太白县大河滩铜-金-多金属矿点成矿条件及找矿前景分析   总被引：1，自引：0，他引：1  

李永勤  陈二虎  黄长青 《矿产与地质》2004,18(6):541-544

大河滩铜-金-多金属矿点处于两大板块碰撞对接带，其间有庞家河一马鞍桥近EW向铁-金矿带和斜峪关一二郎坝NE向铁-贵金属矿带通过，具有多次成矿作用叠加的特点，可与江西“银山式”大型铜-金多金属矿床的成矿条件、赋矿特征、成矿时代和矿化类型类比，具备形成大型矿床的成矿地质条件，找矿前景较大。  相似文献   

Improved Platinum-Group Element Extraction by NiS Fire Assay from Chromitite Ore Samples Using a Flux Containing Sodium Metaphosphate   总被引：1，自引：0，他引：1  

L. Paul Bédard  Sarah-Jane Barnes 《Geostandards and Geoanalytical Research》2004,28(2):311-316

Many chromite-rich rocks contain relatively high concentrations of the platinum-group elements (PGE). In many cases, the phases carrying PGE occur as either platinum-group minerals (PGM) or as base metal sulfides in solid solution in sulfides. In some cases, such as the UG-2 unit of the Bushveld Complex, the PGM are occluded inside chromite grains. Chromites are notably difficult to dissolve in most fluxes and if the chromite contains some PGM the possibility exists that not all the PGE will be recovered during fusion. In this work, shortcomings in published methods of analysis based on the nickel sulfide fire assay procedure were investigated and a new procedure developed based on the addition of sodium metaphosphate to the fusion mixture. Optimum composition of the fusion mixture was found to be 10 g sodium metaphosphate and 9 g silica to 10 g sample, 15 g sodium carbonate, 30 g lithium tetraborate, 7.5 g nickel and 4.5 g sulfur to achieve complete dissolution of chromite grains. The new flux mixture was evaluated by the analysis of reference material CHR-Pt+ (which is known to contain PGM inside chromite grains) and no undissolved chromite grains were found in the glassy slag. Analysis of the nickel sulfide beads from this fire assay using neutron activation analysis showed similar results for Rh and Ru when compared with published conventional true (or accepted) values, while Au, Ir, Os, Pd and Pt values determined here were 10 to 30% higher than the corresponding published conventional true values. It was concluded that the addition of sodium metaphosphate improved chromite dissolution in the flux and appears to improve PGE recovery.  相似文献   

Chemical Composition of Ores from the Takara Volcanogenic Massive Sulfide Deposit, Central Japan     

Daigoro Yakushi  Mamoru Enjoji 《Resource Geology》2004,54(4):437-446

Abstract. The Takara volcanogenic massive sulfide (VMS) deposit occurs in Miocene formation of the Misaka Mountain, the South Fossa Magna region, central Japan. The tectonic setting of the Misaka Mountain is reconstructed to be a part of the paleo Izu-Ogasawara arc which collided with the Honshu arc and to form accreted body in the present position. The Takara deposit, therefore, is considered to have formed in the paleo Izu-Ogasawara arc.
The ores from the Takara deposit are classified into pyrite-type ore, chalcopyrite-type ore, and sphalerite-type ore on the basis of chemical composition and their mineral assemblages. Some pyrite-type ores are characterized by their high Au content. The Au content is hardly recognized in the chalcopyrite-type and sphalerite-type ores.
The ores from the Takara deposit have intermediate bulk chemical composition between those from the Besshi-type deposits and the Kuroko-type deposits that are two representative VMS deposits. However, the bulk chemical composition is closer to that from the Kuroko-type deposits. And moreover, chemical composition of tetrahedrite-tennantite series minerals (tetrahedrite) is similar to that from the Kuroko-type deposits. The bulk chemical composition (Cu, Zn, Co, Pb, and As contents) of ores is affected by the chemical composition of volcanic rocks associated with VMS deposits.  相似文献   

Polymetallic Mineralization at the Suttsu Vein-type Deposit, Southwestern Hokkaido, Japan   总被引：1，自引：0，他引：1  

Shuji Ono  Koji Hirai    Hiroharu Matsueda  Taro Kabashima 《Resource Geology》2004,54(4):453-464

