Mathematical model for hydraulically aided electrokinetic remediation of aquifer and removal of nonanionic copper     

Sadataka Shiba  Yushi Hirata  Tadachika Seno   《Engineering Geology》2005,77(3-4):305-315

One of the most cost-effective in situ technologies for soil and groundwater (i.e., aquifer) remediation is electrokinetic remediation. In electrokinetic remediation, electromigration due to electric field is combined with hydromigration due to hydraulic flow by purge water to remove pollutants from aquifers through the pore water. This study aims at investigating theoretically the role of electromigration (as active movement) of pollutants and the role of hydromigration (as passive movement) of pollutants in electrokinetic remediation, and making it clear that the control variables for electrokinetic remediation are the applied voltage and the hydraulic flow rate. These aims are pursued by construction of a mathematical model based on physico-chemical considerations and by model simulations of the electrokinetic remediation applied to the virtual aquifer polluted by heavy metals of copper sulfate. According to numerical simulations with the model: (1) heavy metal (nonanionic copper) is removed from the upstream anode region and accumulated in the downstream cathode region; (2) to carry away the heavy metal outside the aquifer (global removal), hydromigration by purge water flow is essential; and (3) electromigration contributes mainly to the redistribution of heavy metals within the aquifer (local removal and local accumulation).  相似文献   

Correlation between magnetic susceptibility and heavy metals in urban topsoil: a case study from the city of Xuzhou, China   总被引：7，自引：0，他引：7  

Xue Song WANG  Yong QIN 《Environmental Geology》2005,49(1):10-18

Anthropogenic influence, mainly due to urban and industrial activities and traffic exhaust, may affect urban topsoil via atmospheric contamination and solid waste. Magnetic susceptibility measurements were conducted on 21 urban topsoil samples from the city of Xuzhou, China. High intensities of magnetic susceptibility were detected in the majority of the samples. SEM analysis shows that magnetic minerals are in the form of spherules and mainly due to anthropogenic inputs. The heavy metals Pb, Cu, Zn, Se, Sc, Mo, Fe, and Bi show strong correlations with magnetic susceptibility, and Ag, Ba, Cd, Ni, Cr, Sb, and Sn, on the other hand, show a weak correlation with magnetic susceptibility. Whereas, of these metals studied, only Hg has no significant correlation with the susceptibility. The Tomlinson pollution load index (PLI) also shows significant correlation with the susceptibility (χ). The present study shows that magnetic susceptibility is a fast, inexpensive, and non-destructive method for the detection and mapping of contaminated soils.  相似文献   

Environmental pollution impact on water and sediments of Kumaun lakes, Lesser Himalaya, India: a comparative study     

Brijraj K. Das 《Environmental Geology》2005,49(2):230-239

A study of the water and sediment chemistry of the Nainital, Bhimtal, Naukuchiyatal and Sattal Lakes of Kumaun, has shown that the water of these lakes are alkaline and that electrical conductivity, total dissolved solid and bicarbonate HCO ₃ ⁻ are much higher in Nainital than in the other three lakes. The weathering of limestone lithology and anthropogenic pollution, the latter due to the very high density of population in the Nainital valley, are the primary sources of enhanced parameters. The low pH of Nainital Lake water is due to low photosynthesis and enhanced respiration, increasing CO₂ in the water and the consequent enhancement of Ca²⁺ and HCO ₃ ⁻ . The dissolved oxygen in Nainital Lake is less compared to other lakes, indicating anoxic conditions developing at the mud–water interface at depth. The PO ₄ ³⁻ content in Nainital is higher (124 μg/l), showing an increasing trend over time leading to eutrophic conditions. The trace metals (Cu, Co, Zn, Ni, Mn, and Sr) are present in greater amounts in the water of Nainital Lake than in the other three lakes, though Fe and Cr are high in Bhimtal and Fe in Naukuchiyatal. The higher abundance is derived from the leaching of Fe–Mg from metavolcanic and metabasic rocks. Most of the heavy metals (Cr, Ni, Cu, Mn, Fe, Sr, and Zn) significantly enrich the suspended sediments of the lakes compared to the bed sediments which due to their adsorption on finer particles and owing to multiple hydroxide coating and organic content, except for Fe, which is enriched in the bed sediments. The high rate of sedimentation, 11.5 mm/year in Nainital, compared to Bhimtal with 4.70 mm/year, Naukuchiyatal with 3.72 mm/year, and Sattal with 2.99 mm/year, has resulted in shorter residence time, poor sorting of grains, and lesser adsorption of heavy metals, leading consequently, their depletion in the bed sediments of Nainital Lake.  相似文献   

