Sorption of Eu~(3+) onto nano-size silica-water interfaces     

HU Ping    YIN Xiulan  ZHAO Linghu & LI Dien . Department of Earth Sciences  China University of Geosciences  Wuhan  China  . Northeastern Illinois University  Chicago  IL  USA  . China Institute of Geo-Environmental Monitoring  Beijing  China  . Division of Chemistry  Los Alamos National Laboratory  Los Alamos  NM  USA 《中国科学D辑(英文版)》2005,48(11)

A large amount of nuclear wastes has been pro-duced due to nuclear weapon development and nuclear electricity generation. One possible resolution for the disposal of the nuclear wastes is to seal them in an underground repository, which requires detailed knowledge on the mobility, chemical behavior and immobilization of radionuclides in underground water. In addition, toxic heavy metals are extensively present in ground and underground water, how to immobilize and remedy these toxic heavy meta…  相似文献   

Temperature and pH Dependence of Some Metals Leaching from Fly Ash of Municipal Solid Waste     

Lallan Prasad Gupta    Hodaka Kawahata    Mio Takeuchi  Hidekazu Ohta  Yoshiro Ono 《Resource Geology》2005,55(4):357-372

Abstract. Municipal solid waste combustion leads to concentration of various metals in the solid residue (fly ash) remaining after combustion. These metals pose serious environmental hazard and require proper handling and monitoring in order to control their harmful effects. Leachability of some metals from fly ash was examined in fly ash and Milli-Q water mixture (liquid-to-solid ratio, 100) under various temperature and pH conditions in the laboratory. The leaching experiments conducted for 24 hours showed that pH was generally more important than temperature in controlling the amount of metals leached out of the fly ash. However, at a given pH, rise in temperature led to different degree of (usually one to two fold) enhanced or reduced leaching of metals. Owing to amphoteric nature of oxides of Al, Cr, Pb and Zn, these metals often yielded typical pattern of increase and decrease in their concentrations with change in pH. The extent of leaching of Cr and Pb in our experiments suggests that decrease of pH to acidic range in the case of Pb and to neutral to acidic range for Cr over a long period of storage of fly ash at solid waste dumping site may facilitate leaching of these metals from fly ash, leading to contamination of groundwater to the level that exceeds beyond the level permitted by the environmental laws.  相似文献   

Mathematical model for hydraulically aided electrokinetic remediation of aquifer and removal of nonanionic copper     

Sadataka Shiba  Yushi Hirata  Tadachika Seno   《Engineering Geology》2005,77(3-4):305-315

One of the most cost-effective in situ technologies for soil and groundwater (i.e., aquifer) remediation is electrokinetic remediation. In electrokinetic remediation, electromigration due to electric field is combined with hydromigration due to hydraulic flow by purge water to remove pollutants from aquifers through the pore water. This study aims at investigating theoretically the role of electromigration (as active movement) of pollutants and the role of hydromigration (as passive movement) of pollutants in electrokinetic remediation, and making it clear that the control variables for electrokinetic remediation are the applied voltage and the hydraulic flow rate. These aims are pursued by construction of a mathematical model based on physico-chemical considerations and by model simulations of the electrokinetic remediation applied to the virtual aquifer polluted by heavy metals of copper sulfate. According to numerical simulations with the model: (1) heavy metal (nonanionic copper) is removed from the upstream anode region and accumulated in the downstream cathode region; (2) to carry away the heavy metal outside the aquifer (global removal), hydromigration by purge water flow is essential; and (3) electromigration contributes mainly to the redistribution of heavy metals within the aquifer (local removal and local accumulation).  相似文献   

Correlation between magnetic susceptibility and heavy metals in urban topsoil: a case study from the city of Xuzhou, China   总被引：7，自引：0，他引：7  

Xue Song WANG  Yong QIN 《Environmental Geology》2005,49(1):10-18

Anthropogenic influence, mainly due to urban and industrial activities and traffic exhaust, may affect urban topsoil via atmospheric contamination and solid waste. Magnetic susceptibility measurements were conducted on 21 urban topsoil samples from the city of Xuzhou, China. High intensities of magnetic susceptibility were detected in the majority of the samples. SEM analysis shows that magnetic minerals are in the form of spherules and mainly due to anthropogenic inputs. The heavy metals Pb, Cu, Zn, Se, Sc, Mo, Fe, and Bi show strong correlations with magnetic susceptibility, and Ag, Ba, Cd, Ni, Cr, Sb, and Sn, on the other hand, show a weak correlation with magnetic susceptibility. Whereas, of these metals studied, only Hg has no significant correlation with the susceptibility. The Tomlinson pollution load index (PLI) also shows significant correlation with the susceptibility (χ). The present study shows that magnetic susceptibility is a fast, inexpensive, and non-destructive method for the detection and mapping of contaminated soils.  相似文献   