Abstract. The Suttsu polymetallic vein-type deposit, hosted by tuff, tuff breccia and shale of the Miocene Kunnui Formation and propylitized hornblende-augite andesite, is located in southwestern Hokkaido, Japan. It has been exploited and explored for Cu, Pb, Zn and Ag until 1962.
In this study, we examined K-Ar ages, ore mineralogical characteristics and fluid inclusions to obtain new data for the deposit.
The K-Ar ages on sericite indicate that the polymetallic mineralization occurred in Late Miocene (8.1–5.7 Ma). The polymetallic banded ore from the Ohkubo vein is characterized by an abundance of Au, Ag, Sn, Bi, in, Se and Te. These metals are mainly ascribed to electrum (30.3–37.8 atom% Ag), Se-bearing pavonite (8.5–9.5 wt% Se), gustavite-lillianite solid solution, Se-bearing bismuthinite (5.0–5.3 wt% Se), kawazulite, cassiterite, Sn-bearing chalcopyrite (3.3–4.2 wt% Sn), In-bearing stannite, stannite-chalcopyrite solid solution, and In- and Sn-bearing sphalerite (2.6–8.4 wt% In and 1.8–4.3 wt% Sn), occurring in narrow bands of the ore. The In- and Sn-bearing sphalerite likely forms a sphalerite-roquesite-stannite solid solution with the contents of roquesite and stannite being about 2–9 and 2-A mole%, respectively. Temperatures and salinities (in wt% NaCl equiv.) of the ore fluids are estimated to be 180-250C and 3–4 wt%, respectively. The Sn-bearing chalcopyrite therefore probably precipitated metastably. The geologic and mineralogical features suggest that pre-Tertiary basement rocks rich in organic material underlie the Miocene Kunnui Formation nearby the deposit and that they contributed to local and temporary reduction of magnetite-series magmas favorable for the early stage tin-polymetallic mineralization.  相似文献   

GEOCHEMICAL CHARACTERISTICS OF PLATINUM GROUP ELEMENTS IN JINCHUAN SUPER-LARGE SULFIDE COPPER-NICKEL DEPOSIT, JINCHANG CITY, GANSU PROVINCE, CHINA     

WANG Ruiting MAO Jingwen HE Ying WANG Dongsheng TANG Zhongli 《大地构造与成矿学(英文版)》2005,29(2):152-163

The platinum-group element geochemistry of rocks and ores from Jinchuan super-large copper-nickel sulfide deposit is systemically studied in this paper. The Cu/Pd mean ratio of Jinchuan intrusion is lower than that of original mantle magma, which indicates that these ultrabasic rocks were crystallized from magma that lost Pd in the form of melting segregation of sulfides. The PGE of the rocks show trend of partial melting, similar to that of mantle peridotite, which shows that magma formation occurs during rock-forming and ore-forming processes. The chondrite normalized PGE patterns of the rocks and ores are well related to each other, which signifies the signatures of multi-episode magmatic intrusion, melting and differentiation in the formation processes of rocks and ores. In addition, analyses about the relation between PGE and S, and study on Re-Os isotopes indicate that few contamination of the crustal substances occurred during the magmatic intrusion and the formation of deposit. However, contamination by crustal substances helps to supply part of the S for the enrichment of PGE. Meanwhile, the hydrothermal process is also advantageous for the enrichment of PGE, especially lbr Pt and Pd, due to deep melting segregation. The characteristic parameters （such as Pt/（Pt＋Pd）, （Pt＋Pd）/（Ru＋Ir＋Os）, Pd/Ir, Cu/（Ni＋Cu）, and so on.） for platinum-group elements for Jinchuan sulfide copper-nickel deposit show the same features as those for sulfide copper-nickel deposit related to basic magma, which also illustrates its original magma property representative of Mg-high tholeiite. Therefore, it is the marie （not ultramafic） magma that resulted in the formation of the superlarge sulfide copper-nickel deposit enriched in Cu and PGE. To sum up, the geochemical characteristics of platinum-group elements in rocks and ores from Jinchuan copper-nickel sulfide deposit are constrained by the continental rift tectonic environment, the parent magma features, the enriched mantel magma source, the complex metallogenesis and PGE geochemical signatures, and this would be rather significant for the study about the genetic mechanism of copper-nickel sulfide deposits.  相似文献   

Kübler Index and K-Ar Ages of Illite in the Yinshan Polymetallic Deposit, Jiangxi Province, South China: Analyses and Implications     

Xiaofeng Li    Chunzeng Wang  Jingwen Mao    Renmin Hua    Yarning Liu  Qinghong Xu 《Resource Geology》2005,55(4):397-404

Abstract. The Yinshan polymetallic deposit is a hydrothermal vein-type deposit closely related to Late Jurassic felsic-inter-mediate volcanic-subvolcanic activity in Jiangxi Province, South China. Illite is a major alteration mineral observed in the deposit. Our study shows that the Kübler index of the illite has a close relation to ore-forming fluids of different stages of hydrothermal alteration and mineralization. The early Pb-Zn-Ag mineralization dated at 130–136 Ma is characterized by relatively low water/rock ratios and diffusive fluid movement within phyllite, whereas the later Cu-Au-S mineralization at 122 -125 Ma was accompanied by higher water/rock ratios and localized fluid flow through fractures and channels. Illite formed in the early Pb-Zn-Ag mineralization stage contains swelling layers while the illite formed in the later Cu-Au-S mineralization stage has no swelling layers but was associated with intensive chloritization. The last stage of mineralization (at 104 Ma) was minor and did not produce significant amounts of illite.  相似文献   

