Treatment of Refractory Organics Contained in Actual Agro‐Industrial Wastewaters by UV/H2O2     

Ahmed Bedoui  Kaiis Sindi  Nasr Bensalah 《洁净——土壤、空气、水》2008,36(4):373-379

In this work, the treatment of actual agro‐industrial wastewaters (IWW) by a UV/H₂O₂ process has been investigated. The aqueous wastes were received from industrial olive oil mills and then treated by laboratory scale physicochemical methods, i. e., coagulation using ferrous and aluminum sulfate, decantation, filtration and adsorption on activated carbon. These wastes are brown colored effluents and have a residual chemical oxygen demand (COD) in the range of 1800 to 3500 mgO₂ L^–1, which cannot be further eliminated with physicochemical processes. The UV/H₂O₂ treatments were carried out under monochromatic irradiation at 254 nm using a thermostated reactor equipped with a mercury vapor lamp located in an axial position. The effects of initial H₂O₂ concentration, initial COD, pH and temperature have been studied in order to determine the optimum conditions for maximum color and COD removals. The experimental results reveal the suitability of the UV/H₂O₂ process for both removal of high levels of COD and effectively decolorizing the solution. In particular, 95% of color removal and 90% of COD removal were obtained under conditions of pH = 5 and 32°C using 2.75 g H₂O₂ g^–1 COD L^–1 during 6 h of UV‐irradiation. The treatment is unaffected by pH over the range 2 to 9. In addition, the COD removal is improved by increasing the temperature, whereas the color removal has not been affected by this parameter. The results show that the hydroxyl radicals generated from the catalytic decomposition of H₂O₂ by UV‐irradiation of the solution could be successfully used to mineralize the organics contained in IWW. The mineralization of the organics seems to occur in three main sequential steps: the first is the rapid decomposition of tannins leading to aromatic compounds, which are confirmed by the decolorization of the IWW; the second step corresponds to the oxidation of aromatics leading to aliphatic intermediates, which occurs by the cleavage of an aromatic ring, and is established by the removal of aromatics, and the final step is the slow oxidation of the aliphatic intermediates, which is measured by the COD removal.  相似文献   

环境水中化学需氧量的反向流动注射分析法研究   总被引：1，自引：1，他引：0  

陈慧  安太成  房彦军  全晓塞 《岩矿测试》1999,18(3)

研究了Ｃｅ（ＳＯ４）２Ｈ２ＳＯ４体系反向流动注射分析法测定环境水中化学需氧量（ＣＯＤ）的试验条件。在２．５～１６０．０ｍｇ／Ｌ线性范围内,采样频率达到２５／ｈ,Ｃｌ－的质量浓度至２５００ｍｇ／Ｌ无干扰。对６０ｍｇ／Ｌ的标准试样重复测定１１次,相对标准偏差为０．７９％,检出下限为２．５ｍｇ／Ｌ。该法便于实际工作中ＣＯＤ的连续监测,用于河水、池塘水分析,获得结果与经典的重铬酸钾法相对照,相关性良好  相似文献   

Comparison of Treatment Efficiency and Energy Consumption of Batch and Continuous Electrocoagulation in Urban Wastewater     

Alper Erdem Yılmaz  Yeşim Dede Sağsöz  Baybars Ali Fil  Murat Tolga Yılmaz 《洁净——土壤、空气、水》2023,51(1):2200032

In this study, domestic wastewater was used as the electrolyte. The work was carried out with an up-flow tubular reactor, made of stainless steel that was used as cathode, while the anode electrode material was aluminum and varying values of flow regime (25, 50, 75 and 100 mL/s for continuous system), initial pH value (5, 6, 7 and 7.8) and current intensity (10, 15 and 20 A) were applied. For domestic wastewater with natural pH, the effluent pH was >9 in the batch system, while in the continuous system the pH was 8–8.5. Likewise, while the effluent temperature was up to 60°C in the batch system, it was at most 35°C in the continuous system. However, the energy consumption values in the continuous system were considerably lower compared with the batch system. At a current intensity of 10 A, 80 kWh of energy per unit volume was consumed in the batch system, while it was 50 kWh for the continuous system. The present results show that the batch system can be used for small wastewater streams whereas the continuous system can be used for large wastewater streams for domestic wastewater treatment.  相似文献   

