boldmath Investigation of inter-molecular hydrogen bonding in the binary mixture (acetone + water) by concentration dependent Raman study and ab initio calculations     

欧阳顺利  吴楠楠  孙成林  刘靖尧  里佐威  高淑琴 《海洋学报(英文版)》2010,29(9)

This paper reports that vibrational spectroscopic analysis on hydrogen-bonding between acetone and water comprises both experimental Raman spectra and ab initio calculations on structures of various acetone/water complexes with changing water concentrations. The optimised geometries and wavenumbers of the neat acetone molecule and its complexes are calculated by using ab initio method at the MP2 level with 6-311+G(d,p) basis set. Changes in wavenumber position and linewidth (fullwidth at half maximum) have been explained for neat as well as binary mixtures with different mole fractions of the reference system, acetone, in terms of intermolecular hydrogen bonding. The combination of experimental Raman data with ab initio calculation leads to a better knowledge of the concentration dependent changes in the spectral features in terms of hydrogen bonding.  相似文献   

Performance Enhancement of Multiuser Passive Time Reversal Communication Based on Space-Time Block Coding     

宫改云  姚文斌  潘翔  宫先仪 《中国海洋工程》2010,24(1):173-182

Reliable,with high data rate,acoustic communication in time-varying,multipath shallow water environment is a hot research topic recently.Passive time reversal communication has shown promising results in improvement of the system performance.In multiuser environment,the system performance is significantly degraded due to the interference among different users.Passive time reversal can reduce such interference by minimizing the cross-correlated version of channel impulse response among users,which can be realized by the well-separated users in depth.But this method also has its shortcomings,even with the absence of relative motion,the minimization sometimes may be impossible because of the time-varying environment.Therefore in order to avoid the limitation of minimizing the cross-correlated channel function,an approach of passive time reversal based on space-time block coding (STBC) is presented in this paper.In addition,a single channel equalizer is used as a post processing technique to reduce the residual symbol interference.Experimental results at 13 kHz with 2 kHz bandwidth demonstrate that this method has better performance to decrease bit error rate and improve signal to noise ratio,compared with passive time reversal alone or passive time reversal combined with equalization.  相似文献   

河嘉203H含硫水平气井测试工艺实践     

唐波  乔智国  陈伟  叶翠莲 《海洋地质译丛》2010,(4):103-105

河嘉203H井是川东北河坝构造嘉二高压含硫气藏部署的第一口水平井,具有埋藏深、储层压力高、腐蚀分压高、地层易漏失、水平井压井堵漏难度大的特点,通过开展工具优选、管柱结构优化设计、流程优选,并对替浆、放喷油嘴控制及压井等主要工序的施工工艺参数进行研究,形成了河坝嘉二含硫气藏水平井测试工艺技术体系,并在河嘉203H井获得成功应用。  相似文献   

卡里马塔海峡贯穿流与印尼贯穿流的相互作用     

李淑江  徐腾飞  孙俊川  杨丽娜  滕飞  王冠琳  王永刚 《海洋科学进展》2021,39(2):197-209

卡里马塔海峡贯穿流将中国南海的低盐水输运到爪哇海,与印度尼西亚贯穿流(印尼贯穿流)携带的西太平洋高盐水在印度尼西亚海(印尼海)交汇,二者通过混合、浮力强迫等过程相互作用.这改变了印度尼西亚海的水体热盐性质,影响局地海气交换和热带太平洋-印度洋之间的热盐交换.依据卡里马塔海峡、龙目海峡和望加锡海峡的实测表层海流数据,采用...  相似文献   

西藏冈底斯中段雄村铜金矿床成矿流体特征与成因探讨   总被引：20，自引：5，他引：15  

徐文艺  曲晓明  侯增谦  杨丹  杨竹森  崔艳合  陈伟十 《矿床地质》2006,25(3):243-251

雄村铜金矿是在西藏冈底斯中段新发现的一个矿床,流体包裹体组成分析揭示该矿床成矿流体为富含CO2、N2和有机气体的Na _K _Ca2 _Cl-_SO2-4_HS-_CO2-3体系,Na/K、Na/Ca和Cl-/SO2-4摩尔比值分别为1.5～7.1、0.2～2.1和1.0～29.3。氢、氧同位素分析显示,成矿流体δ18O值范围为-4.7‰～ 2.2‰,δD值范围为-104‰～-82‰,表明成矿流体以大气水为主,但岩浆流体可能也对矿床的形成起了重要作用。硫化物硫同位素组成也显示硫主要来自深源岩浆,雄村矿床高盐度流体的形成可能与岩浆流体的低压不混溶密切相关。高盐度流体是雄村贱金属元素活化、迁移的重要介质;地下水中高的有机质还原SO2是诱发贱金属沉淀成矿的重要机制。有机质还原SO2也为Au的活化、迁移提供了介质和有利的还原环境。雄村矿床的形成与岩浆流体和循环地下水共同作用有关,浅部稳定的热体制和高的有机质还原SO2机制是形成雄村矿床特殊蚀变矿化样式的重要原因。  相似文献   

