圆盘固相萃取富集-气相色谱法测定地表水中有机氯和有机磷农药   总被引：4，自引：2，他引：2  

何淼  饶竹 《岩矿测试》2008,27(1):12-16

采用环境友好的圆盘固相萃取新技术富集水体中有机氯农药和有机磷农药,分别用微池电子捕获检测器(μECD)和火焰光度检测器(FPD)气相色谱法检测,实现了水中有机氯和有机磷农药残留物的测定。结果表明,16种有机氯农药的平均回收率为64.7%~102%,精密度(RSD,n=6)为2.9%~15%;13种有机磷农药的平均回收率为65.9%~104%,精密度(RSD,n=6)为1.7%~17%。方法快速、灵敏、低污染,可用于水体中多种有机氯农药和有机磷农药的残留分析。  相似文献   

X射线衍射数据分析系统评价   总被引：4，自引：1，他引：3  

李建欣  宋党育  张军营  郑楚光 《岩矿测试》2008,27(3):189-193

以贵州省高灰、高污染组分煤中矿物质的分析为例,应用Bruker AXS D8 Advance衍射仪测得煤中矿物相的X射线衍射图谱,分别应用数据分析系统EVA 12.0、X’Pert HighScore 2.0和MDI Jade 5.0对矿物物相组成的原始测试数据进行定性分析,通过对比分析过程和结果的差异比较了三款软件系统之间的异同和优劣。  相似文献   

用随机介质模型方法描述孔洞型油气储层   总被引：5，自引：0，他引：5  

朱生旺  魏修成  曲寿利  刘春园  吴开龙 《地质学报》2008,82(3):420-427

孔洞型储集层具有强烈的非均质性,在空间分布上变化剧烈,规律性差,其地球物理参数(如速度、密度、弹性参数等)在空间上的变化很难用传统的层状介质模型进行刻画.本文借助随机模型方法,研究孔洞型储层中不同孔洞尺度、分布密度与模型参数的关系,建立反映实际孔洞油气储层介质地球物理参数空间分布统计特征的随机介质模型,以更方便地对孔洞型油气储层进行描述,并为碳酸盐岩孔洞型储层地震反射特征的研究提供有效的方法途径.  相似文献   

Neural network prediction of nitrate in groundwater of Harran Plain, Turkey   总被引：2，自引：0，他引：2  

M. Irfan Yesilnacar  Erkan Sahinkaya  Muhsin Naz  Bestamin Ozkaya 《Environmental Geology》2008,56(1):19-25

Monitoring groundwater quality by cost-effective techniques is important as the aquifers are vulnerable to contamination from the uncontrolled discharge of sewage, agricultural and industrial activities. Faulty planning and mismanagement of irrigation schemes are the principle reasons of groundwater quality deterioration. This study presents an artificial neural network (ANN) model predicting concentration of nitrate, the most common pollutant in shallow aquifers, in groundwater of Harran Plain. The samples from 24 observation wells were monthly analysed for 1 year. Nitrate was found in almost all groundwater samples to be significantly above the maximum allowable concentration of 50 mg/L, probably due to the excessive use of artificial fertilizers in intensive agricultural activities. Easily measurable parameters such as temperature, electrical conductivity, groundwater level and pH were used as input parameters in the ANN-based nitrate prediction. The best back-propagation (BP) algorithm and neuron numbers were determined for optimization of the model architecture. The Levenberg–Marquardt algorithm was selected as the best of 12 BP algorithms and optimal neuron number was determined as 25. The model tracked the experimental data very closely (R = 0.93). Hence, it is possible to manage groundwater resources in a more cost-effective and easier way with the proposed model application.  相似文献   

Depths of Partial Crystallization of H2O-bearing MORB: Phase Equilibria Simulations of Basalts at the MAR near Ascension Island (7 11{degrees}S)     

Almeev  Renat; Holtz  Francois; Koepke  Jurgen; Haase  Karsten; Devey  Colin 《Journal of Petrology》2008,49(1):25-45

Phase equilibria simulations were performed on naturally quenchedbasaltic glasses to determine crystallization conditions priorto eruption of magmas at the Mid-Atlantic Ridge (MAR) east ofAscension Island (7–11°S). The results indicate thatmid-ocean ridge basalt (MORB) magmas beneath different segmentsof the MAR have crystallized over a wide range of pressures(100–900 MPa). However, each segment seems to have a specificcrystallization history. Nearly isobaric crystallization conditions(100–300 MPa) were obtained for the geochemically enrichedMORB magmas of the central segments, whereas normal (N)-MORBmagmas of the bounding segments are characterized by polybariccrystallization conditions (200–900 MPa). In addition,our results demonstrate close to anhydrous crystallization conditionsof N-MORBs, whereas geochemically enriched MORBs were successfullymodeled in the presence of 0·4–1 wt% H₂O in theparental melts. These estimates are in agreement with direct(Fourier transform IR) measurements of H₂O abundances in basalticglasses and melt inclusions for selected samples. Water contentsdetermined in the parental melts are in the range 0·04–0·09and 0·30–0·55 wt% H₂O for depleted and enrichedMORBs, respectively. Our results are in general agreement (within±200 MPa) with previous approaches used to evaluate pressureestimates in MORB. However, the determination of pre-eruptiveconditions of MORBs, including temperature and water contentin addition to pressure, requires the improvement of magma crystallizationmodels to simulate liquid lines of descent in the presence ofsmall amounts of water. KEY WORDS: MORB; Mid-Atlantic Ridge; depth of crystallization; water abundances; phase equilibria calculations; cotectic crystallization; pressure estimates; polybaric fractionation  相似文献   