Environmental pollution impact on water and sediments of Kumaun lakes, Lesser Himalaya, India: a comparative study     

Brijraj K. Das 《Environmental Geology》2005,49(2):230-239

A study of the water and sediment chemistry of the Nainital, Bhimtal, Naukuchiyatal and Sattal Lakes of Kumaun, has shown that the water of these lakes are alkaline and that electrical conductivity, total dissolved solid and bicarbonate HCO ₃ ⁻ are much higher in Nainital than in the other three lakes. The weathering of limestone lithology and anthropogenic pollution, the latter due to the very high density of population in the Nainital valley, are the primary sources of enhanced parameters. The low pH of Nainital Lake water is due to low photosynthesis and enhanced respiration, increasing CO₂ in the water and the consequent enhancement of Ca²⁺ and HCO ₃ ⁻ . The dissolved oxygen in Nainital Lake is less compared to other lakes, indicating anoxic conditions developing at the mud–water interface at depth. The PO ₄ ³⁻ content in Nainital is higher (124 μg/l), showing an increasing trend over time leading to eutrophic conditions. The trace metals (Cu, Co, Zn, Ni, Mn, and Sr) are present in greater amounts in the water of Nainital Lake than in the other three lakes, though Fe and Cr are high in Bhimtal and Fe in Naukuchiyatal. The higher abundance is derived from the leaching of Fe–Mg from metavolcanic and metabasic rocks. Most of the heavy metals (Cr, Ni, Cu, Mn, Fe, Sr, and Zn) significantly enrich the suspended sediments of the lakes compared to the bed sediments which due to their adsorption on finer particles and owing to multiple hydroxide coating and organic content, except for Fe, which is enriched in the bed sediments. The high rate of sedimentation, 11.5 mm/year in Nainital, compared to Bhimtal with 4.70 mm/year, Naukuchiyatal with 3.72 mm/year, and Sattal with 2.99 mm/year, has resulted in shorter residence time, poor sorting of grains, and lesser adsorption of heavy metals, leading consequently, their depletion in the bed sediments of Nainital Lake.  相似文献   

Water pollution in gold mining industry: a case study in Roşia Montană district, Romania     

R. M. Florea  A. I. Stoica  G. E. Baiulescu  P. Capotă 《Environmental Geology》2005,48(8):1132-1136

The preliminary study of streams and rivers from the Roşia Montană area revealed that the concntration of heavy metals— Cd, Mn, Cu, Pb, and Zn—are above accepted limits. The gold extraction method is based on flotation. The most important pollution sources are mine tailings. The determinations were performed for samples collected in: April 2004, July 2004, September 2004, November 2004, February 2005 and May 2005. The highest concentrations were found for cadmium in September 2004: 0.17 mg/L; for copper in September 2004: 1.38 mg/L; for manganese in July 2004: 239.4 mg/L; for lead in May 2005: 0.54 mg/L; and for zinc in September 2004: 35.37 mg/L;. This study involved three small rivers (streams) that flow into the Mureş River and finally into the Danube River, having a great impact on human health and environmental stability in the area. In May 2005, a sample of drinking water from the mining district was also collected.  相似文献   

Present environment and historic changes from the record of lake sediments, Dhaka City, Bangladesh   总被引：1，自引：0，他引：1  

Faruque Ahmed  M. Hawa Bibi  M. Hussain Monsur  Hiroaki Ishiga 《Environmental Geology》2005,48(1):25-36