Interaction of glucose and cellulose with hydrogen sulphide and polysulphides     

M.E.C. Moers  J.W. de Leeuw  H.C. Cox  P.A. Schenck 《Organic Geochemistry》1988,13(4-6)

This paper describes simulation experiments in which glucose and cellulose were reacted with polysulphide and hydrogen sulphide at ambient temperatures in an aqueous environment. Organic sulphur containing compounds were formed that yield several thiophenes upon pyrolysis/evaporation. The experiments show that interaction of carbohydrates with hydrogen sulphide or polysulphides is a possible way for carbohydrates to react in very recent sediments. From the results of this study it can be concluded that carbohydrate carbon can be preserved in sediments in a form that is resistant to microbial attack and that will have a greater potential for survival during diagenesis than the carbohydrate precursor.  相似文献   

Responses of the tropospheric ozone and odd hydrogen radicals to column ozone change     

S. C. Liu  M. Trainer 《Journal of Atmospheric Chemistry》1988,6(3):221-233

The response of tropospheric ozone to a change in solar UV penetration due to perturbation on column ozone depends critically on the tropospheric NO _x (NO+NO₂) concentration. At high NO _x or a polluted area where there is net ozone production, a decrease in column ozone will increase the solar UV penetration to the troposphere and thus increase the tropospheric ozone concentration. However, the opposite will occur, for example, at a remote oceanic area where NO _x is so low that there is net ozone destruction. This finding may have important implication on the interpretation of the long term trend of tropospheric ozone. A change in column ozone will also induce change in tropospheric OH, HO₂, and H₂O₂ concentrations which are major oxidants in the troposphere. Thus, the oxidation capacity and, in turn, the abundances of many reduced gases will be perturbed. Our model calculations show that the change in OH, HO₂, and H₂O₂ concentrations are essentially independent of the NO _x concentration.  相似文献   

华北板块北缘中段含铁变质岩系的时代和构造环境初探   总被引：15，自引：1，他引：15  

徐备  陈斌 《地质论评》1994,40(4):307-311

内蒙北部苏尼特右旗以北二道井、哈拉干和红格尔地区的含铁变质岩系中变质基性火山岩Ｓｍ－Ｎｄ全岩等时线年龄为１５１１±７６Ｍａ，这表明该岩系属中元古代而不是以往推测的早古生代，等时线的εＮｄ（ｔ）值为＋６．３±１．７，属亏损型地幔源区岩相学分析表明它形成于规模不大，具中等水深和较弱水动力条件的较封闭海域。据上述特征推测，华北板块北缘中曾存在中元古代初动型火山陆缘。  相似文献   

电气石和水之间的氢同位素分馏   总被引：1，自引：0，他引：1  

钱雅倩  郭吉保 《地球学报》1994,15(Z1):189-196

作者对电气-水体系氢同位素平衡分馏和动力学分馏和动力学分馏开展了实验研究，丰富了羟基矿物氢同位素分馏资料。本文对该研究的实验技术、分析方法作了介绍，并对实验结果进行讨论与国外已有的该方面的资料作了对比。在800-650℃时电气石和水之间氢同位素平衡分馏系数与温度间线性关系为103lna电气石-水=-28.24（106/T2）+2.60；交换速率常数与温度间关系为lnk2=-0.19-6.70（103/T）  相似文献   

大　陆　岩　石　圈　研　究     

何国琦  韩宝福 《地学前缘》1995,2(2):187-194

大陆岩石圈和大洋岩石圈有着深刻的差别，运用板块构造理论和模式研究大陆岩石圈会遇到许多特殊的问题。本文从陆缘演化和多个板块构造旋回叠加两方面做了初步探讨，提出岩浆型被动陆缘是独立的一类古陆缘；在辨认后续板块构造旋回叠加中，新构造成分和格局的确定有重要意义。本文还讨论了汲取大陆地质研究经验，在新的学科水平上重新解释传统大地构造学中一些有用概念的意义。  相似文献