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61.
黄河下游断面形态与水沙输移关系及数学模拟方法   总被引:4,自引:0,他引:4  
以前人对黄河下游的实测资料分析为基础,本文讨论断面形态与来水来沙关系、断面形态对输水输沙的影响,并根据实测资料,提出黄河下游弯段与直段断面冲淤变化的两种模式,建立了主流摆动及坍岸影响断面形态变化以及纵向冲淤量在断面的分布两种数学模拟方法。  相似文献   
62.
中国大陆自由空气重力场的初步研究   总被引:2,自引:0,他引:2       下载免费PDF全文
本文利用地面实测的重力资料计算并构制了从1°×1°到10°×10°平均的中国大陆自由空气重力异常图,并对这套图中所反映出来的基本事实进行了分析和解释,且就这些基本事实与大地构造、地壳均衡、地震活动的关系及其可能的地球动力学过程进行了讨论  相似文献   
63.
High concentrations of arsenic and humic substances in groundwater from the southwestern coastal plain of Taiwan were well known for their probable relationships with black-foot disease. In order to realize the relationships between the concentrations of humic substances and arsenic in this area, 24 well water samples were analyzed. After filtered through 0.45 μm glass fiber membrane in the field, samples were kept in the dark at 4℃ and then separated into six fractions with varying range of molecular weight (〈0.5, 0.5-1, 1-5, 5-10, 10-50 and 〉50 k Da) by ultrafiltration apparatus (Molecular/Por Stirred Cell system) in the lab. Concentrations of humic substances were measured by fluorescence spectrometer (HITACHI F-2000, ex=370, em=445) and arsenic by FIAS-AA (Perkin Elmer AAnalyst 100, FIAS-400). On average, only 6.2% of the total arsenic in water existed in the fraction of 〉0.5 k Da. and the others were complexed with humic substances (including humic acid and fulvic acid). The results demonstrated a distinct positive correlation between the concentrations of humic substances and arsenic.  相似文献   
64.
Arsenic is one of the most important single-substance toxicants in the environment. In Inner Mongolia of China, 300000 residents are believed to drink water containing 〉50 μg/L. Skin lesions have been known as the most common consequences resulting from chronic exposure to arsenic. To clarify the prevalence of arsenic-induced skin lesions, it is important to assess the impact of this problem on the target population, and to make future planning. We evaluated the association between multi-level inorganic arsenic exposure from drinking water and skin lesions in an arsenic-affected area in Inner Mongolia, China. 109 and 32 subjects fi'om high-level arsenic-affected (〉5 μg/L) village and low-level (≤50 μg/L) village were recruited and had detailed physical examination with special emphasis on arsenic-related skin lesions. Arsenic exposure was measured for each participant with As concentration of primary well and the duration of using the well was recorded. Arsenic-induced skin lesions including keratosis, pigmentation, and/or leucomelanosis were diagnosed in 56 and 3 subjects in the two villages, respectively. Logistic regression was conducted to calculate prevalence-odd ratios of skin lesions by levels of arsenic exposure with adjustment of sex, age group, smoking and duration of exposure. A consistent dose-response relationship between arsenic exposure level and skin lesion risk was observed.  相似文献   
65.
Biological iron and manganese removal utilizing indigenous iron and manganese oxidizing bacteria (IRB hereafter) in groundwater can also be applied to arsenic removal according to our pilot-scale test. The arsenic removal probably occurred through sorption and complexation of arsenic to iron and manganese oxides formed by enzymic action of IRB. We investigated the chemical properties of iron and manganese oxides in IRB floc and the valence state of arsenic sorbed to the floc to clarify the mechanisms of the arsenic [especially As (Ⅲ)] removal. The floc samples were collected from two drinking water plants using IRB (Jyoyo and Yamatokoriyama, Japan), and our pilot - scale test site where arsenic and iron removal using IRB is under way (Mukoh, Japan). The Jyoyo and Yamatokoriyama IRB floc samples were subjected to As (Ⅲ) and As(Ⅴ) sorption experiments. The elemental composition of the floc samples was measured. XANES spectra were collected on As, Fe and Mn K-edges at synchrotron radiation facility Spring 8 (Hyogo, Japan). FT-IR and the X-ray diffraction spectra of the samples were also obtained. The IRB floc contained ca. 35 % Fe, 0.3%-3.5% Mn and 2%-6% P. The samples were highly amorphous and contained ferrihidrites and hydrated iron phosphate. According to XANES analyses of IRB, As associated with IRB was in +5 valence state when As (Ⅲ) (or As (Ⅴ)) was added in laboratory sorption test, Fe in +3 valence state, and Mn a mixture of+3 and +4 valence states. Small shift was observed in the XANES spectra of IRB on As K-edge as the equilibration time of the sorption experiment was increased. Gradual oxidation of a small amount of As (Ⅲ) associated with IRB or change in arsenic binding with sorption site were the probable mechanism.  相似文献   
66.
