煤层气赋存的分形特征研究          下载免费PDF全文

王辰  冯增朝  周动  赵东  蔡婷婷 《地球物理学报》2019,62(9):3571-3579

本文利用红外热成像手段,对微小煤样内的甲烷吸附区进行了观察,并评估其吸附特征与在煤中的分布规律.研究表明煤中存在不同尺度与甲烷吸附能力的甲烷富集区,吸附/解吸甲烷时,甲烷富集区比邻近区域具有更明显的升温/降温现象.通过图像处理的方法对不同吸附压力条件下的红外热像图中的甲烷富集区进行提取,采用盒维数进行统计发现甲烷富集区符合分形规律.试验表明随着吸附压力升高,甲烷富集区的分形维数增大,分布初值减小.对两个不同煤田的煤层气富集区进行统计表明：从微米级到千米级尺度范围内,甲烷富集区分布具有分形特征,且分形维数均在1.5~2.00之间.  相似文献   

淮南采煤塌陷湖泊浮游植物优势种的营养动力学   总被引：3，自引：1，他引：2  

张鑫  易齐涛  谢凯  张思亮  余艳霞  张银 《湖泊科学》2018,30(3):713-722

在淮南潘谢矿区选取3个营养盐结构差异较大的塌陷湖泊,于2014—2015年4个季度分别对浮游植物群落结构组成进行调查,选取3个湖泊中的优势种(属)具尾蓝隐藻(Chroomonas caudata)、链形小环藻(Cyclotella catenata)和伪鱼腥藻(Pseudanabaena sp.)作为研究对象,设置不同的氮(N)、磷(P)浓度梯度进行营养动力学培养实验,并结合Monod方程,获得3个藻种在不同营养盐限制下的营养动力学参数.N限制下具尾蓝隐藻、小环藻和伪鱼腥藻的最大生长速率(μmax)和半饱和常数(Ks)分别为:0.66 d~(-1)、1.66 mg/L;0.37 d~(-1)、1.06 mg/L;0.71 d~(-1)、2.26 mg/L;P限制下它们的μmax和Ks则分别为:0.51 d~(-1)、0.023 mg/L;0.31 d~(-1)、0.035 mg/L;0.90 d~(-1)、0.015 mg/L.综上所述,在N充足时,伪鱼腥藻能够在竞争中形成优势,同时在P限制情况下易成为优势种,从营养动力学的角度揭示了其在塌陷湖泊中占据优势的营养盐动力学机制.研究结果可以为沉陷区水域开发利用和营养盐管理提供科学依据.  相似文献   

Adsorption characteristics of copper ion on nanoporous silica     

Yanhui Niu  Wenbin Yu  Zonghua Qin  Xin Nie  Shuguang Yang  Quan Wan 《Acta Geochimica》2019,(4):517-529

Adsorption by nanoporous media is critically involved in many fundamental geological and geochemical processes including chemical weathering,element migration and enrichment,environmental pollution,etc.Yet,the adsorption behavior of metal ions on nanoporous materials has not been systematically investigated.In this study,MCM-41 material with a monodisperse pore size(4.4 nm)and a large BET specific surface area(839 m^2/g)was hydrothermally prepared and used as a model silica adsorbent to study the adsorption characteristics of Cu^2+as a representative metal ion.The Cu^2+adsorption capacity was found to increase with increasing suspension pH in the range from 3 to 5 and to decrease in the presence of NaNO3.At 25℃,pH=5,and a solid-to-liquid ratio of 5 g/L,the adsorption capacity was determined to be 0.29 mg/g,which can be converted to a dimensionless partition coefficient of 45,indicating a strong enriching effect of nanoporous silica.The adsorption isotherm and kinetic data were fitted to several commonly used thermodynamic,kinetic,and diffusion models.The adsorption mechanism was also studied by Fourier transform infrared spectroscopy,X-ray photoelectron spectroscopy and synchrotron-based X-ray absorption spectroscopy.The results suggest that Cu2+ion adsorption is an entropy-driven endothermal process,possibly involving both outer-sphere and inner-sphere complexes.  相似文献   

