特大矿渣型泥石流灾害,物源巨大,潜在危害极大。笔者等通过现场调绘及室内试验,对本次泥石流的形成机制及动力特征进行研究,旨在为此类泥石流致灾机理及危害性评价提供借鉴。研究表明,其独特的流域地形特点为泥石流形成的基本因素,以沟道堆积物为主的丰富矿渣型物源是基础条件,高强度的台风暴雨是直接激发因素,与矿山开采、矿渣随意堆放等人为因素共同作用扩大了灾害规模。泥石流形成过程与动力特征为前期强降雨—崩滑碎屑流—矿渣型泥石流—台风暴雨—沟道堵塞雍高—溃决、规模放大。  相似文献   

X射线荧光光谱-X射线衍射-红外光谱联用技术鉴别锰矿与锰冶炼渣     

武素茹  宋义  谷松海  郭芬  孙鑫 《岩矿测试》2015,34(6):659-664

鉴别锰矿与锰冶炼渣对于锰矿进口贸易和环境保护具有重要意义,由于锰冶炼渣与一些锰矿具有相似的元素组成,都含有锰和硅铝镁钙等杂质元素,仅从元素含量的高低无法准确将其鉴别。本文按国别收集我国主要进口锰矿及不同工艺的主要锰冶炼渣作为研究样品,应用X射线荧光光谱、X射线衍射及傅里叶变换红外光谱技术相结合,建立了锰矿与锰冶炼渣的鉴别方法。在元素组成上,锰冶炼渣的硅含量较高,水淬渣和空气冷却渣的钙含量较高。在物相上,锰矿的特征物相包括软锰矿、氧化锰、方锰矿、菱锰矿等;而锰冶炼渣因为经过冶炼的过程存在硅酸铁、锰橄榄石等特征峰,从而对样品属性进行鉴别。红外光谱显示,锰矿在600~400 cm~(-1)范围内有两个强吸收带,并单独或者同时在1420 cm~(-1)处有特征吸收峰;而锰冶炼渣在960 cm~(-1)左右有宽强吸收峰。本法建立了锰矿的物相谱图库及锰冶炼渣的物相特征,并充分利用红外光谱技术作了有力佐证,确定了锰矿及其冶炼渣的主要区别点。  相似文献   

化学激发酸性矿渣粉胶砂性能试验研究          下载免费PDF全文

袁俊航  隆威 《探矿工程》2015,42(8):71-74

以28天最优配方激发酸性矿渣粉为胶凝材料进行试验,分析了质量浓度、灰砂比、减水剂掺量、搅拌时间4个因素对砂浆流动度、失水率、干缩率、抗压强度的影响规律,并且针对灰砂比这一因素将水泥与矿渣粉胶凝材料浆液性能进行了对比。最后选取了合适的比例进行正交试验来优化各因素组合,使砂浆综合性能达到最优。  相似文献   

红层泥岩地区抗浮锚杆施工改进工艺探讨     

贾欣媛  岳大昌  李明  唐延贵 《岩土工程技术》2019,(3):134-137

红层泥岩是比较特殊的一类岩土体,在该类地层中进行抗浮锚杆施工时,因红层泥岩具有遇水软化强度降低、破碎后在锚孔内易形成含水量较高的塑性泥土、泥浆附着于孔壁影响锚固体强度、进入大气形成扬尘污染环境等不良特性,常导致地基土承载力受到扰动、锚固体抗拔承载力不足、施工现场作业环境恶劣等问题。针对以上难题,秉承因地制宜、绿色环保的原则对施工工艺进行了改进,并通过应用实例验证了改进工艺的可行性,改进后的抗浮锚杆施工工艺具有极好的推广价值,能够为今后类似工程的建设提供一定的参考和借鉴。  相似文献   

转炉炉衬溅渣层蚀损的工艺岩石学研究     

崔淑贤  佟溥翘 《矿物岩石地球化学通报》1999,(4)

转炉溅渣护炉技术对提高转炉炉龄成绩显著。如宝钢３００吨转炉炉龄已超过１４００１炉,武钢８０吨复吹转炉炉龄已达到１１０００炉以上,均为溅渣前的三四倍。该技术是将出钢后残留的钢渣经调整成分后,以高压氮气喷吹,使渣滴飞溅到炉衬上,形成涂敷于炉壁上的溅渣层以保护炉衬延长其寿命。本工作的目的是通过试验室试验,研究溅渣层蚀损机理,为企业开展和推广此项技术提供可靠的工艺参数。１　影响溅渣层抗蚀损能力的因素为了能经受冶炼过程中各个不同时期钢渣的熔蚀以保护炉衬,溅渣层必须具备一定的耐火性和强固性。研究认为,溅渣层…  相似文献   

