EROD activity, serum SDH and PAH biliary metabolites in sand flathead (Platycephalus bassensis) collected in Port Phillip Bay, Australia     

Gagnon MM  Holdway DA 《Marine pollution bulletin》2002,44(3):230-237

In order to evaluate the health status of fish inhabiting Port Phillip Bay, Australia, southern sand flathead (Platycephalus hassensis, N = 133) were collected at six stations throughout the Bay. Fish had a similar serum sorbitol dehydrogenase (SDH) activity level (p = 0.12), indicating that they were not experiencing hepatocellular injuries. Ethoxyresorufin-O-deethylase (EROD) activity was generally lower in the non-urbanized and non-industrialized southern part of the Bay. The highest EROD activity was observed in Hobson Bay, the closest station from Melbourne city. Naphthalene-type biliary metabolites were also highest in Hobson Bay with intermediate levels found in Corio Bay where refineries are present. An opposite trend was observed with the pyrene-type bile metabolites, the highest levels being observed in Corio Bay while intermediate levels were found in Hobson Bay. The ratio of naphthalene-type to benzo(a)pyrene (B(a)P)-type metabolites indicate that relatively to other sites sampled in Port Phillip Bay, Corio Bay is subjected to enriched petroleum hydrocarbons of pyrolytic origin. Temporal trends indicate that the availability of xenobiotics to fish remained unchanged over the 1990s.  相似文献   

Products and Mechanism of the Gas Phase Reaction of Ozone with β-Pinene     

Richard Winterhalter  Peter Neeb  Dirk Grossmann  Antje Kolloff  Osamu Horie  Geert Moortgat 《Journal of Atmospheric Chemistry》2000,35(2):165-197

Gas phase ozonolysis of -pinene was performedin a 570 l static reactor at 730 Torr and 296 K insynthetic air and the products were analysed by acombination of gas phase FTIR spectroscopy, HPLC andIC analyses of gas phase and aerosol samples,respectively. The reaction mechanism was investigatedby adding HCHO, HCOOH and H₂O as Criegeeintermediate scavenger and cyclohexane as OH radicalscavenger. Main identified products (yields inparentheses) in the presence of cyclohexane as OHradical scavenger were HCHO (0.65 ± 0.04),nopinone (0.16 ± 0.04), 3-hydroxy-nopinone (0.15± 0.05), CO₂ (0.20 ± 0.04), CO (0.030± 0.002), HCOOH (0.020 ± 0.002), the secondaryozonide of -pinene (0.16 ± 0.05), andcis-pinic acid (0.02 ± 0.01). The decompositionof the primary ozonide was found to yieldpredominantly the excited C₉-Criegee intermediateand HCHO (0.84 ± 0.04) and to a minor extent theexcited CH₂OO intermediate and nopinone (0.16± 0.04). Roughly 40% of the excitedC₉-Criegee intermediate becomes stabilised andcould be shown to react with HCHO, HCOOH and H₂O. The atmospherically important reaction of thestabilised C₉-Criegee intermediate with H₂Owas found to result in a nopinone increase of (0.35± 0.05) and in the formation of H₂O₂(0.24 ± 0.03). Based on the observed products,the unimolecular decomposition/isomerisationchannels of the C₉-Criegee intermediate arediscussed in terms of the hydroperoxide and esterchannels. Subsequent reactions of the nopinonylradical, formed in the hydroperoxide channel, lead tomajor products like 3-hydroxy-nopinone but also tominor products like cis-pinic acid. A mechanismfor the formation of this dicarboxylic acid isproposed and its possible role in aerosol formationprocesses discussed.  相似文献   

东营凹陷古近系砂岩成岩作用与孔隙演化   总被引：8，自引：2，他引：8  

游国庆潘家华  刘淑琴陈永峤 《岩石矿物学杂志》2006,25(3):237-242

东营凹陷是重要的油气富集区，在古近系地层发育湖相水下扇沉积、滨浅湖沉积和三角洲沉积等砂岩。砂岩的成岩作用及孔隙演化对储层的储集性能有重要影响。在对大量薄片和岩心进行分析的基础上，运用扫描电镜和X衍射粘土分析等手段，对东营凹陷砂岩储层的成岩作用和孔隙演化进行了研究。研究结果表明，该区压实作用、胶结作用使砂岩孔隙度降低，不稳定矿物的溶蚀作用和碳酸盐胶结物的溶解作用导致孔隙度增大。根据有机质的演化及粘土矿物的变化序列，在不同的构造单元，砂岩成岩作用和孔隙演化随埋深具有明显的规律性，可划分出原生孔隙带、原生次生孔隙带和次生孔隙带3个孔隙演化带，存在着较有利的次生孔隙发育带。  相似文献   

