Upwelling signals in radiocarbon from early 20th-century Peruvian bay scallop (Argopecten purpuratus) shells     

Kevin B. Jones  Gregory W.L. Hodgins  Miguel F. Etayo-Cadavid  C. Fred T. Andrus 《Quaternary Research》2009,72(3):452-456

We quantified Δ¹⁴C, δ¹⁸O, and δ¹³C cycles along ontogeny within four bay scallop (Argopecten purpuratus) shells collected from Callao Bay, Salaverry, and Sechura Bay, Peru following the 1907–1908 non-El Niño years and the 1925–1926 El Niño. Δ¹⁴C and δ¹³C generally covary; Δ¹⁴C and δ¹⁸O vary inversely. Simultaneous decreases in Δ¹⁴C and increases in δ¹⁸O in non-El Niño shells are followed by constant Δ¹⁴C and gradually decreasing δ¹⁸O, which we interpret as evidence for discrete marine upwelling events followed by warming of the initially cold upwelled water. Upwelling changes from El Niño events are detectable with difficulty in mollusk shell Δ¹⁴C.  相似文献   

Heating duration of igneous rim formation on a chondrule in the Northwest Africa 3118 CV3oxA carbonaceous chondrite inferred from micro-scale migration of the oxygen isotopes     

《Chemie der Erde / Geochemistry》2019,79(4):125524

Due to their common occurrence in various types of chondrites, igneous rims formed on pre-existing chondrules throughout chondrule-forming regions of the solar nebula. Although the peak temperatures are thought to reach similar values to those achieved during chondrule formation events, the heating duration in chondrule rim formation has not been well defined. We determined the two-dimensional chemical and oxygen isotopic distributions in an igneous rim of a chondrule within the Northwest Africa 3118 CV3_oxA chondrite with sub-micrometer resolution using secondary ion mass spectrometry and scanning electron microscopy. The igneous rim experienced aqueous alteration on the CV parent body. The aqueous alteration resulted in precipitation of the secondary FeO-rich olivine (Fa_40–49) and slightly disturbed the Fe-Mg distribution in the MgO-rich olivine phenocrysts (Fa_11–22) at about a 1 μm scale. However, no oxygen isotopic disturbances were observed at a scale greater than 100 nm. The MgO-rich olivine, a primary phase of igneous rim formation, has δ¹⁷O = −6 ± 3‰ and δ¹⁸O = −1 ± 4‰, and some grains contain extreme ¹⁶O-rich areas (δ¹⁷O, δ¹⁸O = ∼−30‰) nearly 10 μm across. We detected oxygen isotopic migration of approximately 1 μm at the boundaries of the extreme ¹⁶O-rich areas. Using oxygen self-diffusivity in olivine, the heating time of the igneous rim formation could have continued from several hours to several days at near liquidus temperatures (∼2000 K) in the solar nebula suggesting that the rim formed by a similar flash heating event that formed the chondrules.  相似文献   

中国对虾生物能量学研究Ⅰ——温度、体重、盐度和摄食状态对耗氧率和排氨率的影响   总被引：2，自引：0，他引：2  

张硕  董双林  王芳 《中国海洋大学学报(自然科学版)》1998,(2)

实验于１９９６年５月～９月对３种规格养殖中国对虾在不同条件下的耗氧率和排氨率进行了测定。结果表明,温度、体重、盐度和摄食状态对其代谢有显著影响。耗氧率（ＱＯ）和排氨率（ＱＮ）与温度正相关,ｌｎＱＯ＝０．０５８Ｔ－２．８９４;ｌｎＱＮ＝０．０７６Ｔ＋１．１１６;而与体重呈负相关,ＱＯ＝０．５１５Ｗ－０．１２６;ＱＮ＝２５．０５Ｗ－０．１９９。在盐度５～３５范围内,中国对虾（３．０２５ｇ±０．０８８ｇ）的耗氧率和排氨率在盐度２８时最小。中国对虾（３．１３ｇ±０．０７２ｇ）摄食沙蚕和配合饲料,在饱食状态下耗氧率比饥饿状态下分别提高了８３．９％和２９．３％,排泄率增加了１１３．８％和９３．６％,表明摄食时蛋白质代谢增加显著。  相似文献   

Redox evolution of western Tianshan subduction zone and its effect on deep carbon cycle     