Water pollution in gold mining industry: a case study in Roşia Montană district, Romania     

R. M. Florea  A. I. Stoica  G. E. Baiulescu  P. Capotă 《Environmental Geology》2005,48(8):1132-1136

The preliminary study of streams and rivers from the Roşia Montană area revealed that the concntration of heavy metals— Cd, Mn, Cu, Pb, and Zn—are above accepted limits. The gold extraction method is based on flotation. The most important pollution sources are mine tailings. The determinations were performed for samples collected in: April 2004, July 2004, September 2004, November 2004, February 2005 and May 2005. The highest concentrations were found for cadmium in September 2004: 0.17 mg/L; for copper in September 2004: 1.38 mg/L; for manganese in July 2004: 239.4 mg/L; for lead in May 2005: 0.54 mg/L; and for zinc in September 2004: 35.37 mg/L;. This study involved three small rivers (streams) that flow into the Mureş River and finally into the Danube River, having a great impact on human health and environmental stability in the area. In May 2005, a sample of drinking water from the mining district was also collected.  相似文献   

Quantitative assessment on the influence of heavy rainfall on the crystalline schist landslide by monitoring system -case study on Zentoku landslide, Japan   总被引：2，自引：1，他引：2  

Yong Hong  Hiromasa Hiura  Kazuo Shino  Kyoji Sassa  Hiroshi Fukuoka 《Landslides》2005,2(1):31-41

On Shikoku Island, which is one of the four main islands of Japan, a large number of large-scale crystalline schist landslides have been revealed and are being monitored by an observation system. Seasonal heavy rainfall is the most active meteorological factor that can threaten the stability of this kind of site-specific landslide. In this paper, on the basis of the study of the rainfall-related behavior of a typical crystalline schist landslide, the Zentoku landslide, by analyzing the precisely and continuously observed piezometric and movement data, a method was developed to quantitatively assess the effect of heavy rainfall on a large-scale landslide. The results indicated that heavy rainfall-induced landslide displacement shows good correlation with the variation of groundwater levels. Variations of groundwater level have been simulated with the use of a tank model. The simulation using this model permits the change in water levels for future rainfall events to be predicted. By combining the predicted results with the empirical relation between displacements and water levels, rainfall-induced landslide movement during extreme rainfall events can be estimated in advance. The effect of heavy rainfall on sliding behavior can be quantified in terms of the change in displacement. Thus warning information or advisories for the local residents can be provided.  相似文献   

江苏暴雨概率预报及其业务应用   总被引：1，自引：0，他引：1  

陈圣劼  孙燕  刘安宁  罗兵 《气象科学》2016,36(2):269-274

以未来12~36 h、36~60 h和60~84 h的暴雨预报为目标,利用2011年—2013年夏季6—8月欧洲细网格数值模式预报产品分析了江苏夏季暴雨的可能预报因子。通过对各因子进行相关性、敏感性和代表性分析后,优选了22个对不同强度降水具有较好区分能力的暴雨预报因子。以这些因子为基础建立了一种简单的江苏省暴雨概率预报方法。其预报产品已在江苏省气象业务一体化平台上投入业务使用。该方法在2011—2013年7月,针对提前12 h预报的历史回报试验中,TS技巧评分平均为13.6,明显高于EC细网格24 h降水预报产品(平均TS评分仅为4.5)。在2014年梅汛期的6月25—26日、7月1—2日和7月4—5日三次区域性暴雨个例的预报试验中,提前60、36、12 h的预报效果均较好,其平均TS评分(44.6)也明显高于欧洲细网格数值模式的降水预报(20.4)。  相似文献   

