青藏高原影响亚洲夏季气候研究的最新进展   总被引：40，自引：6，他引：40  

吴国雄  毛江玉  段安民  张琼 《气象学报》2004,62(5):528-540

文中回顾了近 10a来吴国雄等在青藏高原影响亚洲夏季气候研究方面的最新进展。通过分析东西风交界面的演变证明 ,由于青藏高原的春季加热 ,亚洲季风区对流层低层冬季盛行偏东风转变为夏季偏西南风最早发生在孟加拉湾东部 ,与其相伴随的激烈对流降水出现在其东面。因此孟加拉湾东部至中印半岛西部是亚洲季风最早爆发的地区。同时也指出盛夏伊朗高原和青藏高原加热所激发的同相环流嵌套在欧亚大陆尺度的热力环流中 ,从而加强了东亚的夏季风 ,加剧了中西亚的干旱 ;并通过其所激发的波动对夏季东亚的气候格局产生重要影响。文中还比较了夏季南亚高压的伊朗模态和青藏模态性质的异同及其对亚洲夏季降水异常分布的不同影响。  相似文献   

能量色散X射线荧光光谱法测定卤水中痕量溴铷砷   总被引：3，自引：4，他引：3  

樊兴涛  詹秀春  巩爱华 《岩矿测试》2004,23(1):15-18

用模拟卤水建立了能量色散X射线荧光光谱法测定卤水中溴、铷、砷痕量元素含量的方法.实验表明,方法可以直接取样测定,适用于大批量样品的测试分析.方法的精密度RSD(n＝15)小于1%,加标回收率为86.8%～101.6%.卤水中溴、铷、砷的测定结果与比色法、原子吸收和原子荧光法结果相符.  相似文献   

喜马拉雅中段高压麻粒岩变质作用、地球化学与年代学   总被引：2，自引：7，他引：2  

季建清  钟大赉宋彪朱美妃  温大任 《岩石学报》2004,20(5):1283-1300

研究的高压麻粒岩发现于西藏亚东以北约40公里的(Zherger-La)、出露在藏南拆离系(STDS)主构造面下盘的高喜马拉雅结晶岩系中,是继喜马拉雅东西构造结的Nanga Barbat、Namjag Barwa和喜马拉雅中段Khatra & Marina地区、定结地区发现的榴辉岩或高压麻粒岩之后,在青藏高原上新近发现的高压麻粒岩.该麻粒岩呈岩片被包裹于花岗质片麻岩中.麻粒岩记录了两期变质作用,早期矿物组合为Grt+Cpx+Pl+Qz,属麻粒岩相变质产物,矿物成分分析显示早期矿物组合达到了平衡,并且没有表现成分扩散;后期矿物组合为Hbl+Pl+Bio或Opx+Pl,指示了较高温但相对压力较低的麻粒岩相退变变质作用,矿物成分分析和结构显示了退变作用没有达到变质平衡.显微结构可以观察到多组变质反应Grt+Cpx+Qtz=Opx+Pl,Grt+Qtz=Opx+Pl,Grt+Cpx+L=Hbl+Pl+Bio+Mt,和Cpx+L=Hbl+Mt.根据矿物平衡关系,利用Grt-Cpx温度计和Grt-Cpx-Pl-Qz压力计估算的早期变质作用温压为T=780～850℃,P=12～15kbar,相对应的地温梯度16℃～18℃/km.借用Hbl-Pl温度计和A1tot in Hbl压力计估算的晚期变质作用温压为T=730～760℃;P=4～6kbar,相当的地温梯度为38℃～50℃/km.变质作用P-T演化呈等温降压轨迹,指示麻粒岩地体从增厚(或俯冲)地壳到减薄增温(或部分熔融)地壳,进而被快速剥露地表的构造过程.初步的地球化学结果表明高压麻粒岩原岩可能相当于大陆拉斑玄武岩.麻粒岩锆石SHRIMP年代学有两组相对集中的年龄分别为98±5 Ma(5 spots)和17.0±0.3 Ma(13 spots).高压麻粒岩的两期变质作用的温度都在700℃以上,略高于锆石U-Pb同位素体系计时封闭温度,推断17 Ma是高压麻粒岩变质后发生折返,随高喜马拉雅结晶岩系剥露冷却的年龄;98.4Ma的测年结果被推测是高压麻粒岩原岩形成的年龄.在喜马拉雅山,高压麻粒岩记录了类似增厚地壳到减薄地壳的转变一方面可能是地壳深部作用机制的转变,另一方面,这种机制与喜马拉雅南坡巨大的降雨量和去顶作用有密切关系,意义重大.  相似文献   

