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71.
The Visible and Infrared Spin-Scan Radiometer(VISSR) onboard the Fengyun-2(FY-2) satellite can provide valuable thermal infrared observations to help create a precipitable water vapor(PWV) product with high spatial and temporal resolutions. The current FY-2/VISSR PWV product in operation is produced by using a traditional two-band physical split-window(PSW) method, which produces low quality results under dry atmospheric conditions. Based on the sensitivity characteristics of FY-2 F/VISSR water vapor channel and two split-window channels to atmospheric water vapor, this study developed a new, robust operational PWV retrieval algorithm for FY-2 F to improve the operational precision of the current PWV product. The algorithm uses a modified three-band PSW method, which adds a scale for the water vapor channel in the improved three-band PSW method. Integrated PWV products from the radiosonde data in 2016 are used here to validate the precision of the PWV retrieved by the modified three-band and traditional two-band PSW methods. The mean bias, root mean square error(RMSE), and correlation coefficient of the PWV retrieved by the modified three-band PSW method are 0.28 mm, 4.53 mm, and 0.969, respectively. The accuracy is much better than the PWV retrieved by the two-band method, whose mean bias, RMSE, and correlation coefficient are 12.67 mm, 29.35 mm, and 0.23. Especially, in mid-or high-latitude regions, the RMSE of the PWV is improved from 10 to 2 mm by changing the inversion in the two-band method to the modified three-band PSW method. Furthermore, the modified three-band PSW results show a better consistency with the radiosonde PWV at any zonal belt and season than the two-band PSW results. This new algorithm could significantly improve the quality of the current FY-2 F/VISSR PWV product, especially at sites where the actual PWV are lower than 15 mm. 相似文献
72.
Himawari-8是日本发射的新一代静止气象卫星,与前一代的MTSAT-2相比,在时间、空间分辨率上都有了很大提升,特别是红外通道数量从4个增至10个,为红外遥感沙尘提供了新的观测数据。本研究利用Himawari-8的红外观测数据,发展了仅用红外通道的沙尘全天候判识算法,可以实现对白天和夜间的连续监测。算法在前人基础上去除了可见光通道,同时引入更多红外通道来进行云检测和沙尘判识。由于一日之中,地表温度发生变化,因此针对白天和夜间设置了两套不同的判别阈值,来保证算法的全天适用性。最后通过两次沙尘事件对沙尘判别结果的分析和检验表明,遥感判识结果与地面气象站和PM_(10)观测较为一致,说明了只用红外通道全天候判识沙尘的可行性。 相似文献
73.
波伏棱型羟基纤蛇纹石是波伏棱型纤蛇纹石矿物的新变种,本文报导它的吸收光谱、红外光谱、穆斯堡尔谱、电子顺磁共振谱和核磁共振谱。 研究表明,吸收光谱是Fe~(3 )和Fe~(2 )的晶场跃迁以及Fe~(2 )→Fe~(3 )的荷移跃迁引起的;红外光谱是OH和Si-O的伸缩振动、OH转动以及Mg-O和Si-O的弯曲振动引起的;穆斯堡尔谱是Fe~(2 )_(八面体)、Fe~(3 )_(八面体)和Fe~(3 )_(四面体)引起的;电子顺磁共振谱是Mn~(2 )_(八面体)、Fe~(3 )_(八面体)和Fe~(3 )_(四面体)引起的;核磁共振谱是管道水,镁八面体和硅氧四面体上的OH引起的;矿物加热到825℃时,结构开始破坏并出现镁橄榄石相。 此外,本文还解释了该蛇纹石颜色的本质,阐明了上述过渡金属离子和OH在该矿物中的结构环境。 相似文献
74.
R. L. McKenzie W. A. Matthews Y. Kondo R. Zander Ph. Demoulin P. Fabian D. G. Murcray F. J. Murcray O. Lado-Bordowsky C. Camy-Peyret H. K. Roscoe J. A. Pyle R. D. McPeters 《Journal of Atmospheric Chemistry》1988,7(4):353-367
Column measurements of nitric oxide were made using several techniques during the MAP/GLOBUS campaign in France in September 1985. The data sets are nearly co-located and simultaneous, therefore allowing a valid intercomparison of the various measurement methods. The range of altitudes sampled differs from instrument to instrument. This complicates the comparison because the data sets are to some extent complementary. The NO distributions apparently vary significantly from day to day, and possibly over shorter timescales. Changes in dynamics may be responsible for these variations. The results from the instruments which measure in the infrared and the ultraviolet are self-consistent, and show good agreement with photochemical predictions. On 19 September, when the intercomparison was made, the profile measured by the in-situ chemiluminescent instrument differed significantly from the predicted profile, and the measured columns were generally higher. 相似文献
75.