黄土高原一次超级单体短时强降水中尺度分析   总被引：2，自引：2，他引：0  

王楠  李萍云  井宇  赵强 《气象科学》2016,36(6):742-751

2012年盛夏陕西绥德县出现短时强降水,4 h雨量超过100 mm。利用NCEP 1°×1°再分析资料进行诊断分析发现,在陕北东北部对流层中下层有一中α尺度气旋存在,且随高度向东北倾斜,垂直方向上形成次级环流,使强降水区的上升运动加剧。分析地面观测、卫星资料发现,西路冷空气引导干侵入加强层结不稳定性,东路冷空气楔形抬升作用,使得不稳定能量释放;同时,在东西两路干冷空气的夹击作用下,绥德县内形成中气旋,暖湿空气在当地得以聚集上升;2个中β尺度对流云团在东西路风场作用下合并后迅速增强。多普勒雷达资料显示,2个中γ尺度的超级单体回波在绥德先后发展形成列车效应;2个超级单体中的中气旋特征各有不同,是回波结构演变的主要原因。  相似文献   

Geochemical fractionation of Ni,Cu and Pb in the deep sea sediments from the Central Indian Ocean Basin: An insight into the mechanism of metal enrichment in sediment     

《Chemie der Erde / Geochemistry》2016,76(1):39-48

Metal speciation study in combination with major element chemistry of deep sea sediments provided possible metal enrichment pathways in sediments collected from environmentally different locations of Central Indian Ocean Basin (CIB). Metal speciation study suggests that Fe–Mn oxyhydroxide phase was the major binding phase for Ni, Cu and Pb in the sediments. The second highest concentrations of all these metals were present within the structure of the sediments. Easily reducible oxide phase (within the Fe–Mn oxyhydroxide binding phases) was the major host for all the three metals in the studied sediments. Major element chemistry of these sediments revealed that there was an increased tendency of Cu and Ni to get incorporated into the deep sea sediment via the non-terrigenous Mn-oxyhydroxide fraction, whereas, Pb gets incorporated mostly via amorphous Fe-hydroxides into the sediment from the CIB. This is the first attempt to provide an insight into the mechanism of metal enrichment in sediment that host vast manganese nodule.  相似文献   

Contamination,bioaccessibility and human health risk of heavy metals in exposed-lawn soils from 28 urban parks in southern China's largest city,Guangzhou     

《Applied Geochemistry》2016

The total concentrations and oral bioaccessibility of heavy metals in surface-exposed lawn soils from 28 urban parks in Guangzhou were investigated, and the health risks posed to humans were evaluated. The descending order of total heavy metal concentrations was Fe > Mn > Pb > Zn > Cu > Cr > Ni > Cd, but Cd showed the highest percentage bioaccessibility (75.96%). Principal component analysis showed that Grouped Cd, Pb, Cr, Ni, Cu and Zn, and grouped Cr and Mn could be controlled two different types of human sources. Whereas, Ni and Fe were controlled by both anthropogenic and natural sources. The carcinogenic risk probabilities for Pb and Cr to children and adults were under the acceptable level (<1 × 10⁻⁴). Hazard Quotient value for each metal and Hazard Index values for all metals studied indicated no significant risk of non-carcinogenic effects to children and adults in Guangzhou urban park soils.  相似文献   

青藏高原东部暴雨的中尺度有效位能收支分析          下载免费PDF全文

Kuo Zhou  Lingkun Ran  Yi Liu  Xiuxia Tian 《大气和海洋科学快报》2021,14(2):53-59

针对2018年7月10-11日青藏高原东部一次暴雨过程,利用模式模拟资料分析了有效位能分布特征,成因及其对降水发展演变的影响.结果表明,有效位能主要分布在对流层低层4km以下和高层8-14km,高层有效位能和降水有更好的对应性西北冷平流和降水粒子下落的蒸发作用是低层有效位能高值中心的主要成因,而降水过程释放潜热带来的热力扰动叠加高原大地形造成的位温扰动是导致高层有效位能高值的主要原因.有效位能收支分析表明,有效位能的通量输送项以及与动能间的转换项是主要源汇项.低层有效位能的经向通量输送和动能向有效位能的转化补给了有效位能的耗散;高层有效位能向垂直动能转化增强垂直运动是促进降水发展演变的主要因素.高层有效位能与垂直运动之间的正反馈过程使得两者相关性较强;低层较长时间内均存在垂直动能向有效位能的转化,削弱了垂直运动,而西北冷平流使得低层有效位能有增强的趋势,因此二者相关性较弱.  相似文献