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101.
Numerical studies of vertical Cl−, δ2H and δ18O profiles in the aquifer–aquitard system in the Pearl River Delta,China 
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下载免费PDF全文 Sedimentation may have a significant effect on the transport of solutes and environmental isotopes in sediment. The depth profiles of the Cl?, δ2H and δ18O in a borehole in the aquifer–aquitard system in the Pearl River Delta (PRD), China, were obtained by centrifuging the core sediment samples. A one‐dimensional model based on the sedimentation and sea level changes of the PRD during the Holocene was built to investigate numerically the transport mechanisms of Cl?, δ2H and δ18O. The sedimentation process was modelled as a moving boundary problem with the moving rate equal to the sedimentation rate. The model was calibrated and the parameters were obtained by comparing simulated and measured data. Very good agreement between all the three observed profiles and the simulated ones demonstrates the reliability of the model and the parameters. Simulation results show that the shapes of the curves are controlled by the combination of sedimentation and upper boundary conditions. Diffusion solely is adequate to reconstruct the observed profiles, which indicates that diffusion is the dominant vertical transport mechanism. The effective diffusion coefficients of the aquitard and the aquifer equal to 5.0 × 10?11 and 2.0 × 10?10 m2/s, respectively. The results of this study will help in understanding the transport mechanisms of solutes and environmental tracers in deltas with geology and hydrogeology similar to the PRD. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
102.
海洋混凝土结构的表面氯离子浓度反映了海洋氯化物环境的腐蚀作用强度,是海洋混凝土结构耐久性分析和定量设计的重要参数。本文依据国内外不同地区的大量自然暴露试验数据,通过数理统计和回归分析,确定了各种海洋环境条件下表面氯离子浓度的统计特征值,分析了海洋潮汐浪溅区混凝土中氯离子的传输机理和积聚规律,揭示了水胶比对混凝土表面氯离子浓度的影响规律,进而综合考虑水胶比、胶凝材料种类和时变特性等因素的影响,建立了海洋潮汐浪溅区混凝土表面氯离子浓度的改进计算模型。结合国内外各种表面氯离子浓度经验模型的预测结果和海洋自然暴露试验的实测数据,对比验证了所建立表面氯离子浓度计算模型的有效性和适用性,为海洋氯化物环境下混凝土结构的耐久性设计和服役寿命分析提供了重要边界条件。 相似文献
103.
氯离子侵蚀已成为影响海洋及近海环境中混凝土结构耐久性的主要因素。考虑材料组成的非匀质特性,将混凝土看作由粗骨料、硬化水泥砂浆及二者界面过渡区组成的三相复合材料的细观层次方法,是开展物质传输过程研究的新途径。建立非饱和混凝土中氯离子传输的一维非线性对流扩散方程,并利用伽略金加权余数法给出了该方程的有限元形式,采用适用于物质传输的细观格构网络模型开展了水分及氯离子在非饱和混凝土中传输过程及分布规律研究,分析了干湿循环周期和循环机制对水分及氯离子传输性能的影响规律。数值计算结果表明,干湿交替下,相同的干燥时间,非饱和混凝土内水分及氯离子的侵入深度主要取决于湿润时间,而干燥时间和循环周期数则影响混凝土表层氯离子含量,并在混凝土表层10 mm处有浓度集中现象。 相似文献
104.
Zygosaccharomyces rouxii is a salt-tolerant yeast species capable of removing cadmium(Cd) pollutant from aqueous solution. Presently, the physiological characteristics of Z. rouxii under the stress of sodium chloride(NaCl) and Cd are poorly understood. This study investigated the effects of NaCl and Cd on the growth, oxidative stress and antioxidant enzyme activities of Z. rouxii after stress treatment for 24 h. Results showed that NaCl or Cd alone negatively affected the growth of Z. rouxii, but the growth-inhibiting effect of Cd on Z. rouxii was reduced in the presence of NaCl. Flow cytometry assay showed that under Cd stress, NaCl significantly reduced the production of reactive oxygen species(ROS) and cell death of Z. rouxii compared with those in the absence of NaCl. The activities of superoxide dismutase(SOD), catalase(CAT), and peroxidase(POD) of Z. rouxii were significantly enhanced by 2%–6% NaCl, which likely contributed to the high salt tolerance of Z. rouxii. The POD activity was inhibited by 20 mg L-1Cd while the SOD and CAT activities were enhanced by 8 mg L-1 Cd and inhibited by 20 mg L-1 or 50 mg L-1 Cd. The inhibitory effect of high-level Cd on the antioxidant enzyme activities of Z. rouxii was counteracted by the combined use of NaCl, especially at 6%. This probably accounted for the decrease in Cd-induced ROS production and cell death of Z. rouxii after incubation with NaCl and Cd. Our work provided physiological clues as to the use of Z. rouxii as a biosorbent for Cd removal from seawater and liquid highly salty food. 相似文献
105.