转炉高温熔渣显微结构研究     

佟溥翘  崔淑贤  丁永良 《矿物岩石地球化学通报》1999,(4)

传统的炉渣岩相分析方法是在显微镜下观察其冷凝渣的岩相结构,并以此来推测该炉渣在高温下的行为。但炉渣在由熔融态逐渐冷却的过程中,会发生物理、化学变化,故用冷凝渣结构来反映炉渣高温状态是有缺陷的。为此,试用热台高温显微镜进行了炉渣高温显微结构研究,并与冷凝渣进行了对比。１　研究方法１－１　试验设备采用英国１２Ｄ型热台高温显微镜,进行了高温熔渣研究。该高温显微镜是以热电偶、发热体和样品支架为一体的微型高温炉为主体,ＰｔＲｈ热丝炉可迅速将约０－１ｍｇ试样加热到１６５０℃以上,并可利用放大５０倍的显微镜…  相似文献   

Remanent Magnetization in Portland-Cement-Based Materials     

Bidegain  J.C.  Sinito  A.M.  Rodriguez  M.E. 《Studia Geophysica et Geodaetica》1999,43(3):289-302

The purpose of this research is to demonstrate the possibility of applying one geophysical method to studying untraditional systems as is the case with Portland-cement-based materials. The research demonstrates how conventional paleomagnetic methodology can be employed in studying the mode of magnetic recording in present-day industrial materials. Portland-cement admixtures such as fly ashes and furnace slags should be discriminated, because those particles interact in soils and sediments in nature. Moreover, a better undertanding of magnetic remanent acquisition in model materials can serve to improve the interpretation of magnetic remanent acquisition in natural rocks formed a long time ago. The magnetic constituents of Portland-cement paste and mortar acquire a magnetic remanence due to their alignment with the earth's magnetic field at the casting place. This magnetization can be measured using ordinary paleomagnetic techniques. The alignment of the individual magnetic particles accounts for the intensity of the magnetic remanence, which can be increased by adding water and by vibration before setting and hardening. Blast furnace slag admixtures also add to the enhancement of the intensity of remanence. The magnetization of Portland-cement-based materials shows a near linear relationship with the water /cement (w/c) ratios employed in the experimental work; the w/c ratios range between 0.2 – 0.6 in pastes and 0.3 – 0.6 in mortar. Stable remanent magnetization was obtained during the first seven days of setting and hardening, a period necessary for magnetic particles to become locked parallel to the earth's magnetic field. The stability of magnetic remanence predicts the usefulness of the methodology in studying the properties of Portland cement and particularly in the control of iron-bearing admixtures.  相似文献   

活性MgO碱性激发粒化高炉矿渣固化黏土的抗硫酸盐侵蚀试验研究     

于博伟  杜延军  刘辰阳  薄煜琳 《岩土力学》2015,36(Z2):64-72

通过系列室内试验,研究了硫酸盐长期浸泡环境下GGBS-MgO固化黏土的物理和力学性质及微观特征变化规律,并与水泥固化黏土进行对比,揭示了GGBS-MgO固化黏土抵抗硫酸盐侵蚀的机制。与水泥固化黏土相比,硫酸盐浸泡条件下GGBS-MgO固化黏土表面完整度较好;质量变化率在浸泡120 d时仅为水泥固化黏土的0.25倍;固化黏土体pH略小于同期水泥固化黏土;浸泡初期GGBS-MgO固化黏土强度增长达20%,同周期时无侧限抗压强度较水泥固化黏土高15%～80%。X射线衍射试验（XRD）表明,硫酸盐侵蚀下GGBS-MgO固化黏土中水化硅酸钙（C-S-H凝胶）的峰值高于水泥固化黏土,而钙矾石（AFt）的XRD图谱峰值明显低于水泥固化黏土。电镜扫描试验结果表明,两种固化黏土中钙矾石形态明显不同：钙矾石在水泥固化黏土中以团聚型晶体存在,可具较强膨胀性,而在GGBS-MgO固化黏土中则以细短形态分布于颗粒间,可有效填充试样孔隙,使其具备良好的抗硫酸盐侵蚀能力。  相似文献   

X-射线荧光光谱法测定高炉渣和电炉渣中8种常见元素     

伊志宏  于想琼 《华东地质学院学报》2000,23(4):349-350

研究了借助熔片法制样,将高炉渣、电沪渣两种基体建于同一组工作曲线。所获曲线线性良好。分析结果与标准值或湿分析值吻合。  相似文献