《地学前缘(英文版)》2020,11(3):915-924

Knowing the phase relations of carbon-bearing phases at high-pressure(HP) and high-temperature(HT) condition is essential for understanding the deep carbon cycle in the subduction zones.In particular,the phase relation of carbon-bearing phases is also strongly influenced by redox condition of subduction zones,which is poorly explored.Here we summarized the phase relations of carbon-bearing phases(calcite,aragonite,dolomite,magnesite,graphite,hydrocarbon) in HP metamorphic rocks(marble,metapelite,eclogite) from the Western Tianshan subduction zone and high-pressure experiments.During prograde progress of subduction,carbonates in altered oceanic crust change from Ca-carbonate(calcite) to Ca,Mg-carbonate(dolomite),then finally to Mgcarbonate(magnesite) via Mg-Ca cation exchange reaction between silicate and carbonate,while calcite in sedimentary calcareous ooze on oceanic crust directly transfers to high-pressure aragonite in marble or amorphous CaCO3 in subduction zones.Redox evolution also plays a significant effect on the carbon speciation in the Western Tianshan subduction zone.The prograde oxygen fugacity of the Western Tianshan subduction zone was constrained by mineral assemblage of garnet-omphacite from FMQ-1.9 to FMQ-2.5 at its metamorphic peak(maximum P-T) conditions.In comparison with redox conditions of other subduction zones,Western Tianshan has the lowest oxygen fugacity.Graphite and light hydrocarbon inclusions were ubiqutously identified in Western Tianshan HP metamorphic rocks and speculated to be formed from reduction of Fe-carbonate at low redox condition,which is also confirmed by high-pressure experimental simulation.Based on petrological observation and high-pressure simulation,a polarized redox model of reducing slab but oxidizing mantle wedge in subduction zone is proposed,and its effect on deep carbon cycle in subduction zones is further discussed.  相似文献   

Kainsaz(CO3)陨石中两个富Al球粒的氧同位素组成特征与形成演化     

戴德求  包海梅  刘爽  尹锋 《岩石学报》2020,36(6):1850-1856

富Al球粒是原始球粒陨石中一种矿物岩石学特征介于富钙铝包体(CAIs)和镁铁质硅酸盐球粒之间的特殊集合体,所以常常认为富Al球粒在认识CAIs和镁铁质硅酸盐球粒形成演化过程中的相互联系具有特殊意义。然而,对富Al球粒的初始物质组成以及形成演化过程一直存在较多争议,而氧同位素组成研究能够对球粒演化和早期星云环境等提供重要的信息。在本文中我们报导了来自Kainsaz(1937年降落于俄罗斯,CO3型)碳质球粒陨石中的2个富Al球粒(编号K1-CH1和K2-CH2)的矿物岩石学和氧同位素组成特征。K1-CH1的矿物组成主要为橄榄石、低钙辉石和富钙长石,K2-CH2为橄榄石和富钙长石。2个球粒中的矿物均具有贫~(16)O同位素组成特征。K1-CH1中矿物的△~(17)O组成基本上位于2个区间:-11.1‰～-8.7‰和-3.9‰～0.4‰;而K2-CH2的△~(17)O介于-6.6‰～-0.6‰之间,且具有从中部至边部升高的趋势。矿物岩石学和氧同位素特征表明,这2个富Al球粒的初始物质组成为富CAIs和镁铁质硅酸盐。在球粒熔融结晶过程中,与贫~(16)O同位素组成(△~(17)O:-8.7‰～-7.8‰)的星云发生了氧同位素交换。球粒形成后,发生迁移进入陨石母体,在相对更贫~(16)O同位素组成(△~(17)O:-0.6‰～0.4‰)的母体中(流体参与)发生变质作用,并再次发生了氧同位素交换。  相似文献   

Fluid sources and stable isotope signatures in authigenic carbonates from the Northern Apennines,Italy     

