联合机制下黏土垫层多离子扩散模型     

张志红  韩林  吕清硕 《岩土力学》2022,43(2):539-548

扩散是工程领域中的一种重要现象,尤其是针对填埋场底部的压实黏土垫层。扩散过程受多种因素影响,如离子种类、离子价态和离子浓度等,因此建立准确的扩散模型对填埋场垫层系统设计和评估具有极其重要的意义。引入简化的Guntelberg活度系数表示真实溶液与理想溶液浓度值的偏差,采用化学势和扩散势共同表征多离子扩散的驱动力,并考虑黏土介质特有的半透膜性能对离子扩散规律的影响,建立了复杂机制联合作用下多组分并存时离子在黏土垫层中的扩散模型。采用多物理场仿真软件COMSOL Multiphysics对所建扩散模型进行数值求解,结果表明,黏土半透膜效应、溶液非理想性和扩散势均显著影响多离子扩散行为,考虑黏土半透膜效应及溶液非理想性条件下,多离子扩散进程明显减缓,考虑扩散势时,阳离子扩散速度显著提高。复杂机制联合作用下,多离子扩散规律并非单一影响机制的简单叠加,各机制之间相互制约共同影响多离子扩散行为。  相似文献   

绿柱石中铁离子的晶格占位及致色作用     

吴晓  韩孝朕  冯锡淇  郭守国 《岩石矿物学杂志》2023,42(4):577-590

绿柱石族宝石颜色丰富,一直是市场上重要的宝石品种。几十年来,国内外学者对不同颜色绿柱石的致色机理及改色工艺开展了广泛的研究。铁离子作为重要的致色过渡金属离子之一,其价态调控是绿柱石改色工艺的关键,所以铁离子的价态、晶格占位和对应的致色作用也一直是绿柱石研究的焦点。铁离子被认为可能存在于绿柱石中的铝氧八面体Al³⁺格位、硅氧四面体Si⁴⁺格位、铍氧四面体Be²⁺格位、结构通道2a或2b位和晶格间隙6g位等位置,是蓝、绿或黄等颜色绿柱石的主要致色元素。本文通过对绿柱石的晶体结构、铁离子的核外电子排布和晶格占位等方面文献资料的梳理及综合分析,认为Fe²⁺和Fe³⁺分别对蓝色和黄色绿柱石的呈色起着主导作用。当Fe²⁺和Fe³⁺处于晶格中不同位置时致色作用的具体差异,仍有待于进一步研究。  相似文献   

Low frequency variations in currents on the southern continental shelf of the Caspian Sea     

《Dynamics of Atmospheres and Oceans》2019

The Caspian Sea (CS) is the largest enclosed basin in the world, located inside the Eurasian continent in the Northern Hemisphere. Although there have been few studies of the dynamics of the coastal zone in the CS, observations show that oscillations with periods from 2–3 days to 1–3 weeks dominate. These oscillations are presumed to be related to the synoptic variability of direct wind impact and to coastally-trapped waves (CTW). Here, we describe and interpret current meter observations on the continental margins of the southern CS from 2012 to 2014 to identify and characterize CTW there. Time series analysis provides evidence for both remote and locally wind-forced eastward traveling signals with time lags consistent with CTW theory. A wind-forced model with two CTW modes is able to reproduce the structure, amplitudes, and phases of observed alongshore current fluctuations, explaining half of the variance at frequencies less than 1 cpd. Remote forcing effects are present at all times, but are most striking when the local winds are weak, as in summer. The CTW calculations also suggest that the source region for the remote forcing may extend farther north along the west coast of the CS.  相似文献   

Heavy ion formation in Titan's ionosphere: Magnetospheric introduction of free oxygen and a source of Titan's aerosols?     

