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51.
Thomas B. Boving Mark H. Stolt Janelle Augenstern Brian Brosnan 《Environmental Geology》2008,55(3):571-582
The control of polluted surface runoff and the assessment of possible impacts on groundwater is a concern at the local and
regional scale. On this background, a study investigates possible impacts of organic and inorganic pollutants (including bacteria)
originating from a permeable asphalt parking lot on the water quality immediately beneath it. The functioning of the permeable
pavement, including clogging and restricted vertical percolation, was also evaluated. Four nested sample ports (shallow and
deep) were installed below low- and high-traffic areas, including one port outside the parking lot. At least initially there
was a good hydraulic connection between the parking surface and the shallow sample ports. The presence of a geotextile layer
at the base of the parking lot structure, however, was identified in lab tests as one factor restricting vertical percolation
to the deeper ports. Clogging of the permeable surface was most pronounced in heavy traffic areas and below snow pile storage
areas. Corroborated by high electric conductivity and chloride measurements, sand brought in by cars during winter was the
principal cause for clogging. No bacteria or BOD were found in percolating water. Polycyclic aromatic hydrocarbons (PAH) were
present at concentrations near minimum detection limit. Nutrients (nitrate and phosphate) were being leached into the ground
via the permeable parking lot surface at annual flux rates of 0.45–0.84 g/m2/year. A multi-species tracer test demonstrated a retention capacity of the permeable parking lot structure of >90% for metals
and 27% for nutrients, respectively. 相似文献
52.
This work deals with disposal of slurries generated during the cutting and polishing processes of slabs of decorative sedimentary
carbonate rocks in the north western Sicily. At present, they are used as fillers of dismantled quarries near the sawmills
and, as a final step of reclamation, are covered with earth layers. In spite of such inexpensive solution, there is lack of
knowledge about the composition of the waste. In order to assess if there is any threat for the environment and to suggest
indications for alternative solutions, such as recycling or inactivation processes, the slurries were analysed by XR diffraction,
simultaneous thermal analysis, ICP/MS, ionic chromatography, FTIR, UV-Vis, COD and TOC measurements, grain size analysis.
Results indicate that the slurries can threaten the groundwater, because of the high chemical oxygen demand; furthermore they
can modify the mechanism of groundwater recharge, because of their grain size distribution. Some laboratory tests show that,
even in very aggressive conditions, the solid pollutants persist in the waste and slowly release into water the products of
their degradation. The slurry therefore should be subjected to inactivation treatment before disposal or, alternatively, recycled
as secondary raw material for a suitable process. 相似文献
53.
Concentrations of trace elements and heavy metals (Al, As, Ba, Cd, Co, Cr, Cu, Fe, Hg, Mn, Ni, Pb, Sb, Se, Sr, V and Zn) in
the Danjiangkou Reservoir, the water source area of the Middle Route of China’s interbasin South to North Water Transfer Project,
were analyzed using an Inductively Coupled Plasma Atomic Emission Spectrometer (ICP-AES) and compared with the national and
international standards for drinking water. The results indicated that concentrations of As, Pb, Sb and Se in the Reservoir
exceeded the standards and they would pose health risk for residents in the region and the water receiving areas of the interbasin
water transfer project. Spatial and temporal variability of the trace elements and heavy metals in the Reservoir implies their
mixed sources of natural processing and anthropogenic activities in the upper drainage of the Reservoir. The research results
would help develop water resource management and conservation strategy for the interbasin water transfer project. 相似文献
54.
Helmut Kerndorff Stephan Kühn Thomas Minden Dagmar Orlikowski Thomas Struppe 《Environmental Geology》2008,55(2):291-301
The aim of this research project is to identify, characterize and quantify natural attenuation (NA) processes in groundwater
affected by emissions of abandoned waste disposal sites in Berlin-Kladow/Gatow, Germany. It is part of the funding priority
called KORA established by the Federal Ministry for Education and Research (BMBF) to explore the extent to which NA can be
used for remedial purposes for varied forms of soil and groundwater contamination. Information on the emission behaviour of
individual parameters is generated on the basis of hydrogeochemical comparison of 20 years old and new data. Using groundwater-modelling
and CFC-analysis, information on the transport and retention of pollutants in groundwater is compiled. The microbial colonization
of contaminated aquifers is characterized by molecular biological methods [polymerase chain reaction (PCR) and denaturing
gradient gel electrophoresis (DGGE)] to differentiate between contaminated and not contaminated zones. 相似文献
55.