Although inorganic species are predominant in natural systems, but there are many kinds of organoarsenic species such as methylated and phenylated arsenic compounds. Phenylarsonic acid (PA) is a degradation product of organoarsenics used for chemical warfare agents, which has been detected in well water at the disposal site of the agents in Japan. There are few reports studying behavior of PA in soil. In this study, PA was adsorbed onto ferrihydrite and its chemical forms were determined using high performance liquid chromatography connected to inductivity-coupled plasma mass spectrometry (HPLC-ICP-MS). 100 mg/kg of PA was mixed with 0.03 g of 2-line ferrihydrite. For each suspension, pH was adjusted by HNO3 or NaOH. Each sample was incubated for more than 19 hours and the final pH was measured. After filtration, the chemical form of arsenic in the filtrate was measured using HPLC-ICP-MS. In addition, ferrihydrite separated by filtration was dissolved by 3 ml of 0.5 M HCI and the arsenic species in the solution was detected by HPLC-ICP-MS (column: Tosoh TSKgel SuperlC-AP, eluent: 0.01 M HNO3). It was verified that PA is not degraded by heating in 0.5 M HCl solution. At pH 3.1, any arsenic compounds were not detected from the solution, because almost all arsenic species were adsorbed onto ferrihydrite at lower pH. At pH= 12, however, 7%-10% of inorganic arsenic was detected in the solution. In solid phase, there are some problems to determine the precise ratio of inorganic and organic species. When the solution includes Fe ion at 0.01 M level, the retention time of arsenic species drifted compared to those in standard solution, which makes it difficult to determine precisely the arsenic species adsorbed on ferrihydrite. Therefore, more study is needed to determine the ratio of inorganic and organic species in the system.  相似文献   
67.
张卫芸  唐亚 《山地学报》2006,24(B10):294-299
与低海拔地区相比,青藏高原的太阳辐射、水分条件、氧分压、气温等环境条件都有明显差异,青藏高原的植物在细胞壁厚度、栅栏细胞层数、通气组织大小、异细胞数量和分布、表皮附属物类型等方面与低海拔地区的相比也有较大的不同。综述了在青藏高原特殊的生态条件下,植物在形态和解剖方面的适应性表现,分析了该领域目前的研究特点和存在的一些问题,并在全球环境变化背景下,对其发展前景进行了展望,指出了未来的发展趋势。  相似文献   
68.
李建林  冯起 《干旱区地理》2006,29(5):658-662
以兰州市区96条主要的泥石流沟为例,利用分形理论的统计自相似性对泥石流沟数的累计分布随沟谷形态要素沟道比降、汇水面积和沟道长度的变化进行了分析;并与不同流域形态要素的分维进行了比较,探讨了分维不同的原因。兰州市区泥石流沟三个形态要素均具有统计意义上的自相似性,其中以汇水面积显示出分维最小(0.46),沟道长度次之(0.71),沟道比降最大(1.09)。分维的大小描述了作为系统的沟谷及其泥石流的形成的空间结构,即分形结构,同时也反映了不同形态要素对系统所起作用的差异,分维越小,所起作用越显著。其结果对西北干旱半干旱地区石流灾害的进一步研究与防治提供了新的思路。  相似文献   
69.
黔西南高砷煤的元素地球化学特征   总被引:1,自引:0,他引:1  
谢宏  聂爱国 《贵州地质》2006,23(2):109-113
通过分析黔西南高砷煤的元素地球化学特征,探索高砷煤中微量元素、稀土元素的地球化学行为,从而揭示了高砷煤的形成机理。分析表明,高砷煤与非高砷煤在微量元素含量方面存在较大差异,金、汞、铊矿石与龙潭煤系中的砷具有同源性,龙潭煤系页岩与峨眉山玄武岩在稀土元素组成上具有继承性。  相似文献   
70.
在人体胃肠液的酸度条件下,采用正辛醇-水分配体系模拟药物在人体肠胃中的分配情况,研究了中药和补铁制剂中铁的形态及其在人体内的吸收情况,并探讨了中药不同比例的配伍、胃肠酸度及还原性物质的存在对水溶态铁和醇溶态铁的影响。结果表明,药物溶液中的铁形态与药物本身特性和配伍情况有关,酸度及配伍对药物中铁的溶出率和溶液中铁的形态有较大影响,人体对铁的吸收与胃肠酸度和还原性物质的存在有关。  相似文献   
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