E.C. Sittler Jr.  A. Ali  J.F. Cooper  R.E. Johnson  D.T. Young 《Planetary and Space Science》2009,57(13):1547-17884

Discovery by Cassini's plasma instrument of heavy positive and negative ions within Titan's upper atmosphere and ionosphere has advanced our understanding of ion neutral chemistry within Titan's upper atmosphere, primarily composed of molecular nitrogen, with ~2.5% methane. The external energy flux transforms Titan's upper atmosphere and ionosphere into a medium rich in complex hydrocarbons, nitriles and haze particles extending from the surface to 1200 km altitudes. The energy sources are solar UV, solar X-rays, Saturn's magnetospheric ions and electrons, solar wind and shocked magnetosheath ions and electrons, galactic cosmic rays (GCR) and the ablation of incident meteoritic dust from Enceladus’ E-ring and interplanetary medium. Here it is proposed that the heavy atmospheric ions detected in situ by Cassini for heights >950 km, are the likely seed particles for aerosols detected by the Huygens probe for altitudes <100 km. These seed particles may be in the form of polycyclic aromatic hydrocarbons (PAH) containing both carbon and hydrogen atoms C_nH_x. There could also be hollow shells of carbon atoms, such as C₆₀, called fullerenes which contain no hydrogen. The fullerenes may compose a significant fraction of the seed particles with PAHs contributing the rest. As shown by Cassini, the upper atmosphere is bombarded by magnetospheric plasma composed of protons, H₂⁺ and water group ions. The latter provide keV oxygen, hydroxyl and water ions to Titan's upper atmosphere and can become trapped within the fullerene molecules and ions. Pickup keV N₂⁺, N⁺ and CH₄⁺ can also be implanted inside of fullerenes. Attachment of oxygen ions to PAH molecules is uncertain, but following thermalization O+ can interact with abundant CH₄ contributing to the CO and CO₂ observed in Titan's atmosphere. If an exogenic keV O+ ion is implanted into the haze particles, it could become free oxygen within those aerosols that eventually fall onto Titan's surface. The process of freeing oxygen within aerosols could be driven by cosmic ray interactions with aerosols at all heights. This process could drive pre-biotic chemistry within the descending aerosols. Cosmic ray interactions with grains at the surface, including water frost depositing on grains from cryovolcanism, would further add to abundance of trapped free oxygen. Pre-biotic chemistry could arise within surface microcosms of the composite organic-ice grains, in part driven by free oxygen in the presence of organics and any heat sources, thereby raising the astrobiological potential for microscopic equivalents of Darwin's “warm ponds” on Titan.  相似文献   

有关沿岸山地俘获波的研究     

卢姁  黄伟健  张铭  何锡玉 《高原气象》2008,27(6)

在采用线性化的浅水方程组并假设地形坡度沿山脉走向不变的情况下,本文对具有底面地形坡度的沿岸山地俘获波作了研究,结果表明,当底面地形缓变时,可用摄动法得到沿岸山地俘获波的结构,此时零级近似为经典Kelvin波解,一级近似体现了Rossby变形半径内的底面地形对经典Kelvin波解的修正;直至一级近似,沿岸山地俘获波仍是非频散的。在沿岸处当底面地形坡度平缓时,沿岸山地俘获波表现为Kelvin波结构,此时扰动位势高度最大值出现在沿岸;而当底面地形坡度陡峭时,其表现为修正Kelvin波结构,此时扰动位势高度最大值偏离沿岸,在沿岸则扰动位势高度相对为低值,而在沿岸外侧则有位势高度的高值。在沿岸底面地形高度越高,地形坡度越大,扰动位势高度廓线的变化就越剧烈。  相似文献   

Mechanism of currents through the straits of the Japan Sea: Mean state and seasonal variation     

Hiroyuki Tsujino  Hideyuki Nakano  Tatsuo Motoi 《Journal of Oceanography》2008,64(1):141-161

The mechanism governing the mean state and the seasonal variation of the transports through the straits of the Japan Sea is studied using a newly presented, simple analytical model and a basin scale general circulation model (GCM). The GCM reproduces the transports through the straits of the Japan Sea realistically owing to its fine horizontal resolution of about 20 km and realistic topography. A series of experiments conducted by changing surface forcing shows that the annual mean wind-driven circulation in the North Pacific Ocean is most responsible for the formation of the mean transports. It is also found that the seasonal variation of the alongshore component of monsoonal wind stress over the North Pacific basin, especially that over the Okhotsk Sea, is responsible for the seasonal variation of the transports. The simple analytical model can explain these simulated features very well. The physical concept of this model is based on the formation of the around-island circulation through the adjustment of coastally trapped waves and Rossby waves and geostrophic control at the narrow straits. It solves the sea surface heights (SSHs) at the edge of each strait and the transport through it. The value of the line integral of the SSH along the island is determined by the baroclinic Rossby waves approaching the island from the east and the alongshore wind stress around the island. The basin scale seasonal variation of SSH along the coast induced by the variation of the alongshore monsoonal wind stress can also be incorporated into this model by giving the SSH anomaly at the northeastern point of the Soya Strait. Thus, it is suggested that both the mean state and the seasonal variation are caused mainly by wind stress forcing. Minor modification by the seasonal heat flux forcing brings the amplitude and the phase of the seasonal variation closer to the observed values.  相似文献   