东濮凹陷沙一段源岩的成烃动力学参数特征   总被引：1，自引：0，他引：1  

常振恒  沈忠民  陈义才  汪巍 《矿物岩石》2005,25(1):80-82

运用成烃动力学原理对东濮凹陷沙一段源岩进行研究表明,沙一段源岩中的成烃有机质具有非均质性．沙一段目前正在生烃的活化能范围为90kJ／mol～110kJ／mol之间．对应的成熟生烃门限埋深约在2200m左右。该结果为评价沙一段源岩提供了基于动力学上的证据．同时对推进沙一段的油气勘探具有积极意义。  相似文献   

Untersuchungen zur adsorptiven Abtrennung von leichtflüchtigen chlorierten Kohlenwasserstoffen (LCKW) aus huminstoffhaltigen Wässern mit neuartigen Adsorberpolymeren und Aktivkohlen. Teil II:: Dynamik der Adsorption     

A. Kowaszik  K. Pichowski 《洁净——土壤、空气、水》1999,27(6):437-445

Investigations of the Adsorptive Separation of Volatile Chlorinated Hydrocarbons (VCHC) from Water with Humic Substance by Novel Polymeric Adsorbents and Activated Carbons. Part II: Dynamics of Adsorption In this publication, the dynamics of adsorption of different volatile chlorinated hydrocarbons (VCHC) (1,2-dichloroethane, 1,1,1-trichloroethane, trichloroethene) and a humic substance from water as well as of these VCHC from water with humic substance onto novel polymeric ad-[QJ][HR] sorbents (WOFATIT EP 63, DOWEX XUS 43493, MACRONET MN 100 and MN 200) was studied in comparison to activated carbons (NORIT ROW 0.8 SUPRA, PRECOLITH BKK 3, HYDRAFFIN CG). The obtained breakthrough curves and the following predicted characteristic values reveal that the polymeric adsorbents do not remove or remove the humic substance only with low adsorption capacity in contrast to the activated carbons. At the adsorption of the VCHC from water with humic substance it was determined that the influence of the humic substance on the adsorption capacity is substantially less on polymeric adsorbents than on activated carbons.  相似文献   

Assessment of the impact of pore-scale mass-transfer restrictions on microbially-induced stable-isotope fractionation     

《Advances in water resources》2014

Stable-isotope fractionation has become an established method for the assessment of contaminant biodegradation in groundwater. At the pore scale however, mass-transfer processes can limit the bioavailability of chemical species and therefore affect the observed fractionation. This can challenge the application of stable-isotope analysis in practice. A linear-exchange model provides a computational link between the microbially-induced isotope fractionation, determined under ideal conditions, and the fractionation observed under conditions of limited bioavailability. This simplifying conceptual approach allows for accurately estimating the mass-transfer limited degradation rates but its applicability for stable-isotope fractionation at the pore scale has not been evaluated yet. In this study, we perform high-resolution numerical simulations of microbial degradation and stable-isotope fractionation of a chemical species in a pore-scale model. The numerical results are compared to theoretical predictions derived from the linear-exchange model. Our results show an overall good agreement between numerical simulations and theoretical predictions, which confirms the applicability of the theoretical approach and of the value for the mass-transfer coefficient previously derived from the geometry of the pore space. In addition we provide a quantitative link between the value of the observable fractionation factor and the effective bioavailability of a biodegradable contaminant.  相似文献   

UV/Peroxyacetic Acid Mediated Chlorophenol Congener Degradation          下载免费PDF全文

Swati Sharma  Zagabathuni Venkata Panchakshari Murthy 《洁净——土壤、空气、水》2014,42(3):276-283

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Bioaccumulation of cadmium in the ascidian Styela clava (Herdman 1881)     