A Reflection on Mg, Cd, Ca, Li and Si Isotopic Measurements and Related Reference Materials   总被引：6，自引：1，他引：6  

Jean Carignan  Damien Cardinal  Anton Eisenhauer  Albert Galy  Mark Rehkamper  Frank Wombacher  Nathalie Vigier 《Geostandards and Geoanalytical Research》2004,28(1):139-148

This contribution aims to report the reflections we had with the scientific community during two international workshops on reference materials for stable isotopes in Davos (2002) and Nice (2003). After evaluating the isotopic homogeneity of some existing reference materials, based on either certificates, literature data or specific inter-laboratory rounds, we confirm these as primary reference materials or propose new ones relative to which stable isotope compositions should be reported. We propose DSM-3 for Mg, NIST SRM 915a for Ca, L-SVEC for Li and NBS28 for Si. Cadmium does not yet have a well identified delta zero material, although three commercial mono-elemental Cd solutions have yielded the same isotopic composition relative to one another. In order to scale the linearity of any mass spectrometer, some secondary reference materials are also proposed: Cambridge-1 solution for Mg, the "Münster-Cd" and JEPPIM Cd solutions for Cd and the "Big Batch" silicate for Si. The team from Nancy propose to prepare a mixed spike solution for Li isotopes. Well-characterised natural samples such as ocean or continental waters, diatoms, sponges, rocks and minerals are needed to validate the entire analytical procedure, particularly to take into account the effect of sample mineralisation and of chemical manipulations for elemental separation prior to analysis.  相似文献   

The magmatic–hydrothermal transition—evidence from quartz phenocryst textures and endoskarn abundance in Cu–Zn skarns at the Empire Mine, Idaho, USA     

Zhaoshan Chang  L.D. Meinert 《Chemical Geology》2004,210(1-4):149-171

Information about the magmatic to hydrothermal transition is preserved in late-stage features of quartz phenocrysts and endoskarn alteration in some Cu–Zn skarn deposits such as the Empire Mine in Idaho. Important features include: (1) quartz phenocrysts with strong resorption textures such as vermicular zones of igneous groundmass cutting primary quartz cathodoluminescence banding, (2) anomalous amounts of endoskarn (more than 50% of mineralized rock), (3) high F activities as evidenced by fluorite as an accessory mineral in igneous rocks, in alteration assemblages, and in fluid inclusions and by high F in hydroxyl sites in igneous biotite and amphibole, and (4) direct association of Zn, which normally is deposited distally at low temperature, with Cu in proximal locations and in endoskarn. These features are explained by the following model: (1) F lowers the solidus temperature of the magma, thus changing the timing, temperature, and duration of hydrothermal fluid exsolution. (2) Upon magmatic vapor saturation the F-rich hydrothermal fluids form bubbles that adhere to quartz phenocrysts and chemically corrode/tunnel into the quartz forming vermicular resorption textures. (3) F-rich hydrothermal fluids also promote the formation of endoskarn; silicic rocks are attacked by F-rich fluids in the same sense that carbonate wall rocks are dissolved by weakly to moderately acidic hydrothermal fluids. (4) Low fluid exsolution temperature facilitated by high F activity promotes high Zn/Cu ratios in proximal locations due to the solubility of Zn relative to Cu at lower temperatures. This model may be applicable at other localities such as the world-class Cu–Zn skarn Antamina mine, as well as some tin and rapakivi granites.  相似文献   

High-pressure experimental growth of diamond using C–K₂CO₃–KCl as an analogue for Cl-bearing carbonate fluid     

Emma Tomlinson  Adrian Jones  Judith Milledge 《Lithos》2004,77(1-4):287-294

High-pressure, high-temperature diamond growth experiments have been conducted in the system C–K₂CO₃–KCl at 1050–1420 °C, 7.0–7.7 GPa. KCl is of interest because of the strong effect of halogens on the phase relations of carbonate-rich systems [Geophys. Res. Lett. 30 (2003) 1022] and because of the occurrence of KCl coexisting with alkali silicate–carbonate fluids in natural-coated diamond [Geochim. Cosmochim. Acta 64 (2000) 717]. We have used system C–K₂CO₃–KCl as an analogue for these mantle fluids in diamond growth experiments. The presence of KCl reduces the potassium carbonate liquidus to ≤1000 °C at 7.7 GPa, allowing it to act as a solvent catalyst for diamond growth at temperatures below the continental geotherm. This is a reduction on the minimum diamond growth temperature reported in the alkali-carbonate–C–O–H system [Lithos 60 (2002) 145]. Diamond growth using carbonate solvent catalysts is characterised by a relatively long induction period. However, the addition of KCl also reduced the period for diamond growth in carbonate to 5 min; no such induction period appears to be necessary. It is suggested that KCl destabilises carbonate, allowing greater solubility and diffusion of carbon.  相似文献   