太湖流域上游西苕溪支流的营养状态特征及成因分析     

王欢  袁旭音  陈海龙  许海燕  李正阳 《湖泊科学》2015,27(2):208-215

为了解太湖流域上游支流水体的营养状态特征及流域附近土地利用对水质的影响,选取了入湖水系西苕溪的10条主要支流进行了野外采样和实验室研究.研究结果表明,支流总磷(TP)、颗粒磷(PP)、总溶解性磷(TDP)、总氮(TN)、铵态氮(NH+4-N)、硝态氮(NO-3-N)含量季节间差异较大,TP含量范围为0.033~0.205 mg/L,PP含量范围为0.007~0.104 mg/L,TN含量范围为2.014~5.921 mg/L,NH+4-N含量范围0.021~1.659 mg/L,NO-3-N含量范围1.082~3.415mg/L,COD范围为6.5~15.5 mg/L.总体上呈现为枯水期平水期丰水期.部分支流受到不同程度的氮污染.利用水质参数进行聚类分析,可以将10条支流分成4类,其水体营养特征与周围环境相联系.支流营养盐、COD的通量明显受流量控制,表现为丰水期平水期枯水期.土地利用类型的差异是导致其水质变化的主要原因,耕地和居民地主要起源的作用,林地和草地主要起汇的作用.在丰水期和枯水期,对各指标影响最大的土地利用类型为耕地和林地;在平水期,对TP影响最大的是居民地,而对TN影响最大的是林地.  相似文献   

南极麦克斯韦尔湾及邻近海域高锰酸钾指数研究   总被引：1，自引：1，他引：0       下载免费PDF全文

袁峻峰  陈皓文  李永祺  吴宝铃 《极地研究》1998,10(3):55-59

为了研究南极水域的污染状况,于１９９３年１２月～１９９４年２月对南极麦克斯韦尔湾及邻近海域的高锰酸钾指数（ＣＯＤＭｎ）的变化和分布状况进行了监测。３９个站次的测值在０．３３４～１．９５９ｍｇ／Ｌ之间,符合中国《海水水质标准》（ＧＢ３０９７－８２）第一类水质（３．０００ｍｇ／Ｌ）要求。各考察站附近的测值高;长城湾内高于湾口及湾外。分析了湾内、湾口和湾外在１９９３年１２月、１９９４年１月及２月的变化情况和原因;对ＣＯＤＭｎ的主要来源进行了研究分析;并对南极长城站及邻近海域的环境保护和研究提出了建议。  相似文献   

The flux of land-based source pollutants from tumen river system entering the sea of Japan   总被引：1，自引：0，他引：1  

殷兴军  尹澄清 《中国地理科学(英文版)》1998,8(3):239-245

Ｉ．ＩＮＴＲＯＤＵＣＴＩＯＮ“Ａｇｅｎｄａ２１”ｒｅｃｏｇｎｉｚｅｓｔｈｅｉｍｐｏｒｔａｎｃｅｏｆｌａｎｄｂａｓｅｄｓｏｕｒｃｅｐｏｌｕｔａｎｔｓｔｏｍａｒｉｎｅｐｏｌｕｔｉｏｎ．Ｃｏａｓｔａｌｗａｔｅｒｉｓｏｆｇｒｅａｔｓｉｇｎｉｆｉｃａｎｃｅ...  相似文献   

台风对工厂化虾池生态系统中COD的影响     

韦蔓新  童万平  何本茂 《广东海洋大学学报》2005,25(6):46-50

根据2003年7月台风发生期间工厂化虾池生态系中的实测数据,重点分析了不同养成密度虾池生态系中COD的变化状况及其影响因素。结果表明:台风气候对虾池生态系中COD的影响较大,台风发生时COD含量相对较高,台风前后相对较低;台风气候对COD周日变化的影响以养成密度大的养殖池较为显著,养成密度小的养殖池则影响较小;COD与环境因子之间的相关性差异也较大,台风前,养成密度大的养殖池与NO2-呈显著正相关(r=0.668),与T和Chl.a呈负相关关系(r=-0.608或r=-0.633);台风后与PO4-P、NH4+和Chl.a之间则表现的显著正相关(r=0.907、0.832、0.846)。而养成密度低的养殖池,台风前COD与pH呈显著负相关(r=-0.732),台风后与PO4-P和NO2-分别呈显著正相关(r=0.720)和良好正相关(r=0.591)。但在台风发生时,二池均无此类相关性出现。  相似文献   