Over the last two decades, the probabilistic assessment of reinforced concrete (RC) structures under seismic hazard has been developed rapidly. However, little attention has been devoted to the assessment of the seismic reliability of corroded structures. For the life‐cycle assessment of RC structures in a marine environment and earthquake‐prone regions, the effect of corrosion due to airborne chlorides on the seismic capacity needs to be taken into consideration. Also, the effect of the type of corrosive environment on the seismic capacity of RC structures has to be quantified. In this paper, the evaluation of the displacement ductility capacity based on the buckling model of longitudinal rebars in corroded RC bridge piers is established, and a novel computational procedure to integrate the probabilistic hazard associated with airborne chlorides into life‐cycle seismic reliability assessment of these piers is proposed. The seismic demand depends on the results of seismic hazard assessment, whereas the deterioration of seismic capacity depends on the hazard associated with airborne chlorides. In an illustrative example, an RC bridge pier was modeled as single degree of freedom (SDOF). The longitudinal rebars buckling of this pier was considered as the sole limit state when estimating its failure probability. The findings show that the life‐cycle reliability of RC bridge piers depends on both the seismic and airborne chloride hazards, and that the cumulative‐time failure probabilities of RC bridge piers located in seismic zones can be dramatically affected by the effect of airborne chlorides. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
106.
107.
In order to study the durability behavior of marine reinforced concrete structure suffering from chloride attack,the structural service life is assumed to be divided into three critical stages,which can be characterized by steel corrosion and cover cracking.For each stage,a calculated model used to predict the lifetime is developed.Based on the definition of durability limit state,a probabilistic lifetime model and its time-dependent reliability analytical method are proposed considering the random natures of influencing factors.Then,the probabilistic lifetime prediction models are applied to a bridge pier located in the Hangzhou Bay with Monte Carlo simulation.It is found that the time to corrosion initiation t0 follows a lognormal distribution,while that the time from corrosion initiation to cover cracking t1 and the time for crack to develop from hairline crack to a limit crack width t2 can be described by Weibull distributions.With the permitted failure probability of 5.0%,it is also observed that the structural durability lifetime mainly depends on the durability life t0 and that the percentage of participation of the life t0 to the total service life grows from 61.5% to 83.6% when the cover thickness increases from 40 mm to 80 mm.Therefore,for any part of the marine RC bridge,the lifetime predictions and maintenance efforts should also be directed toward controlling the stage of corrosion initiation induced by chloride ion. 相似文献
108.
109.
110.
The results of a study evaluating the recharge/discharge conditions of an unconfined stressed granitic aquifer situated in a semi‐arid region of Andhra Pradesh, Southern India are presented. Over the last three decades, excessive withdrawal of groundwater has drastically lowered the water table to the bedrock. The watershed studied was divided into four zones based on geomorphology and hydrogeological conditions. Using environmental chloride data pertaining to groundwater, soil depth profiles, and some hydrogeologic and hydrochemical observations, a recharge model for the watershed was developed. The model revealed that the bulk of the vertical recharge in the western elevated land occurs through preferred pathways and that a small fraction occurs through the soil matrix. In addition, the watershed has a poor hydrogeologic fabric, as indicated by the small range of matrix flow recharge (1 to 1·5% of rainfall) among the four zones. The dominating preferential flow was high (～16% of the annual average rainfall) in the valley fills, but decreased to 5–5·5% in the plains. Furthermore, although the bulk of the recharge occurs vertically, considerable lateral movement of groundwater down the slope indicates that sequential hydrochemical changes occur. Distinct geomorphological features that exist in the watershed support the proposed model. Situations similar to those described above may exist in numerous watersheds in the granitic hard rock region; therefore, information obtained from investigations conducted in this watershed can aid in the development of plans enabling the sustainable exploitation of watersheds that have not yet been developed, as well as implementation of appropriate rainwater conservation measures in over‐exploited watersheds. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献