Experimental and theoretical study of stability of dense hydrous magnesium silicates in the deep upper mantle     

Tetsuya Komabayashi  Soichi Omori  Shigenori Maruyama 《Physics of the Earth and Planetary Interiors》2005,153(4):191-209

Fluid-undersaturated experiments were conducted to determine the phase relations in the simplified peridotite system MgO-SiO₂-H₂O (MSH) at 11.0-14.5 GPa and 800-1400 °C. Stability relations of dense hydrous magnesium silicates (DHMSs) under fluid-undersaturated conditions were experimentally examined. From the fluid-absent experimental results, we retrieved thermodynamic data for clinohumite, phase A, phase E, and hydrous wadsleyite, consistent with the published data set for dry mantle minerals. With this new data set, we have calculated phase equilibria in the MSH system including dehydration reactions. The dehydration reactions calculated with lower water activities of 0.68-0.60 match the fluid-present experiments of this study above 11.0 GPa and 1000 °C, indicating that considerable amounts of silicate component were dissolved into the fluid phase. The calculated phase equilibria illustrate the stability of the post-antigorite phase A-bearing assemblages. In the cold subducting slab peridotite, phase A + enstatite assemblage survives into the transition zone, whereas phase A + forsterite + enstatite assemblage forms hydrous wadsleyite at a much shallower depth of about 360-km. The slab is subducted with no dehydration reactions occurring when entering the transition zone. The phase equilibria also show the high temperature stability of phase E. Phase E is stable up to 1200 °C at 13.5 GPa, a plausible condition in the mantle of relatively low temperature, i.e., beneath subduction zones. Phase E is a possible water reservoir in the mantle as well as wadsleyite and ringwoodite.  相似文献   

Microthermometric measurement of fluid inclusions and its constraints on genesis of PGE-polymetallic deposits in Lower Cambrian black rock series, southern China   总被引：2，自引：0，他引：2  

WANG Min 《中国地球化学学报》2005,24(4):297-305

Systematic microthermometric measurements of fluid inclusions in the PGE-polymetallic deposits hosted in the Lower Cambrian black rock series in southern China were performed, and the results suggest: (1) there exist two types of fluid inclusions. TypeⅠis of NaCl-H2O system with low-medium salinity, and its homogenization temperatures (Th) and salinities are 106.9- 286.4℃ and ( 0.8- 21.8) wt%NaCl eq. respectively; TypeⅡ is of CaCl2-NaCl-H2O system with medium-high salinities, and its homogenization temperatures and salinities range from 120.1℃ to 269.6℃ and ( 11.4- 31.4) wt%NaCl eq., respectively. The typeⅡ fluid inclusions have been discovered for the first time in this kind of deposits; (2) two generations of ore-forming fluids were recognized. Characteristics of fluid inclusions in the PGE-polymetallic ores and carbonate-quartz stockworks in the underlying phosphorites are almost of no difference, they may represent ore-forming fluids at the main metallogenic stage. The peak value of homogenization temperature of those fluid inclusions is about 170℃, while their salinities possess a remarkable bimodal distribution pattern with two peak values of (27-31) wt%NaCl eq. and (4-6) wt%NaCl eq. On the contrary, fluid inclusions in the carbonate-quartz veins in the hanging wall may represent ore-forming fluids at the post-metallogenetic stage. The homogenization temperatures and the peak values of salinities are mostly 130-170℃ and (12-14) wt%NaCl eq., respectively; (3) nobel gas isotopic composition analyses in combination with the microthermometric measurements of fluid inclusions suggest that the ore-forming fluids at the main metallogenetic stage were probably derived from mixing of basinal hot brines with the CaCl2-NaCl-H2O system and seawater with the NaCl-H2O system; (4) in the Early Cambrian, the basinal hot brines were trapped in the Caledonian basins, which were distributed along the southern margin of the Yangtze Craton, and where giant thick sediments were accumulated, and expelled and migrated laterally along the strata because of the pressure caused by overlying sediments. The basinal hot brines absorbed Ni, Mo, V, PGE from the surrounding rocks and were transformed into ore-bearing hydrothermal fluids with the CaCl2-NaCl-H2O system and medium-high salinities, then ascended along faults and mixed with seawater of the NaCl-H2O system, and finally PGE-polymetallic deposits or occurrences were formed in the black rock series.  相似文献   