磷灰石结构通道离子对晶胞参数的影响   总被引：8，自引：1，他引：8  

刘羽  胥焕岩 《矿物岩石》2001,21(1):1-4

磷灰石晶胞参数受其结构中Ca多面体，磷氧四面体及结构通道位置上的类质同角替换的影响，本文探讨了54个磷灰石样吕的晶胞参数与结构通道离子F，OH，Cl相同象替换的影响，本文讨论了54个磷灰石样品的晶胞参数与结构通道离子F，OH，Cl相对含量的关系，发现Cl和取代是影响岩浆型磷灰石晶胞参数的主要因素，每原子／晶胞的Cl使a增大0．121 1（6）nm，c减少0．0633 （3）nm，根据成分与结构的经验关系式，可以验证电子探针对F的分析结果。  相似文献   

Porewater geochemistry and solute flux from bottom sediments,Devils Lake,North Dakota   总被引：1，自引：0，他引：1  

Robert M. Lent  W. Berry Lyons 《International Journal of Salt Lake Research》1994,3(2):113-135

Sediment cores were collected for pore-water analysis from the eastern end of Devils Lake, located in northeastern North Dakota, to determine diagenetic reactions occurring in surficial bottom sediments and to evaluate the impact of these reactions on chemical concentrations in the overlying lake water. Sediment pore waters are enriched in major ions and nutrients relative to lake water. The principal sources of major ions to pore water are saline sediments located in the upper 1 m of bottom sediment. The principal source of titration alkalinity and nutrients to pore water is microbial decomposition of sedimentary organic matter by sulfate reduction. Sediment pore waters in the eastern part of Devils Lake have higher major-ion concentrations and solute-flux rates than the sediment pore waters in the central part of the lake. In contrast, sediment pore waters in the central part of Devils Lake have significantly higher nutrient concentrations and solute-flux rates. Major-ion concentrations and solute-flux rates in sediment pore water increase from west to east. These trends indicate that bottom-sediment diagenetic processes are, in part, responsible for the observed concentration gradient in the lake. The higher nutrient concentrations and the higher nutrient diffusional-flux rates in Main Bay are the result of more labile sedimentary organic matter and the occurrence of sulfate reduction. Environmentally-reactive trace-metal concentrations (Cu, Pb, Zn, and Fe) in bottom sediments decrease from west to east with distance from the surface-water sources and with increasing surface-water salinity.  相似文献   

海原断裂带断层通道波观测与破碎带宽度   总被引：5，自引：0，他引：5  

刘明军  李松林  张先康  樊计昌  宋占龙 《物探与化探》2004,28(6):549-552

断层通道波是低速断层破碎带与高速围岩之间的边界相干多重反射形成的,其振幅和频率强烈依赖于断层的几何形态和物理性质,故能用于探测断裂带的内部结构.在宁夏海原西安州附近海原断裂带上,横跨1920年海原8.6级地震地表破裂带布设2条测线,接收测线之间人工爆破激发的断层通道波.每条测线由1台3分量数字地震仪组成,靠近破裂带台间距30～40 m,远离破裂带台间距增大至230～250 m.对测线1的台站接收到的一炮垂直道地震波数据进行了0.1～4.0 Hz频段的滤波,结果表明在S波到时之后存在多组强振幅、低频率、长波链的断层通道波.由断层通道波揭示的海原断裂带在西安州附近的断裂破碎带宽度约为250 m.  相似文献   

Deep structure of the Mozumi-Sukenobu fault, central Japan, estimated from the subsurface array observation of fault zone trapped waves   总被引：1，自引：0，他引：1  

Takashi Mizuno  Kin'ya Nishigami  Hisao Ito  Yasuto Kuwahara 《Geophysical Journal International》2004,159(2):622-642

  相似文献