GC—MSD定测土壤中有机磷有机氯农药的残留     

刘金巍  孟志鑫  刘庆学  刘敬上 《河北地质》2008,(2):27-30

研究了土壤中有机磷有机氯农药残留的GC—MSD—SIM测定方法。通过乙腈超声提取,佛罗里硅土净化或直接GC—MSD—SIM方法测定有机氯和有机磷农药残留;采用有机质谱离子选择模式采集数据,简化了样品处理流程。实验数据表明该方法灵敏、快速、准确,方法的精密度为2．7～9．4％,检出限为0．005-0．007μg／g,适用于土壤中的有机磷有机氯农药残留的测定。  相似文献   

用气象站地温资料计算多年平均土壤热流的初步结果   总被引：11，自引：3，他引：8  

董文杰  汤懋苍 《高原气象》1992,11(2):115-125

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西安南郊丰水年秋季土壤水分研究   总被引：4，自引：0，他引：4  

李艳花  赵景波 《中国沙漠》2006,26(1):113-116

 通过对西安南郊丰水年秋季土壤含水量的测定，研究了地下0~6 m之间土壤含水量的变化与土壤干层的恢复问题。研究结果表明，丰水年西安南郊人工林下2~3 m的土壤含水量在20％左右，远远高于正常年份的土壤含水量，而且大于表层和深层的土壤含水量。分析得出，土壤干层发育较弱的地区在降水丰富的年份可以得到一定程度的恢复；西安地区基本适合进行人工造林；通过人工措施，增强降水入渗和土壤含水量，对树木成活和长期的生长应当具有明显的作用。  相似文献   

土壤颜色——一个可靠的气候变化代用指标   总被引：3，自引：0，他引：3  

陈一萌  陈兴盛  宫辉力  魏明建  李小娟 《干旱区地理》2006,29(3):309-313

将研究剖面自上而下以2cm间隔采取的样品,烘干并研磨至小于45μm,此时,土壤的颜色将不再发生变化。将处理好的样品分别测土壤颜色指标亮度、红度和黄度,将测得的亮度、红度和黄度指标分MIS4、MIS3、MIS2和MIS14个阶段,通过与研究剖面的气候指标磁化率、粒度和CaCO_3在百年尺度、千年尺度上的对比分析,以及在万年尺度上与高纬格陵兰GRIP冰芯记录和反映全球冰量变化的SPECMAP曲线进行对比分析表明：土壤颜色指标作为气候变化的代用指标无论在百年尺度、千年尺度还是在万年尺度上均是可靠的,这种可靠性在末次冰期阶段表现得更为显著,这一结论是否适用于整个第四纪冰期间冰期旋回,尚需更多黄土剖面的研究事实来加以证明。  相似文献   

Spatial analysis of elements in soils from Chengdu City     

Shuyun XIE Zhengyu BAO Bing LI 《中国地球化学学报》2006,25(B08):7-8

Three kinds of spatial analysis methods （geostatistics, concentration-area fractal model and the multifractal analysis called the moment method） were used for almost 50 elements, including heavy metals, disperse elements, rare elements and even others, in 6586 top soil （0-20 cm） samples and 1833 deep soil （150-200 cm） samples from Chengdu metropolitan area of 12400 km^2, southwestern China. The ranges of spatial correlation revealed by variograms are quite different for different kinds of elements in the top and deep soils. The most interest is the fact that the multifractal spectra of environmentally important elements such as Pb, Cr, Cd and Ni in top soils in the metropolitan area show systematic change from those in the deep soils, revealing a strong anthropogenic addition, while Hg, Zn, As, Cu and all common elements show no such kind of addition. In terms of multifractal properties based on the multifractal spectrum curves, those disperse and rare elements show great deviation from other major and trace elements, which is also of great interest.  相似文献   