《African Journal of Marine Science》2013,35(3):289-295

The processes of bioaccumulation and elimination of cadmium by tissues of Styela clava (Herdman 1881) were investigated based on a semi-static two-compartment model. The kinetic parameters (accumulation rate constant k ₁, elimination rate constant k ₂, bioconcentration factor BCF, biological half-life t _1/2 and maximum equilibrium concentration C _Amax) were obtained by non-linear regression. The results showed that S. clava accumulates cadmium from its aquatic environment. BCF decreased with increasing metal concentration in the water, and when the accumulation achieved balance, C _Amax correlated positively with metal concentrations in the water. Concentrations of cadmium in different tissues of S. clava were: gonad > digestive gland ≈ other parts > tunic. The t _1/2 values for cadmium were 15.54-50.40 days in the accumulation process and 11.53-24.55 days in the elimination phase. The high rate of accumulation and elimination of cadmium from the body reveals the potential of the organism to be used as a biomonitor of short-term cadmium fluctuation in marine systems.  相似文献   

Mechanisms and factors affecting the adsorption of sodium alginate onto modified clays     

林勇新  曹西华  宋秀贤  王楠  俞志明 《中国海洋湖沼学报》2013,31(4):867-875

Algal organic materials (AOMs) are one critical factor affecting the efficiency of modified clays used for the mitigation of harmful algal blooms (HABs). This study was conducted to develop a deeper understanding of the mechanisms and factors affecting the adsorption of AOMs onto modified clays. Sodium alginate (polysaccharide) and kaolinite modified with polyaluminium chloride (PACl) were used as AOMs and modified clay model substances, respectively, and the effects of modifier dosage, contact time, solution pH and ionic strength were investigated through batch adsorption experiments. Kinetics revealed that the alginate adsorption rate was described well by a pseudo-second order model. PACl effectively enhanced the adsorption capacity of kaolinite and increased the adsorption rate, and the optimum additive amount of PACl was 5%. The experimental data fitted both the Freundlich and Langmuir adsorption equations well. The adsorption thermodynamics for alginate onto modified clays suggests that alginate adsorption is a spontaneous process. The adsorption of alginate onto modified clays was highly dependent on pH, with a decrease in adsorption observed with increased pH to 9.48, but the opposite was true above pH 9.48. Finally, adsorption increased with increasing ionic strength.  相似文献   

The Seashell Wastes as Biosorbent for Reactive Dye Removal from Textile Effluents     

Daniela Suteu  Doina Bilba  Magdalena Aflori  Florica Doroftei  Gabriela Lisa  Marinela Badeanu  Teodor Malutan 《洁净——土壤、空气、水》2012,40(2):198-205

This study investigates structural and adsorption properties of the powdered waste shells of Rapana gastropod and their use as a new cheap adsorbent to remove reactive dye Brilliant Red HE‐3B from aqueous solutions under batch conditions. For the powder shells characterization, solubility tests in acidic solutions and X‐ray diffraction (XRD), scanning electron microscopy (SEM), energy‐dispersive X‐ray spectroscopy (EDX), Fourier transform IR spectroscopy (FT‐IR) and thermogravimetric analyses were performed. The results revealed that the adsorbent surface is heterogeneous consisting mainly from calcium carbonate layers (either calcite or aragonite) and a small amount of organic macromolecules (proteins and polysaccharides). The dye adsorptive potential of gastropod shells powder was evaluated as function of initial solution pH (1–5), adsorbent dose (6–40 g L^?1), dye concentration (50–300 mg L^?1), temperature (5–60°C), and contact time (0–24 h). It was observed that the maximum values of dye percentage removal were obtained at the initial pH of solution 1.2, shells dose of 40 g L^?1, dye initial concentration of 50–50 mg L^?1 and higher temperatures; the equilibrium time decreases with increasing of dye concentration. It is proved that the waste seashell powder can be used as low cost bioinorganic adsorbent for dyes removal from textile wastewaters.  相似文献