Changes in the urban environment of Dhaka City have been evaluated from the geochemical compositions of bottom sediments from two lakes, Gulshan-1 and –2. Abundances of Pb, Zn, Fe₂O₃ and total sulfur in a Gulshan-1 core gradually increase toward the sediment–water interface. Three stages of condition change can be recognized in Gulshan-1, based on trace metal concentration patterns. The basal Stage I corresponds to background Dhaka sedimentation, whereas gradual increase in Stage II represents the beginning of pollution. Marked increases in Pb and Zn in Stage III reflect rapid urban development and increased emissions to the atmosphere. The condition of the Dhaka environment is compared to that of Japan based on Zn–Fe₂O₃ and Pb–Fe₂O₃ relations. Zn–Fe₂O₃ ratios in Stage I Dhaka sediments are similar to normal Japanese sediments, whereas Stage II data lie on the same trend as Japan urban sediments. Dhaka Stage III samples have greater Zn:Fe₂O₃ ratios than Japanese urban sediments, suggesting Zn pollution from poorly-controlled industrial sources. In contrast, the Dhaka Pb–Fe₂O₃ trend lies between normal and urban Japanese sediments. Although vehicle emissions in Dhaka are now significant, the data suggest that Pb pollution from this source remains in its early stages.  相似文献   

Quantitative assessment on the influence of heavy rainfall on the crystalline schist landslide by monitoring system -case study on Zentoku landslide, Japan   总被引：2，自引：1，他引：2  

Yong Hong  Hiromasa Hiura  Kazuo Shino  Kyoji Sassa  Hiroshi Fukuoka 《Landslides》2005,2(1):31-41

On Shikoku Island, which is one of the four main islands of Japan, a large number of large-scale crystalline schist landslides have been revealed and are being monitored by an observation system. Seasonal heavy rainfall is the most active meteorological factor that can threaten the stability of this kind of site-specific landslide. In this paper, on the basis of the study of the rainfall-related behavior of a typical crystalline schist landslide, the Zentoku landslide, by analyzing the precisely and continuously observed piezometric and movement data, a method was developed to quantitatively assess the effect of heavy rainfall on a large-scale landslide. The results indicated that heavy rainfall-induced landslide displacement shows good correlation with the variation of groundwater levels. Variations of groundwater level have been simulated with the use of a tank model. The simulation using this model permits the change in water levels for future rainfall events to be predicted. By combining the predicted results with the empirical relation between displacements and water levels, rainfall-induced landslide movement during extreme rainfall events can be estimated in advance. The effect of heavy rainfall on sliding behavior can be quantified in terms of the change in displacement. Thus warning information or advisories for the local residents can be provided.  相似文献   

Chemical effects of a near-to-nature detention pond on a small urban headwater     

《Limnologica》2017

The near-to-nature approach has been established as best practice for stormwater management. However, pollutant mobility within such systems and its impact on small receiving waters are partly unexplained. The study takes place in an urbanised headwater catchment in south-western Germany with an area of 0.4 km². Runoff from roofs, roads, parking lots and gardens is collected in wells or trenches and stored in private and public dry detention basins. Accordingly, this study investigates pollutant input to a detention pond, removal efficiency and the associated effects on the receiving water.Grab samples with high temporal resolution of the receiving water (16 flood events with 315 samples and 41 baseflow samples), the three inflows of the detention basin and its outflow (four flood events with 64 samples) were taken. The outflow of the dry pond is recovered in the hydro- and chemographs of the receiving water. Runoff from roads with increased traffic volume caused the highest PAH inputs and runoff from the residential area showed the highest zinc concentrations, which partly infringe European Environmental Quality Standards. Yearly pollutant inputs (DOC, TSS, PAH, nutrients, metals) from the settlement into the tributary are reduced in the detention pond by up to 80%.  相似文献   

江苏暴雨概率预报及其业务应用   总被引：1，自引：0，他引：1  

陈圣劼  孙燕  刘安宁  罗兵 《气象科学》2016,36(2):269-274

以未来12~36 h、36~60 h和60~84 h的暴雨预报为目标,利用2011年—2013年夏季6—8月欧洲细网格数值模式预报产品分析了江苏夏季暴雨的可能预报因子。通过对各因子进行相关性、敏感性和代表性分析后,优选了22个对不同强度降水具有较好区分能力的暴雨预报因子。以这些因子为基础建立了一种简单的江苏省暴雨概率预报方法。其预报产品已在江苏省气象业务一体化平台上投入业务使用。该方法在2011—2013年7月,针对提前12 h预报的历史回报试验中,TS技巧评分平均为13.6,明显高于EC细网格24 h降水预报产品(平均TS评分仅为4.5)。在2014年梅汛期的6月25—26日、7月1—2日和7月4—5日三次区域性暴雨个例的预报试验中,提前60、36、12 h的预报效果均较好,其平均TS评分(44.6)也明显高于欧洲细网格数值模式的降水预报(20.4)。  相似文献