Sediment–water interactions of natural oestrogens under estuarine conditions     

J. C. Bowman  J. L. Zhou  J. W. Readman 《Marine Chemistry》2002,77(4)

The natural human female hormones oestrone and 17β-oestradiol have been implicated in the disruption of endocrine systems in some wildlife adjacent to sewage effluents. The sorption behaviour of these two compounds under estuarine conditions was studied by spiking either 2.55 μg of oestrone or 2.65 μg of 17β-oestradiol in kinetic experiments. In equilibrium experiments, 3 ng of oestrone or 3.2 ng of 17β-oestradiol was added in each of the centrifuge tubes. Sorption onto sediment particles was relatively slow, with sorption equilibrium being reached in about 70 and 170 h for oestrone and 17β-oestradiol, respectively. The effects of a variety of environmental parameters on sorption were studied including salinity, sediment concentration (SC), the presence of a third phase, particle size and, also, surfactant concentrations. Results show that although salinity did not induce any statistically significant effect on the sorption of 17β-oestradiol, it did statistically enhance the sorption of oestrone, and a salting constant of 0.3 l mol⁻¹ was derived. The partition coefficient for both compounds decreased with increasing sediment concentration, a phenomenon that has been widely reported and attributed to the presence of colloids (which could enhance dissolved concentrations). In this paper, the true partition coefficients for sediment particles (K_p^true) and colloidal particles (K_c^true) have been calculated, and a K_p^true value of 141 and 102 ml g⁻¹ was obtained for oestrone and 17β-oestradiol, respectively. In addition, K_c^true values for oestrone (222×10² ml g⁻¹) and 17β-oestradiol (135×10² ml g⁻¹) were two orders of magnitude higher than their respective K_p^true values, suggesting that the colloidal particles are significantly stronger sorbents for natural oestrogens than sediment particles. Particles of different sizes were found to have different partition coefficients due to the strong relationships between partition coefficients for the two compounds and particulate organic carbon (POC) contents and specific surface areas (SSAs). The presence of a surfactant was shown to reduce the partition coefficients for the two compounds, although its concentrations being used were higher than those normally found in the natural environment.  相似文献   

一种基于BP算法学习的小波神经网络   总被引：2，自引：1，他引：2  

陈哲  冯天瑾  陈刚 《中国海洋大学学报(自然科学版)》2001,31(1)

为发展 Szu的基于信号表示的小波神经网络 ,提出一种多输入多输出的小波网络模型 ,网络隐层采用框架小波函数、输出层采用 Sigmoid激励函数 ,并选用“熵误差函数”以加速网络的学习速度。奇偶判别和混沌时间序列预测例子的实验结果表明了它具有良好的函数逼近能力和推广能力 ,收敛速度和均方误差均优于相同结构的多层感知器模型。  相似文献   

Calculation of transverse hydrodynamic coefficients using computational fluid dynamic approach   总被引：1，自引：0，他引：1  

Amit Tyagi  Debabrata Sen 《Ocean Engineering》2006,33(5-6):798-809

Computational Fluid Dynamic (CFD) based on Reynolds Averaged Navier–Stokes equation is used for determining the transverse hydrodynamic damping force and moment coefficients that are needed in the maneuverability study of marine vehicles. Computations are performed for two geometrical shapes representing typical AUVs presently in use. Results are compared with available data on similar geometries and from some of the available semi-empirical relations. It is found that the CFD predictions compares reasonable well with these results. In particular, the CFD predictions of forces and moments are found to be nonlinear with respect to the transverse velocity, and therefore both linear and nonlinear coefficients can be derived. A discussion on the sources of the component forces reveal that the total force and moment variations should in fact be nonlinear.  相似文献   

比较原理在多有理数时滞区间系数离散系统的应用     

张彩虹  高存臣 《中国海洋大学学报(自然科学版)》2006,36(Z1):219-221

应用多组有理数时滞离散系统的比较原理和频域法,将多组有理数时滞区间系数离散系统化为多组有理数时滞定常离散系统,以判定其时滞无关稳定性,并举例说明了新定理的有效性和实用性。  相似文献   

Separation of Waves by Interpolation Method     

孙鹤泉  王永学 《中国海洋工程》2003,17(1)