Primary Ore Mineral Assemblage and Fluid Inclusion Study of the Batu Hijau Porphyry Cu-Au Deposit, Sumbawa, Indonesia   总被引：3，自引：0，他引：3  

Akira Imai  Satoshi Ohno 《Resource Geology》2005,55(3):239-248

Abstract. The Batu Hijau porphyry Cu‐Au deposit, Sumbawa Island, Indonesia, is associated with a tonalitic intrusive complex. The temperature‐pressure condition of mineralization at the Batu Hijau deposit is discussed on the basis of fluid inclusion microthermometry. Then, the initial Cu‐Fe sulfide mineral assemblage is discussed. Bornite and chalcopyrite are major copper ore minerals associated with quartz veinlets. The quartz veinlets have been classified into ‘A’ veinlets associated with bornite, digenite, chalcocite and chalcopyrite, ‘B’ veinlets having chalcopyrite bornite along vuggy center‐line, rare ‘C’ chalcopyrite‐quartz veinlets, and late ‘D’ veinlets consisting of massive pyrite and quartz (Clode et al., 1999). Copper and gold mineralization is associated with abundant ‘A’ quartz veinlets. Abundant fluid inclusions are found in veinlet quartz consisting mainly of gas‐rich inclusions and polyphase inclusions throughout the veinlet types. The hydrothermal activity occurred in temperature‐pressure conditions of aqueous fluid immiscibility into hypersaline brine and dilute vapor. The halite dissolution (Tm[halite]) and liquid‐vapor homogenization (Th) temperatures of the polyphase inclusions in veinlet quartz range from 270 to 472d?C and from 280 to 454d?C, respectively. The estimated salinity ranges from 36 to 47 wt% (NaCl equiv.). The apparent pressures lower than 300 bars are estimated to have been along the liquid‐vapor‐halite curve for the fluid inclusions having the Th lower than the Tm that trapped the brine saturated with halite, or at slightly higher pressure relative to liquid‐vapor‐halite curve for the fluid inclusions having the Th higher than the Tm that trapped the brine unsaturated with halite. The actual temperature and pressure during the hydrothermal activity at the Batu Hijau deposit are estimated to have been around 300d?C and 50 bars. At such temperature‐pressure conditions, the principal and initial Cu‐Fe sulfide mineral assemblages are thought to be chalcopyrite + bornite solid solution (bnss) for the chalcopyrite‐bearing assemblage, and chalcocite‐digenite solid solution and bnss for the chalcopyrite‐free assemblage.  相似文献   

Intrusion and its implication for subsidence: A case from the Baiyun Sag, on the northern margin of the South China Sea   总被引：12，自引：0，他引：12  

Xiaobin Shi  Evgenii Burov  Sylvie Leroy  Xuelin Qiu  Bin Xia 《Tectonophysics》2005,407(1-2):117-134

We develop a series of simple numerical models to explain the anomalous subsidence and deposition phenomena on the northern continental margin of the South China Sea, in particular in the Baiyun Sag. The results suggest that a short-period high rate deposition of around 17 Ma is related to a rapid subsidence event, which may be due to episodic emplacement of a dense intrusion. Necking and gravity models indicate that in the basement of the Baiyun Sag, there is a dense zone that is 100–200 kg/m³ more dense than the surrounding country rock. Considering its high magnetic intensity and regional igneous activity, the dense zone is thought to be related to a phase of basalt intrusion that may have taken place around 17 Ma. Thermal and subsidence models indicate that a hot denser intrusion can cause significant subsidence immediately after the intrusion. The subsidence rate then slows down with cooling, thus becoming consistent with the observed subsidence curves at around 17 Ma. The results also indicate that the lithospheric strength under the Baiyun Sag is negligible, and that the high-velocity layer in the lowermost crust may be not an original part of the pre-rift crust. Instead, it is thought to be underplated intrusion emplaced at around 30 Ma when the continental margin broke up.  相似文献