Analysis on the sources of mercury in soils in the Chengdu Basin, China     

Limin REN Bing QIN Wenchun TANG Zhendong MA Yikeng HU 《中国地球化学学报》2006,25(B08):10-10

Mercury is a pollutant of concern due to its toxic and bioaccumulative properties. Studies on the distribution and hazard of mercury in the environment are mainly focused on its forms, toxicity and the environment standard, and progresses and results have been achieved. But these studies in the past were concentrated on the scales of laboratory or smaller districts merely, such as a small unit of mineral area, vegetable base, paddy field, lake, etc. Multi-target regional geochemical survey carried out by China Geological Survey from the 1990s to now is a fundamental and commonweal geological survey, large-scale and systematical inquisition and research were conducted in 19 provinces （or municipalities directly under the Central Government） in the eastern overlay region of China, and the purpose is to provide the basic geochemical data for national economic construction, adjustment of industrial and agricultural structures and sustainable social development. Geochemical studies aim at investigating soils in these regions and 52 elements have been tested, producing a great amount of data at the same time. Methods： based on the data from 3061 samples of surface soil and 832 samples of deep soil from the project of multi-purpose geochemical survey in the Chengdu Basin, Sichuan, China, this paper describes the correlation relationship between Hg and other 48 elements and their spatial distribution in surface and deep soils of these areas by applying the method of linear regression and factor analysis.  相似文献   

Measurement of the total nitrogen in lake sediments： Comparison and its environmental significance     

Wei JIANG Xinqing LEE 《中国地球化学学报》2006,25(B08):12-12

Nitrogen cycle is an important bio-geochemical process in the environment. Measurement of the total nitrogen （TN） is a routine experiment in agriculture, biology and environmental sciences. The Kjeldahl method （KM） and elemental analyzer method （EA） are both commonly used to determine TN. Total nitrogen by EA is the sum of nitrate （NO3）, nitrite （NO2）, organic nitrogen and ammonia. Total nitrogen by KM （TKN） is made up of both organic nitrogen and ammonia. A comparative study focused on the two methods is conducted by analysis of TN in 97 samples from the sediment sequence of Gouchi, a salt lake in North China. KM presents a higher degree of accuracy than EA with a standard deviation of 0.007 vs. 0.024. With the presence of nitrate and/or nitrite nitrogen, however, measurement by KM is considerably lower than that by EA. Therefore, for samples from lake sediment sequences or soils in North China, KM is inapplicable to determining TN because of usually high contents of nitrous salt. Despite the inconsistency, use of both methods to the same samples makes sense in reconstructions of climatic and environmental changes from lake sediments. In Lake Gouchi, the contents of nitrate and nitrite nitrogen vary from 1.40% in the lower part of the sequence to 14.77% in the uppermost part, suggesting a gradual evolution process from a fresh water lake to the present-day salt lake.  相似文献   

Environmental impacts from mining at Taojiang Mn ore deposit, central Hunan, China     

Bo PENG Shurong XIE Meilian XIAO Fucheng WU Zhi SONG 《中国地球化学学报》2006,25(B08):23-24

The Taojiang Mn ore deposit was exploited in the early 1960s, and waste rocks were developed since then. Because the Mn ores were hosted within the metal-enriched black shales （Peng et al., 2004）, the continuous mining has led to the exposure of an immense quality of black shales, which might cause serious impacts on environments. The present study deals with this environmental issue with samples from the waste rocks, and from the surrounding soils and surface water. The mineralogy of the waste rock was studied using EMPA, then a large number of elements in all waste rock, soil, and water samples were analyzed at a wide range of concentrations with high accuracy using an Elan6000 ICP-MS machine at Guangzhou Institute of Geochemistry, Chinese Academy of Sciences. The waste rock is composed mostly of black shales, with minor Mn carbonates. Both black shales and Mn carbonates of the waste rock contain many sulfide minerals, mainly pyrite, with minor galena, sphalerite, chalcopyrite, and others. The waste rocks are enriched in many metals including Sc, V, Cr, Co, Ni, Fe, Mn, Cu, Zn, Pb, Th, U, Mo, Sb, Sn, Tl, and others, and the metals are mostly hosted within the sulfides. Weathering of waste rocks might cause emission of the following metals： V, Cd, Ni, Th, U, Mo, Sb, Tl, Sc, Cr, Cu, Zn, Sn, and minor Co, and Pb. The surrounding soils are highly enriched in Cr, Co, Cu, Zn, Mn, Mo, Cd, Tl, and Pb, with the enrichment factors of 2.67.3.8, 7.26, 7.27, 8.2, 5.7, 13, and 5.4, respectively. The element ratios （Rb/Cs, Fe/Mn, Nb/Zr, Hf/Zr, and Ba/Sr） and REE distribution patterns of the soils are similar to those of the waste rocks and bedrocks.  相似文献   