常州地区含水层系统土层压缩变形特征研究   总被引：6，自引：1，他引：6  

施小清  薛禹群  吴吉春  张云  于军  朱锦旗 《水文地质工程地质》2006,33(3):1-6

根据近十几年来分层标和含水层水位观测资料分析了常州地区土层压缩变形特征,表明承压含水砂层中的压缩变形不容忽视,且含水砂层的压缩变形与弱透水层的粘土、粉质粘土相似,均表现出明显的变形滞后现象.为此从水位与时间关系、土层变形与时间关系和水位与变形关系出发,结合室内试验方法,通过选取常州地区含水层系统中第一、二、三承压含水层以及二、三承压含水层间弱透水层和第三承压含水层下覆弱透水层的原状土样,采用单轴侧限压缩试验,分析了常州地区砂土和粉质粘土的次固结（蠕变）特性.试验结果表明常州地区不论是粉质粘土还是砂土,均存在一定的次固结变形,从而启示我们该地区地面沉降模拟中应同时考虑含水砂层的蠕变特性.  相似文献   

遥感技术在防震减灾领域中的应用   总被引：1，自引：0，他引：1  

吴焕娟  郭明珠  张皎 《地震工程与工程振动》2006,26(3):267-269

为了有效地组织救灾和震后重建,快速地获取地震造成的破坏程度、破坏范围成为至关重要的一环。遥感技术本身所具有的宏观性、时效性、经济高效性使其被广泛应用于防震减灾事业中。本文简单介绍了遥感技术的原理、特点及其在防震减灾领域中的应用历史及现状。在借鉴已有成果的基础上较系统地阐述了遥感技术在地震防灾方面的应用及展望。  相似文献   

南京地区新近系含膏砂泥地层的发现及其意义   总被引：2，自引：0，他引：2  

胡存礼杨献忠  杨祝良魏乃颐 袁平 《地质通报》2006,25(4):516-520

在进行南京市城市立体地质填图试点工作中,经钻探于仙林大学城发现一套新近系含膏砂泥地层,可与六合灵岩山雨花台组沉积地层对比.该地层的发现对于重新认识南京地区某些相类似断陷盆地基岩面之上的松散覆盖层的结构很有意义,对其在环境地质和工程地质中的影响进行了评述.同时,对地下水参与成矿作用进行了初步论述.  相似文献   

油气二次运移研究进展述评     

王连进  吴冲龙  王春辉 《地质通报》2006,(Z2)

油气运移,尤其油气的二次运移是石油地质学研究的重要内容,同时也是一个薄弱环节。20世纪90年代以来,油气二次运移研究所取得的主要进展是:①对油气二次运移机理的认识有了很大提高;②油气二次运聚模拟实验设计更加科学,实验结果更为可信;③油气二次运聚数值模拟水平有了长足进步。深入的综合研究和油气运移聚集的三维可视化模拟是今后的研究方向。  相似文献   

盐井二次定向对接连通施工工艺     

沙亚南  谢卫炜 《中国煤田地质》2007,19(A01):48-49,58

新汶矿业集团泰山盐化工ZJ03-PJ03井组为一对定向连通采卤井井组，采用二次定向钻井连通施工工艺，技术套管下入深度907．6m（8矿层顶板），有效地阻隔了上部含较多杂质的岩盐矿层，确保了卤水质量能满足盐化工的需要。本对接连通井组，采用随钻测量井斜、方位及钻进轨迹控制技术，为该井组的顺利对接提供了技术保障。  相似文献   

弱二次切变流轴对称涡旋演变的解析研究     

衡骏遥  周伟灿 《南京气象学院学报》2007,30(1):72-78

运用格林函数方法,给出了弱二次切变流轴对称涡旋演变的解析解.结果表明:当环境流中弱二次切变强度增加(减少)时,扰动动能的最大值增加(减小),扰动动能的变化加速(减速);而扰动涡旋的范围对扰动动能的大小与变化也存在一定的影响.  相似文献   

塔里木河流域绿洲边缘土壤蒸发与积盐的初步分析   总被引：8，自引：1，他引：7  

李国振 《干旱区地理》1998,21(1):29-33

本文通过对塔里木河流域土壤分的分析测定,视频研究了盐分积累的特点及其与蒸发的关系;盐分含量高,累积速度快、表聚性强。  相似文献