M. I. Holloway F. Bussy T. W. Vennemann 《Contributions to Mineralogy and Petrology》2008,155(1):111-121
Migmatites produced by low-pressure anatexis of basic dykes are found in a contact metamorphic aureole around a pyroxenite–gabbro
intrusion (PX2), on Fuerteventura. Dykes outside and inside the aureole record interaction with meteoric water, with low or
negative δ18O whole-rock values (+0.2 to −3.4‰), decreasing towards the contact. Recrystallised plagioclase, diopside, biotite and oxides,
from within the aureole, show a similar evolution with lowest δ18O values (−2.8, −4.2, −4.4 and −7.6‰, respectively) in the migmatite zone, close to the intrusion. Relict clinopyroxene phenocrysts
preserved in all dykes, retain typically magmatic δ18O values up to the anatectic zone, where the values are lower and more heterogeneous. Low δ18O values, decreasing towards the intrusion, can be ascribed to the advection of meteoric water during magma emplacement, with
increasing fluid/rock ratios (higher dyke intensities towards the intrusion acting as fluid-pathways) and higher temperatures
promoting increasing exchange during recrystallisation.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
56.
Shear strength characterization of municipal solid waste at the Suzhou landfill, China 总被引:5,自引:0,他引:5
The current practice of slope stability analysis for a municipal solid waste (MSW) landfill usually overlooks the dependence of waste properties on the fill age or embedment depth. Changes in shear strength of MSW as a function of fill age were investigated by performing field and laboratory studies on the Suzhou landfill in China. The field study included sampling from five boreholes advanced to the bottom of the landfill, cone penetration tests and monitoring of pore fluid pressures. Twenty-six borehole samples representative of different fill ages (0 to 13 years) were used to perform drained triaxial compression tests. The field and laboratory study showed that the waste body in the landfill can be sub-divided into several strata corresponding to different ranges of fill age. Each of the waste strata has individual composition and shear strength characteristics. The triaxial test results showed that the MSW samples exhibited a strain-hardening and contractive behavior. As the fill age of the waste increased from 1.7 years to 11 years, the cohesion mobilized at a strain level of 10% was found to decrease from 23.3 kPa to 0 kPa, and the mobilized friction angle at the same strain level increasing from 9.9° to 26°. For a confinement stress level greater than 50 kPa, the shear strength of the recently-placed MSW seemed to be lower than that of the older MSW. This behavior was consistent with the cone penetration test results. The field measurement of pore pressures revealed a perched leachate mound above an intermediate cover of soils and a substantial leachate mound near the bottom of the landfill. The measurements of shear strength properties and pore pressures were utilized to assess the slope stability of the Suzhou landfill. 相似文献
57.
Almeev Renat; Holtz Francois; Koepke Jurgen; Haase Karsten; Devey Colin 《Journal of Petrology》2008,49(1):25-45
Phase equilibria simulations were performed on naturally quenchedbasaltic glasses to determine crystallization conditions priorto eruption of magmas at the Mid-Atlantic Ridge (MAR) east ofAscension Island (7–11°S). The results indicate thatmid-ocean ridge basalt (MORB) magmas beneath different segmentsof the MAR have crystallized over a wide range of pressures(100–900 MPa). However, each segment seems to have a specificcrystallization history. Nearly isobaric crystallization conditions(100–300 MPa) were obtained for the geochemically enrichedMORB magmas of the central segments, whereas normal (N)-MORBmagmas of the bounding segments are characterized by polybariccrystallization conditions (200–900 MPa). In addition,our results demonstrate close to anhydrous crystallization conditionsof N-MORBs, whereas geochemically enriched MORBs were successfullymodeled in the presence of 0·4–1 wt% H2O in theparental melts. These estimates are in agreement with direct(Fourier transform IR) measurements of H2O abundances in basalticglasses and melt inclusions for selected samples. Water contentsdetermined in the parental melts are in the range 0·04–0·09and 0·30–0·55 wt% H2O for depleted and enrichedMORBs, respectively. Our results are in general agreement (within±200 MPa) with previous approaches used to evaluate pressureestimates in MORB. However, the determination of pre-eruptiveconditions of MORBs, including temperature and water contentin addition to pressure, requires the improvement of magma crystallizationmodels to simulate liquid lines of descent in the presence ofsmall amounts of water. KEY WORDS: MORB; Mid-Atlantic Ridge; depth of crystallization; water abundances; phase equilibria calculations; cotectic crystallization; pressure estimates; polybaric fractionation 相似文献
58.