《Marine and Petroleum Geology》2017

Authigenic carbonates are frequently associated with methane cold-seep systems, which extensively occur in various geologic settings worldwide. Of interest is the relation between the fluids involved in their formation and the isotopic signals recorded in the carbonate cements. Along the Northern Apennines foothills (Italy), hydrocarbons and connate waters still seeping nowadays are believed to be the primary sources for the formation of fossil authigenic carbonate found in Plio-Pleistocene marine sediments. Four selected outcrops of dolomitic authigenic carbonates were analysed to compare signature of seeping fluids with fractionation of stable carbon and oxygen isotopes recorded in the carbonate.Along the foothills, deep methane-rich fluids spontaneously rise to the surface through mud volcanoes or are exploited in wells drilled nearby to the fossil Plio-Pleistocene authigenic carbonates. The plumbing system providing fluids to present-day cold seeps was structurally achieved in Late Miocene and Plio-Pleistocene. δ¹³C values of methane, which vary from −51.9 to −43.0‰ VPDB, indicate that gas composition from the deep hydrocarbon reservoirs is relatively uniform along the foothills. On the contrary, δ¹³C in fossil authigenic carbonates strongly varies among different areas and also within the same outcrop.The different carbon sources that fed the investigated carbonates were identified and include: thermogenic methane from the deep Miocene reservoirs, ¹³C-enriched CO₂ derived from secondary methanogenesis and microbial methane from Pliocene successions buried in the Po Plain. The δ¹³C variability documented among samples from a single outcrop testifies that the authigenic carbonates might represent a record of varying biogeochemical processes in the hydrocarbon reservoirs. The sources of stable oxygen isotopes in authigenic carbonates are often ascribed to marine water. Oxygen isotopic fractionation in the dolomite cements indicates that marine pore water couldn't be the sole source of oxygen. δ¹⁸O values provide a preliminary evidence that connate waters had a role in the carbonates precipitation. The concomitant occurrence of active cold seepages and fossil record of former plumbing systems suggests that generation and migration of hydrocarbons are long-lasting and very effective processes along the Northern Apennines foothills.  相似文献   

湖泊碳酸盐在过去环境变化研究中的应用   总被引：2，自引：0，他引：2       下载免费PDF全文

郭金春  马海州  宋恩玉  陈宁 《盐湖研究》2008,16(2):66-72

国内外的研究成果表明,湖泊沉积碳酸盐矿物及其微量元素、同位素分布特征记录了全球或区域古气候环境演变历史,可以从中提取大量定量化的古气候参数。因此,可以根据湖泊碳酸盐矿物的含量和碳、氧同位素变化等信息推知其形成时期的气候环境,重建古环境,揭示气候环境演变的规律。湖泊碳酸盐是一种研究古环境演化重要的代用指标,在过去气候环境变化研究中有广阔的应用前景。  相似文献   

Improvement of Oxygen Release from Calcium Peroxide‐polyvinyl Alcohol Beads by Adding Low‐cost Bamboo Biochar and Its Application in Bioremediation          下载免费PDF全文

Chih‐Hung Wu  Shih‐Hsien Chang  Chi‐Wen Lin 《洁净——土壤、空气、水》2015,43(2):287-295

  相似文献   

Paramagnetic lattice defects in quartz for applications to ESR dating     

《Quaternary Geochronology》2015

Quartz is one of the minerals useful for ESR dating with many applications. Although the study has quite a long history since 1980's, ESR dating of quartz is still in a developing stage. After the basis in physics for the ESR signals in quartz is described, the current status of ESR dating of quartz is summarized for applications to fault gouge, tephra and sediment. Both basic studies for mechanisms and practical applications with independent age controls are still necessary to establish the protocols.  相似文献   

大荔人遗址黄土-古土壤剖面岩石磁学性质研究   总被引：1，自引：0，他引：1       下载免费PDF全文

霍俊杰  Reidar Lovlie  李斌  苏朴 《地球物理学报》2010,53(6):1463-1474

自从大荔人化石被发现以来,其遗址剖面便成为研究热点.先前的研究主要集中在地层的对比划分与头盖骨年龄的推断方面,然而对于载磁矿物的鉴定及其古气候含义方面的研究却相对较少.鉴于此,本文运用热磁分析、饱和等温剩磁和剩磁矫顽力谱分析、磁滞回线分析、频率磁化率分析、热退磁分析等方法,对大荔人遗址剖面进行了系统的岩石磁学性质研究,鉴定出其主要载磁矿物为磁铁矿,赤铁矿,磁赤铁矿,磁畴状态主要是似单畴.磁铁矿,赤铁矿是样品中特征剩磁的携带者;主要起源于成土作用的超顺磁颗粒和新生成的亚铁磁性矿物,是古土壤样品磁化率增强的主要贡献者;古土壤中软磁性矿物的含量高于黄土.样品中磁赤铁矿的含量并不高.黄土-古土壤样品的频率磁化率曲线,古里雅冰芯氧同位素、细微粒浓度曲线,岐山五里铺剖面有机质含量曲线在古气候记录方面具有一致性,都展示出至少从MIS5以来,气候从冰期到间冰期的变化是渐变的,反之则表现了突变特征.上述岩石磁学研究丰富了大荔剖面的磁学领域研究内容,为相关课题的深入研究提供了依据.  相似文献