红外光谱方法在找金中的应用综述 总被引:4,自引:1,他引:4
从四个方面介绍了红外光谱在金矿普查评价中的应用:石英薄片中气液包裹体与金的关系研究;石英中杂质阳离子与金的关系研究;黄铁矿与金的关系研究;金矿区氧化带和矿带共生组合矿物研究。 相似文献
76.
离子色谱—双电导法同时测定水样中多种阴离子的研究 总被引:2,自引:0,他引:2
本文在Dionex2020i离子色谱仪上,选用0.61×10~(-3)mol/L NaHCO_3-1.61×10~(-3)mol/LNa_2CO_3水溶液作淋洗液,在HPIC-AS4A阴离子分离柱上分离痕量F~-、NO_2~-、Br~-和较高浓度的Cl~-、NO_3~-、SO_4~(2-);选用2.0×10~(-3)mol/L TBAOH-6%CH_3CN水溶液作淋洗液,在MPIC-NS1分离柱上分离痕量F~-、Br~-和较高浓度的Cl~-,然后用串联双电导检测器的不同输出范围分别同时定量测定。本法特别适用于相邻两种离子浓度相差较大,前面高含量的离子对后面痕量离子测定有干扰的样品。用本文拟定的HPIC方法测定除铬后的地下水样中多种阴离子的结果与文献值吻合。 相似文献
77.
本文以红外细分波段新疆铁木尔特航带为例,依据不同地质体各自的光谱特征,运用主成分分析、多种信息复合等技术与综合分析方法,使该地段的矿化特征提取收到了良好效果。 本航带的矿化特征信息在图像处理结果中表现为黄色异常色调。它反映了当地多金属成矿带中二氧化硅含量低、全铁含量较高的岩矿矿化特征。团块状黄色异常色调表示出地表出露的铁帽、磁铁矿化和矽卡岩化的分布状况。野外验证表明,黄色调的分布地域与实地的地表矿化范围相吻合。 遥感特征信息提取的综合分析方法包括信息基本特征分析、图像处理、后验分析和机理解释等四个相互联系的步骤。研究表明,只有经过综合分析,才能揭示出特征信息的内在规律性,使特征信息具有较好的实用价值。 相似文献
78.
用红外光谱法研究海泡石的热相变 总被引:3,自引:2,他引:3
本文用红外光谱法研究沉积型海泡石粘土岩中海泡石的热稳定性和热相变现象。经实验证实:沉积型海泡石的热稳定上限为375℃,因为在375℃时海泡石的结构开始向滑石型结构变化,一直到800℃为界,呈滑石型结构,从800℃至1200℃则呈顽火辉石结构,在1200℃时还有方英石出现。 相似文献
79.
A sequential fractionation procedure employing a series of selected mild organic solvents of different polarity has been applied for the isolation of chemically different organic fractions from a brown coal humic acid. Elemental composition, molecular weight distribution, i.r. and electron spin resonance analysis were carried out on the isolated humic fractions. They were characterized by: (a) a low polydispersity, (b) a decreasing aliphatic and increasing aromatic character along the series, (c) very different molecular weight which significantly correlated with E4/E6 ratios (particle aggregation and molecular association) and free radical concentrations (chemical and biochemical activity). Significant correlations were found between physico-chemical parameters of the isolated humic fractions, i.e. Mn, Mw, E4/E6 ratios, spins/g contents and the dielectric constants of the solvents used. This suggested the efficiency of the applied procedure in isolating chemically different organic fractions from the bulk, original humic acid. 相似文献
80.
The natural thermal evolution of type III coals (Humic origin) is expressed during diagenesis by a loss of oxygen as CO2 and H2O. Other phenomena such as oxidation can cause extensive geochemical modifications and may complicate the effects of simple maturation.Humic coals from the Jurassic in southeastern Utah were studied by elemental analysis, Rock-Eval pyrolysis and infrared spectroscopy. In a van Krevelen diagram (atomic H/C vs atomic O/C), the samples fall within the envelope defined by 860 reference humic coals covering the entire range of diagenesis. Nevertheless, various criteria (geochemical, petrographic, geological and microscopic) cast doubt upon the interpretation that such a distribution of coal composition results from thermal maturation.The same criteria indicate the intervention of redox phenomena. Comparison of our results with those from artificial and natural oxidation shows that these coals were subjected to an oxidation process different from ordinary late alteration. This process was probably due to circulation of highly oxidizing saline water causing oxygen fixation and the transformation of carboxyls into carboxylate anions. The cations that were fixed are oxygenated and certainly contain calcium, but also uranium and perhaps several other cations (V, Mo, Fe...). Emphasis is placed on possible mechanisms that cause such phenomena. 相似文献