引水工程秦巴段隧洞地应力模拟及工程地质问题     

李东林  吴树仁  韩金良  刘景儒 《地质与勘探》2008,44(5):81-86

利用Ansys有限元软件对三峡引水工程秦巴段线路不同深度、不同截面形态隧洞围岩的应力重分布情况进行模拟计算,得到圆形隧洞、城门形隧洞和马蹄形隧洞围岩的应力数值和等值线图.利用库仑一纳维尔强度准则,对花岗岩区及灰岩区隧洞围岩的剪切破坏进行分析;利用三种岩爆应力判别指标,对岩爆进行初步预测;进而对不同深度、不同截面形态的隧洞围岩的稳定性进行分析;最后对引水工程隧洞设计中截面形态的选择给出了初步建议.  相似文献   

相山铀矿田变质基底的变质作用期次   总被引：1，自引：0，他引：1  

蒋振频  吴雅梅  董永杰  胡荣泉  吴水林 《铀矿地质》2008,24(1):32-37

相山铀矿田的变质基底,自晋宁期以来经历了长期而复杂的变质变形演化历史,至中生代为止,共经历了4个期次变质作用的叠加改造:中元古代区域热动力变质作用,中元古代后的热接触变质作用,中生代动力变质作用,中生代晚期的热接触变质作用.多期次变质作用的叠加改造,反映了本区自元古宙以来一直是一处地热异常区.相山地区铀成矿期的成矿作用,是一系列构造-岩浆-变质作用叠加的结果.  相似文献   

Response of the barrier island coastal region of southwestern Nigeria to climate and non-climate forcing     

IB Danladi  M Gül  E Ateş 《African Journal of Marine Science》2020,42(1):43-51

Despite threats emanating from the influence of climate and non-climate forcing on the barrier island coastal region of southwestern Nigeria, the extent of the coastal erosion is poorly understood. We report evidence of coastal erosion and sediment accumulation in the region over a 34-year period (1973–2017), using Landsat imagery at intervals of approximately six years. Landsat image corrections and various water-extraction algorithms were used to systematically delineate coastal erosion and accumulation in the area. The region was subdivided into western and eastern subregions separated by Lagos Harbour. In the west, erosion took place during the periods 1973–1979, 1979–1984, 1990–1999 and 2005–2011, whereas in the east, erosion occurred during 1973–1979, 1990–1999 and 1999–2005. Coastal sediment accumulation occurred in the east during 1979–1984, 1984–1990, 2005–2011 and 2011–2017, whereas gains in the west occurred during 1984–1990, 1999–2005 and 2011–2017. The study revealed substantial net erosion of 1 228.1 ha in the region as a whole, over the full period. Sediment accumulation accompanying the coastal erosion appears to be linked to longshore drift. Erosion between 1973 and 2011 was probably attributable to climate change (storms and tidal conditions), longshore drift, the inflow and outflow of water at Lagos Harbour, coastal morphology and, possibly, human impacts. However, the coastal changes between 2011 and 2017 were more obviously associated with human activities, such as development of the Eko Atlantic construction project. Coastal surveillance, together with the use of environmentally sensitive protective measures, could possibly help to reduce coastal erosion in the region. Careful coastal management practices, including artificial nourishing and the installation of resilient structures (e.g. seawalls), should be undertaken to protect human settlements that are already at risk from sea-level rise.  相似文献   

水下工程项目监理的任务与条件     

张国光 《海洋工程》2002,20(3):76-80

结合近年来参与有关水下工程检测和项目监理的实践体验 ,从总结水下工程项目的基本特征着手 ,分析了水下工程项目监理的主要任务 ,并结合对于实施水下工程项目监理必备装备条件的探讨 ,介绍了国内外现有水下监测技术装备的开发应用状况  相似文献   

Estimation of Sea Ice Thickness from SARAL/AltiKa in Drifting Orbit Phase     

Purvee Joshi  Sandip R. Oza  Ujjwal K. Gupta  Shailendra Saini  D. Ram Rajak  I. M. Bahuguna 《Marine Geodesy》2020,43(3):302-323

Abstract

Intra and inter-annual variations in the sea ice thickness are highly sensitive indicators of climatic variations undergoing in the earth’s atmosphere and oceans. This paper describes the method of estimating sea ice thickness using radar waveforms data acquired by SARAL/Altika mission during its drifting orbit phase from July 2016 onwards yielding spatially dense data coverage. Based on statistical analysis of return echoes, classification of the surface has been carried out in three different types, viz. floe, lead and mixed. Time delay correction methods were suitably selected and implemented to make corrections in altimetric range measurements and thereby freeboard. By assuming hydrostatic equilibrium, freeboard data were converted into sea ice thickness. Results show that sea ice thickness varies from 4 to 5?m near ice shelves and 1 to 2.5?m in the marginal sea ice regions. Freeboard and sea ice thickness estimates were also validated using NASA’s Operation Ice Bridge (OIB) datasets. Freeboard measurements show very high correlation (0.97) having RMSE of 0.13. Overestimation of approximately 1–2?m observed in the sea ice thickness, which could be attributed to distance between AltiKa footprint and OIB locations. Moreover, sensitivity analysis shows that snow depth and snow density over sea ice play crucial role in the estimation of sea ice thickness.  相似文献