G. Diego Gatta Nicola Rotiroti Martin Fisch Milen Kadiyski Thomas Armbruster 《Physics and Chemistry of Minerals》2008,35(9):521-533
The elastic and structural behaviour of the synthetic zeolite CsAlSi5O12 (a = 16.753(4), b = 13.797(3) and c = 5.0235(17) Å, space group Ama2, Z = 2) were investigated up to 8.5 GPa by in situ single-crystal X-ray diffraction with a diamond anvil cell under hydrostatic conditions. No phase-transition occurs within the P-range investigated. Fitting the volume data with a third-order Birch–Murnaghan equation-of-state gives: V 0 = 1,155(4) Å3, K T0 = 20(1) GPa and K′ = 6.5(7). The “axial moduli” were calculated with a third-order “linearized” BM-EoS, substituting the cube of the individual lattice parameter (a 3, b 3, c 3) for the volume. The refined axial-EoS parameters are: a 0 = 16.701(44) Å, K T0a = 14(2) GPa (βa = 0.024(3) GPa?1), K′ a = 6.2(8) for the a-axis; b 0 = 13.778(20) Å, K T0b = 21(3) GPa (βb = 0.016(2) GPa?1), K′ b = 10(2) for the b-axis; c 0 = 5.018(7) Å, K T0c = 33(3) GPa (βc = 0.010(1) GPa?1), K′ c = 3.2(8) for the c-axis (K T0a:K T0b:K T0c = 1:1.50:2.36). The HP-crystal structure evolution was studied on the basis of several structural refinements at different pressures: 0.0001 GPa (with crystal in DAC without any pressure medium), 1.58(3), 1.75(4), 1.94(6), 3.25(4), 4.69(5), 7.36(6), 8.45(5) and 0.0001 GPa (after decompression). The main deformation mechanisms at high-pressure are basically driven by tetrahedral tilting, the tetrahedra behaving as rigid-units. A change in the compressional mechanisms was observed at P ≤ 2 GPa. The P-induced structural rearrangement up to 8.5 GPa is completely reversible. The high thermo-elastic stability of CsAlSi5O12, the immobility of Cs at HT/HP-conditions, the preservation of crystallinity at least up to 8.5 GPa and 1,000°C in elastic regime and the extremely low leaching rate of Cs from CsAlSi5O12 allow to consider this open-framework silicate as functional material potentially usable for fixation and deposition of Cs radioisotopes. 相似文献
59.
实验研究不同盐离子对水分子拉曼效应的影响 总被引:3,自引:0,他引:3
对流体包裹体中常见的几种盐水溶液进行了拉曼光谱分析.采用了频移参数描述水分子拉曼峰的形变强度,并讨论了频移参数与盐度之间的关系.实验分析结果表明,盐度越大,频移参数越大,水分子拉曼峰形变越大.对频移参数曲线斜率分析显示,盐类对水分子拉曼峰偏移程度影响的强弱顺序为NaCl>Na2SO4>NaHCO3>Na2CO3.讨论了不同阳离子和阴离子对水伸缩振动拉曼峰的影响,结果表明,高价阳离子的影响明显高于低价阳离子;而阴离子对水拉曼峰影响的强弱顺序初步确定为Cl-≈SO2-4->HCO-3>CO2-3≈NO-3. 相似文献
60.