White-light promoted degradation of leucopterin and related pteridines dissolved in seawater, with evidence for involvement of complexation from major divalent cations of seawater     

Arthur F. Landymore  Naval J. Antia 《Marine Chemistry》1978,6(4):309-325

The photochemical instability of several related pteridines in seawater was investigated by aseptic incubation of solutions at 20–22°C under illumination from cool-white light of intensity 6 kerg cm⁻² sec⁻¹, and the chemical changes were spectrophotometrically monitored. All the pteridines showed markedly accelerated degradation from this illumination relative to their behaviour in total darkness.Pterin and lumazine were degraded very slowly with zero-order reaction kinetics, while the other pteridines photolysed rapidly (according to first-order kinetics) with decomposition rates increasing in the order dioxylumazine (2,4,6,7-tetrahydroxypteridine) < leucopterin < isoxanthopterin < xanthopterin < oxylumazine (2,4,6-trihydroxypteridine). Excepting leucopterin and dioxylumazine, the photolysis rates were attributable to the pH of seawater and not its salt content; this was also the case with oxylumazine which required the salt content of seawater for decomposition in darkness. Leucopterin and dioxylumazine (both 6,7-dihydroxylated pteridines) gave evidence of complexation with the major divalent cations (Ca²⁺, Mg²⁺) of seawater, by virtue of which their photolytic degradation rates were enhanced to magnitudes obtained in pH-10 buffer without seawater. It is proposed that such complexation produces structural forms of these pteridines analogous to their normal ionic forms at pH 10–12.The photolysis of the 6-hydroxylated pteridines (xanthopterin, oxylumazine) proceeded via intermediate formation of their corresponding 7-hydroxylated derivatives (leucopterin, dioxylumazine).  相似文献   

Atlas of Japan (East) Sea hydrographic properties in summer, 1999     

Lynne D. Talley  Pavel Tishchenko  Vladimir Luchin  Alexander Nedashkovskiy  Sergey Sagalaev  Dong-Jin Kang  Mark Warner  Dong-Ha Min 《Progress in Oceanography》2004,61(2-4):277

Hydrographic properties from CTD and discrete bottle sample profiles covering the Japan (East) Sea in summer, 1999, are presented in vertical sections, maps at standard depths, maps on isopycnal surfaces, and as property–property distributions. This data set covers most of the Sea with the exception of the western boundary region and northern Tatar Strait, and includes nutrients, pH, alkalinity, and chlorofluorocarbons, as well as the usual temperature, salinity, and oxygen observations.  相似文献   

1998年长江巨洪与厄尔尼诺事件     

冯利华  张强 《海洋学研究》2001,19(4):13-16

1997～ 1 998年出现了 2 0世纪中最强的一次厄尔尼诺事件。根据长江洪水与厄尔尼诺事件的实测资料 ,指出 1 998年的长江巨洪与这次厄尔尼诺事件具有较密切的关系。同时讨论了厄尔尼诺事件影响长江洪水的物理途径 ,这对长江巨洪的长期及超长期预报具有较重要的指示作用  相似文献   

半封闭海湾潮间带部分围垦后纳潮量计算的商榷——以胶州湾为例   总被引：14，自引：1，他引：14  

杨世伦  陈启明  朱骏  张经 《海洋科学》2003,27(8):43-47

传统的海湾(泻湖)纳潮量计算方法不能精确地反映潮间带被部分围垦后纳潮量的实际情况,本考虑围堤的影响,将纳潮量分解为堤基以下的“梯形”区和堤基以上的“矩形”区两部分之和,在理论上更加严密。根据改进后方法算出的胶州湾近期纳潮量比传统方法算出的纳潮量大15％左右。可见,半个多世纪以来胶州湾的纳潮量只减少了约15％．而不是传统方法得出的约25％。  相似文献   

Composition and Useful Properties of Tailings of Marine Manganese Nodules and Crusts     

Zhimin Bai  John C. Wiltshire 《Marine Georesources & Geotechnology》2005,23(1):13-24

Marine manganese nodules and crusts, when processed, yield tailings which may be utilized for environmental and economic benefit. The key to the reasonable and effective utilization of these tailings lies in making a systematic appraisal of their composition and properties. This article gives an introduction to the investigation of manganese tailings properties. The tailings have a high iron and/or manganese content, high surface area, high porosity, and fine grain size. Some tailings have a high rare earth element content which is valuable. They may also have high SO₃, arsenic, and uranium contents which are harmful. Depending on the process used to produce the tailings, there will likely be some differences in chemical composition, mineral assemblages, surface area and adsorption capability, pore diameter and volume, density and pH. In assigning potentially beneficial applications for these tailings, these differences should be taken into account to optimize utilization.  相似文献   