Environmental aspects of selected trace metals in soils and waters surrounding Singaran Nala, Raniganj Coalfield     

Supriyo Das 《中国地球化学学报》2006,25(B08):24-25

The Raniganj Coalfield is the oldest coalfield in India that has been continuously and extensively mined since the late eighteenth century. The present study reports a geochemical investigation and environmental quality assessment using soil and water in the area surrounding a stream, locally known as Singaran Nala （Nala means storm water drains in Bengali）, in the Raniganj Coalfield. Soil （top soil, mud, silty clay and laterite） and rock samples （sandstone and shale） were collected from the study area and were analyzed for trace metals （Cr, Cu, Fe, Mn, Ni and Zn）. Surface waters from the stream and the Damodar River as well as ground waters from hand pumps and underground mine pits were collected. Water samples were analyzed for major ions （Na^＋, Ca^2＋, Mg^2＋, Cl^-, HNO3^- and SO4^2-） and trace metals （Cu, Fe, Mn, Ni, and Zn）. Trace metal concentrations in soil samples are found higher than the average world soil composition. Nevertheless, trace metal （Cr, Cu, Ni and Zn） concentrations in soils exceed or reach the maximum allowable concentrations （MAC） proposed by the European Commission for agricultural soils. In particular, Ni concentrations exceed the typical value for cultivated soils. Chromium, Cu and Ni concentrations in laterite and Cr concentration in topsoil exceed the ecotoxicological limit.  相似文献   

Heavy metal contents in soil of major towns in the east coast of Peninsular Malaysia     

Seng Chee Poh Norhaxati Mohd Tahir Hafiza Mohamed Zuki Mohd Izwadi Musa Khai Hock Ng Noor Azhar Mohamed Shazili 《中国地球化学学报》2006,25(B08):56-56

A total of 63 soil samples from 3 different soil profiles （urban, suburban and industrial areas） in major towns in the east coast of Peninsular Malaysia were analyzed for the total concentrations of Cu, Zn, Pb, Ni and Cr. The soil samples were subjected to acid digestion and the concentrations of total metals extracted were measured or flame atomic absorption spectrometry and inductively coupled plasma - atomic emission spectrometry. According to the result of this study, Pb and Zn concentrations in urban soils are much higher than those of industrial and suburban soils. Total concentrations of Cu and Cr in industrial soil samples are high compared to other two soil profiles and Ni concentrations in the suburban area are slightly higher those of urban and industrial soils. Since Malaysia has not yet to come up with her own soil maximum allowable limit, the heavy metal concentrations were compared with the Dutch maximum allowable limit. The results indicated that the median of heavy metals values in the three different soil profiles is still below the Dutch system limit. From the maximum allowable value obtained from the Dutch system, a contamination/pollution （C/p） index for each site was calculated for the set of these five heavy metals. An advantage of using this method is to make a differentiation between pollution （C/p〉1） and contamination （C/p〈1） status in soils as well as being able to characterize each status into 5 different categories （slight, moderate, severe, very severe and excessive）.  相似文献