1 .ＩｎｔｒｏｄｕｃｔｉｏｎＴｏｍｅａｓｕｒｅｔｈｅｒｅｆｌｅｃｔｉｏｎｏｆｉｎｃｉｄｅｎｔｗａｖｅｓｐｒｏｄｕｃｅｄｂｙａｐｈｙｓｉｃａｌｍｏｄｅｌｉｎａｗａｖｅｆｌｕｍｅｉｓａｃｏｍｍｏｎｐｒｏｂｌｅｍｗｉｔｈｐｈｙｓｉｃａｌｔｅｓｔｓｏｆｗａｖｅａｃｔｉｏｎｏｎｃｏａｓｔａｌｓｔｒｕｃｔｕｒｅｓ .Ｗａｖｅｓｇｅｎｅｒａｔｅｄｂｙｔｈｅｗａｖｅ ｍａｋｅｒｐｒｏｐａｇａｔｅｆｏｒｗａｒｄｉｎｔｈｅｗａｖｅｆｌｕｍｅａｎｄａｒｅｒｅｆｌｅｃｔｅｄｂｙｔｈｅｐｈｙｓｉｃａｌｍｏｄｅｌ,ａｎｄｔｈｅ…  相似文献   

On the radiation and diffraction of linear water waves by an infinitely long rectangular structure submerged in oblique seas   总被引：1，自引：0，他引：1  

Y.H. Zheng  P.F. Liu  Y.M. Shen  B.J. Wu  S.W. Sheng 《Ocean Engineering》2007,34(3-4):436-450

The radiation and diffraction of linear water waves by an infinitely long rectangular structure submerged in oblique seas of finite depth is investigated. The analytical expressions for the radiated and diffracted potentials are derived as infinite series by use of the method of separation of variables. The unknown coefficients in the series are determined by the eigenfunction expansion matching method. The expressions for wave forces, hydrodynamic coefficients and reflection and transmission coefficients are given and verified by the boundary element method. Using the present analytical solution, the hydrodynamic influences of the angle of incidence, the submergence, the width and the thickness of the structure on the wave forces, hydrodynamic coefficients, and reflection and transmission coefficients are discussed in detail.  相似文献   

A novel technique in analyzing non-linear wave-wave interaction   总被引：1，自引：0，他引：1  

Mohamed A.K. Elsayed   《Ocean Engineering》2006,33(2):168-180

During wave growth non-linear wave–wave interactions cause transfer of some wave energy from lower to higher wave periods as the spectrum grows. Wavelet bicoherence, which is a new technique in the analysis of wind–wave and wave–wave interactions, is used to analyze non-linear wave–wave interactions. A selected record of wind wave that contains the maximum wave height observed during 6 h of wave generation is divided into five segments and wavelet bicoherence is computed for the whole record, and for all divided segments. The study shows that the non-linear wave–wave interaction occurs at different bicoherence levels and these levels are different from one segment to another due to the non-stationarity feature of the examined data set.  相似文献   

双层局部开孔板沉箱对波浪反射的理论研究   总被引：1，自引：0，他引：1  

李玉成  刘洪杰滕斌 《海洋工程》2005,23(1):18-27,32

提出了一种用于研究由双层开孔板和一个不透水后板的开孔结构对斜向波反射率的理论分析方法。整个流域被分成三个子域，在每个子域内应用特征函数展开法以得到该域内包含未知展开系数的势函数的表达式，在速度势的展开中，考虑了非传播模态波浪的影响。通过匹配开孔板处的边界条件可以求解待定的展开系数，继而求解双层开孔板防波堤结构对斜向波的反射率。数值计算结果与试验结果进行了比较，符合较好。并进一步讨论了几个重要因素对反射系数的影响。  相似文献   

In-line response of a cylinder in oscillatory flow     

C.H.K. Williamson 《Applied Ocean Research》1985,7(2):97-106

The most widely used mathematical model to represent flow-induced in-line forces on structures is based on the Morison¹ equation. The present paper investigates the validity of using an extension of Morison's equation for non-stationary structures, by comparing predictions with results from a simple laboratory experiment. An elastically-mounted circular cylinder is placed in the sinusoidal flow of a U-tube, and responds in-line with the flow. Cylinder forces and responses are recorded over a range of Keulegan Carpenter numbers up to 35. An equation of motion is solved simply by using relative coordinates and by employing equivalent linearisation. The linear results are compared over a wide variation of parameters with solutions using the full nonlinear equation. Thereafter experimental results are compared with linear predictions.  相似文献   

分离入射波与反射波的解析方法   总被引：5，自引：0，他引：5  

王永学  彭静萍等 《海洋工程》2003,21(1):42-46,52

提出了一种新的分离入射波和反射波的解析方法（AM）。利用两点处的 波高信息，运用Hilbert变换得到波浪信号在复域内的解析表达式，不需要计算合成波高和相位差即可实现信号的分离。根据分离结果，可以精确地估计入射波与反射波的幅值以及反射系数等参数，能够获得入射波与反射波之间的相位信息，并且可方便地用于不规则波的分离。文中通过数值模拟与物理模型实验对AM法进行了检验，所得的结果与实际值非常吻合。  相似文献