用于有机废水处理的改性膨润土的制备新方法研究   总被引：2，自引：0，他引：2       下载免费PDF全文

凌辉  鲁安怀  王长秋 《岩石矿物学杂志》2011,30(1):135-140

提出一套不同于传统工艺的有机化膨润土制备方法,并首次采用COD(化学需氧量)与XRD(X射线衍射)双重指标衡量有机化膨润土的合成效果。COD测试表明,选择合适的改性剂种类和用量,是制备废水处理用有机化膨润土的两个前提。XRD分析说明,新工艺制备的有机化膨润土中蒙脱石的d001明显增大,有机改性剂长链分子已经插入蒙脱石矿物层间,合成效果良好。新的有机化膨润土合成工艺省去了过滤、洗涤、烘干、粉碎等步骤,能耗大大降低,成本优势明显,能够有力地促进有机化膨润土在废水处理领域的规模化应用。  相似文献   

Characteristics of organic matter as indicators of pollution from small‐scale livestock and nitrate contamination of shallow groundwater in an agricultural area     

Rak‐Hyeon Kim  Jeongho Lee  Ho‐Wan Chang 《水文研究》2003,17(12):2485-2496

The main purpose of this study was to examine the hydrogeochemical factors leading to nitrate contamination of shallow groundwater in an agricultural area. Another purpose was to identify relationships between variations in organic matter levels (as estimated by the BOD and COD parameters) of groundwater that transports effluent from small‐scale livestock holdings. Major cations, anions, BOD and COD of organic matter and total coliforms were analysed. It was found that groundwaters beneath cultivated areas and areas carrying livestock had higher concentrations of calcium, nitrate and chloride than did freshwater. Above all, the nitrification process increased concentrations of nitrate. Nitrate levels were depressed in some places where the groundwater was low in dissolved oxygen. Groundwaters affected by livestock activities showed high concentrations of organic matter (BOD, COD) and high microbial concentrations (as indicated by total coliforms). The COD/BOD ratio increased in the downward direction. It was inferred that this was due to the faster loss of easily biodegradable organic matter compared with non‐biodegradable organic matter proceeding away from a discharge. Accordingly, it is possible to trace effluent in a small area back to a point source by monitoring the COD/BOD ratio of groundwater. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

Color Removal from Synthetic Textile Wastewater by Sono‐Fenton Process     

Celalettin Özdemir  Muhammed Kamil Öden  Serkan Şahinkaya  Erkan Kalipçi 《洁净——土壤、空气、水》2011,39(1):60-67

In this study, the oxidative decolorization of C.I. reactive yellow 145 (RY 145) from synthetic textile wastewater including RY 145 and polyvinyl alcohol by Fenton and sono‐Fenton processes which are the combination of Fenton process with ultrasound has been carried out. The effects of some operating parameters which are the initial pH of the solution, the initial concentration of Fe²⁺, H₂O₂, and the dye, temperature, and agitation speed on the color and chemical oxygen demand (COD) removals have been investigated. The optimum conditions have been found as [Fe²⁺] = 20 mg/L, [H₂O₂] = 20 mg/L, pH 3 for Fenton process and [Fe²⁺] = 20 mg/L, [H₂O₂] = 15 mg/L, pH 3 for sono‐Fenton process by indirectly sonication at 35 kHz ultrasonic frequency and 80 W ultrasonic power. The color and COD removal efficiencies have been obtained as 91 and 47% by Fenton process, and 95 and 51% by sono‐Fenton processes, respectively. Kinetic studies have been performed for the decolorization of RY 145 under optimum conditions at room temperature. It has been determined that the decolorization has occurred rapidly by sono‐Fenton process, compared to Fenton process.  相似文献