Environmental characteristics of the Mandovi-Zuari estuarine system in Goa   总被引：1，自引：0，他引：1  

S.Z. Qasim  R. Sen Gupta 《Estuarine, Coastal and Shelf Science》1981,13(5):557-578

  相似文献   

Coastal geomorphic evolution at the Denglou Cape, the Leizhou Peninsula     

Wang Lirong  Zhao Huanting  Song Chaojing  Yuan Jiayi  Yu Hongbing 《海洋学报(英文版)》2002,21(4):597-611

ＩＮＴＲＯＤＵＣＴＩＯＮＴｈｅＤｅｎｇｌｏｕＣａｐｅ ,ｉｎｔｈｅｓｏｕｔｈｗｅｓｔｏｆｔｈｅＬｅｉｚｈｏｕＰｅｎｉｎｓｕｌａ ,ｉｓａｔｔｈｅｎｏｒｔｈｍａｒｇｉｎｏｆｔｒｏｐｉｃａｌｚｏｎｅ .ＳｅｖｅｒａｌｒｅｓｅａｒｃｈｅｓａｎｄｃａｒｔｏｇｒａｐｈｉｅｓｏｆｔｈｅｒｅｇｉｏｎａｌｇｅｏｍｏｒｐｈｏｌｏｇｙａｎｄＱｕａｔｅｒ ｎａｒｙｇｅｏｌｏｇｙ ,ｗｈｉｃｈｗｅｒｅｃａｒｒｉｅｄｏｕｔｉｎｔｈｅｐａｓｔ,ａｌｌｉｎｃｌｕｄｅｔｈｉｓａｒｅａ (ＭＧＬ ,ＳＣＳＩＯ ,ＣＡＳ ,1 978;ＧＰＣＳＧＲＣＺＴ…  相似文献   

烟台套子湾八角深水港的开发研究     

戚立心  王全东 《海岸工程》1996,15(4):9-19

通过调查和比较，认为在我国渤海和北黄海南岸的套子湾八角海区是一个条件优越的深水港址，在阐述开发八角深水港的重要意义同时，根据城市布局规划和岸线及水域资源，参照国际港口未来发展趋势，结合我国对中、西部地区经济发展战略，对八角深水港的开发和布局进行了研究，为烟台市发展成为“现代化、国际型港口城市”，提出了港区未来建设的模式。  相似文献   

海洋植物营养素的应用研究　Ⅰ.金藻类的培养     

龙丽娟  孙恢礼  何伟宏 《热带海洋学报》1998,(1)

用不同含量的93－B型海洋植物营养素对几种常用的金藻类饵料种进行培养对比试验。结果表明,海洋植物营养素用于培养金藻类效果良好,最适使用含量为30mp·L~-1域40mg·L~-1。此时效果与通常被推荐的培养液所培养的对照组相当或更好．含量过高,则造成某些营养盐过量而产生一定的毒害作用。此营养素使用简便。  相似文献   

中太平洋CP25岩心的矿物、稀土元素及Sr、Nd同位素组成--晚新生代海底火山活动的证据   总被引：3，自引：0，他引：3  

刘季花  崔汝勇  卢效珍  陈丽蓉 《海洋地质与第四纪地质》1999,19(2):5

中太平洋ＣＰ２５岩心沉积物中钙十字沸石、蒙脱石／伊利石比值（Ｍ／Ｉ）、稀土元素含量、铈异常（δＣｅ）、铕异常（δＥｕ）及Ｓｒ、Ｎｄ同位素特征作为海底火山活动的证据,揭示了中太平洋海盆晚新生代以来火山活动和沉积的历史。其结果是,早中新世约２０～１７ＭａＢ．Ｐ．间,火山活动逐渐强烈,在１７ＭａＢ．Ｐ．最强烈,使得沉积物具有高Ｍ／Ｉ和∈Ｎｄ、低δＣｅ和８７Ｓｒ／８６Ｓｒ。１７～１ＭａＢ．Ｐ．发生沉积间断。１ＭａＢ．Ｐ．至现代,火山活动较早中新世减弱  相似文献