Lead-arsenic soil geochemical study as an exploration guide over the Killik volcanogenic massive sulfide deposit, Northeastern Turkey   总被引：3，自引：0，他引：3  

E. ifti  H. Kolayli  S.Tokel 《Journal of Geochemical Exploration》2005,86(1):49-59

A mountainous terrain, the eastern Pontide tectonic belt, located in northeastern Turkey, contains more than 60 known volcanogenic massive sulfide (VMS) deposits that differ in reserves (0.1–30 million tonnes) and grades. Soil geochemistry is conventionally used in exploration programs to discover concealed VMS deposits in the region. In the present study, Pb and As element pair were used as pathfinder elements to investigate the relationship of their anomalies to a completely delineated ore deposit (Killik VMS deposit) in an orientation survey that served as a natural physical model. Two hundred forty soil samples were analyzed in the present study. The two elements, which represent the opposite ends of the mobility range, revealed high contrast and overlapped each other at the location of the ore deposit due to enhancement of the anomalies by hydromorphic dispersion, which is an indication that soil samples would produce reliable results. The successful delineation of the deposit is remarkable considering the rough topography and the climatic limitations. Previously the extremely moist and temperate climate was thought to cause excessive leaching of the trace element pathfinders from the ore deposits to produce extensive anomalies usually extending away from the mineralization thus, leading to erroneous results and/or extensive anomalous areas. But the present research has shown that the method can be used effectively if the sampling and data evaluation is carefully conducted.  相似文献   

胡安·德富卡洋脊因代沃段热液黑烟囱体成矿物质来源:硫同位素的限制     

姚会强  周怀阳  彭晓彤  何高文 《海洋学报(英文版)》2010,29(5):25-33

选取胡安·德富卡洋脊(Juan de Fuca Ridge,JDFR)因代沃(Endeavour)段的17个热液黑烟囱体样品对其中的硫同位素进行分析测定,讨论了因代沃段热液活动区内黑烟囱体成矿的物质来源、将硫同位素数据与已发表的热液流体及硫化物数据耦合,并结合前人的成果得到如下认识:(1)因代沃段硫化物的硫同位素组成与其他无沉积物覆盖的洋脊硫化物硫同位素组成相似,然而其相比于南胡安·德富卡洋脊(South Juan de Fuca Ridge,SJFR)硫化物亏损重同位素;(2)结合前人研究成果,如果SJFR硫化物的硫全部来自基底玄武岩的淋洗与海水中的硫酸盐,那么因代沃段硫化物的硫可能有1%~3%来自沉积物的贡献,故提出因代沃段成矿系统中的硫来源主要来自基底玄武岩,同时伴随有少量海水硫酸盐来源及沉积物来源的硫加入;(3)将硫同位素数据与已发表的热液流体及硫化物数据进行耦合发现热液流体中的沉积物信号与硫化物中的硫可能来自不同的源,并提出沉积物端元可能位于下渗区。  相似文献   

朝不楞多金属矿外围1∶5万地电化学勘查应用     

谢邦廷 《地质与勘探》2016,52(5):885-892

运用地电化学技术在内蒙古半干旱草原风成砂浅覆盖区朝不楞多金属矿外围开展了1∶50000面积性勘查工作,并与常规土壤测量开展了对比研究。结果表明:(1)从元素异常强度、衬度、规模及与已知矿体空间对应性等方面对比,地电化学测量比常规土壤测量具有显著优越性;(2)地电化学测量在区域上显现出Ag-Pb-Zn-Bi-Cd及Cu-Co-Cr-Fe-La-Mo-Ni两套元素异常组合,与已知见矿钻孔中探测到的矽卡岩型铁矿及热液型铅锌矿均有出现具有较好的对应性;(3)在工区东部及东南部未知区发现多处异常强度、规模较大的多元素组合异常,建议开展进一步的勘查工作,以实现该矿区找矿突破。  相似文献   

激发极化法在辽宁本溪某矽卡岩型铜多金属矿勘查中的应用     

周多 《地质与勘探》2016,52(4):688-694

测区燕山期大面积中酸性岩浆侵入寒武系、奥陶系碳酸盐岩,在岩体外接触带上形成大量的矽卡岩,并伴有较强烈的铜多金属矿化。本次物探工作在1∶5万区调工作基础上,采用激电中梯与激电测深两种方法进行金属矿产勘查,圈定激电异常12个,反演了穿过JD3、JD7、JD8高极化异常体的形态,规模及埋深,并解译隐伏断裂2条。结合区内地质特征与钻孔资料,认为异常区的低阻高极化体是岩体外接触带上矽卡岩化蚀变带的反映,断裂为矿液运移、容矿提供了有利条件。该研究成果表明,激发极化法是寻找矽卡岩型铜多金属矿的有效方法。  相似文献