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31.
Ricardo Castelló Clemente Recio Pilar Morillas Carmen Vizcayno 《Environmental Geology》2008,54(4):679-688
The role of municipal solid waste (MSW) landfill leachate on the genesis of minor amounts of pyrite associated with gypsum
in an otherwise predominantly evaporitic sequence was studied in geological and geochemical terms. The potential association
between landfill leachate and the conditions required for bacterial reduction of sulfate and fixation of H2S as pyrite were examined. The lithological column was generally found to contain little or no Fe. The δ34S values for sulfates were consistent with previously reported data; however, the measured δ18O values were slightly higher. Sulfides disseminated in the marl/lutite exhibited higher δ34S values (≈−8‰) than gypsum-coating pyrite crystals (δ34S < −30‰). Dissolution of gypsum to sulfate and the supply of metabolizable organic matter and Fe required for H2S fixation as sulfides may have originated from landfill leachate. Intermittent availability of leachate, a result of the
precipitation regime, can facilitate sulfur disproportionation and lead to fractionations as high as 相似文献
32.
Heavy metals in sediments of the Tecate River, Mexico 总被引:1,自引:0,他引:1
F. T. Wakida D. Lara-Ruiz J. Temores-Peña J. G. Rodriguez-Ventura C. Diaz E. Garcia-Flores 《Environmental Geology》2008,54(3):637-642
Ten sites along the Tecate River, Mexico were sampled to evaluate the cadmium, lead, nickel and chromium concentrations in
sediments. The result shows contamination for cadmium in most of the sites, where two sites were class 4 (polluted to strongly
polluted) according to geoaccumulation index proposed by Muller. Two sites were found polluted for all the heavy metals analyzed
(Cr, Cd, Pb and Ni), indicating the effect of anthropogenic activities. A correlation between Ni and Cd concentration had
been found indicating a common source. These metals are usually used in electroplating industry. The results of this study
can be used for decision makers to prioritize measures to control the pollution for these metals. 相似文献
33.
Doline probability map using logistic regression and GIS technology in the central Ebro Basin (Spain) 总被引:3,自引:0,他引:3
In the surroundings of Zaragoza, karstification processes are especially intense in covered karst areas where fluvial terraces
lie directly on Tertiary evaporites. Since the beginning of Quaternary, these processes have lead to the development of collapse
and subsidence dolines with a wide range of sizes, which have significant economic impacts. To reduce economic impact and
increase safety, a regional analysis of this phenomenon is needed for spatial management. Therefore, a probability map of
dolines was developed using logistic regression and geographic information system (GIS) techniques. This paper covers the
selection of input data, manipulation of data using the GIS technology, and the use of logistic regression to generate a doline
probability map. The primary variable in the doline development in this area is geomorphology, represented by the location
of endorheic areas and different terrace levels. Secondary variables are the presence of irrigation and the water table gradient. 相似文献
34.
Response of groundwater chemistry to water deliveries in the lower reaches of Tarim River,Northwest China 总被引:2,自引:0,他引:2
Yongjin Chen Kefa Zhou Yaning Chen Weihong Li Jiazhen Liu Tao Wang 《Environmental Geology》2008,53(6):1365-1373
In this paper, we analysed the monitored data from nine groundwater-monitoring transects in the lower reaches of Tarim River
during the five times of stream water deliveries to the river transect where the stream flow ceased. The results showed that
the groundwater depth in the lower reaches of Tarim River rose from −9.30 m before the conveyances to −8.17 and −6.50 m after
the first and second conveyances, −5.81 and −6.00 m after the third and fourth the conveyance, and −4.73 m after the fifth.
The horizontal extent of groundwater recharge was gradually enlarged along both sides of the channel of conveyance, i.e.,
from 250 m in width after the first conveyance to 1,050 m away from the channel after the fourth delivery. With the rising
groundwater level, the concentrations of major anions Cl−, SO42− and cations Ca2+, Mg2+, Na+, as well as total dissolved solids (TDS) in groundwater underwent a significant change. The spatial variations in groundwater
chemistry indicated that the groundwater chemistry at the transect near Daxihaizi Reservoir changed earlier than that farther
from it. In the same transect, the chemical variations were earlier in the monitoring well close to watercourse than that
farther away from the stream. In general, the concentration of the major ions and TDS at each monitoring well increased remarkably
when the water delivery started, and decreased with the continued water delivery, and then increased once again at the end
of the study period. Hence, the whole study period may be divided into three stages: the initial stage, the intermediate stage
and the later stage. According to the three stages of groundwater chemistry reaction to water delivery and the relationships
between groundwater chemical properties and groundwater depths, we educe that under the situation of water delivery, the optimum
groundwater depth in the lower reaches of the Tarim River should be −5 m. 相似文献
35.
Natural radioactivity in sediment of Wei River,China 总被引:1,自引:0,他引:1
The concentrations of natural radionuclides in sediment of Wei River of China were measured using γ-ray spectrometry with
the aim of estimating the radiation hazard as establishing a database for radioactivity levels of river sediment of China.
The activity concentrations of 226Ra, 232Th and 40K in sediment samples ranged from 10.4 to 39.9 Bq kg−1, 15.3 to 54.8 Bq kg−1 and 514.8 to 1,175.5 Bq kg−1, respectively. The concentrations of these radionuclides were compared with the typical world values and the average activities
of Chinese soil and Shaanxi soil. Radium equivalent activity (Raeq), external hazard index (H
ex) and representative level index (I
γr) were calculated for the samples to assess the radiation hazards arising due to the use of these sediment samples in the
construction of dwellings. All the sediment samples have Raeq lower than the limit of 370 Bq kg−1, H
ex less than unity and I
γr close to 1 Bq kg−1. The overall mean outdoor terrestrial gamma dose rate is 64.8 nGy h−1 and the corresponding outdoor annual effective dose is 0.079 mSv. None of the studied location is considered a radiological
risk and sediment can be safely used in construction. 相似文献
36.
Zaragoza city is located in the central Ebro Basin, in the Iberian Peninsula. The fluvial terraces formed by the Ebro River
present a valuable resource of sand and gravel deposits. However, taking advantage of these available resources implies conflicts
with other land use interests like urban and industrial development as well as agricultural use, which has also traditionally
occupied the alluvial terraces. These deposits represent a substantial groundwater resource that should be preserved for future
generations. The development of spatial decision support systems (SDSS) has greatly assisted efforts for solving land-use
conflicts. These systems combine the benefits of geographic information systems (GIS) and decision support methodologies and
are therefore suitable to manage sustainable development of urban areas. In this contribution, an extraction suitability map
taking into consideration a variety of environmental criteria is created with the help of a SDSS. The method used is the analytical
hierarchy process which is integrated in ArcGIS. Areas most suitable to sand and gravel extraction are located in the high
terraces, and in those terraces covered by pediments where the thickness of resource is relatively high. These areas are far
from valuable natural areas, outside areas most vulnerable to groundwater contamination, and beneath soils with poor irrigation
characteristics. 相似文献
37.
Three discriminant function models are raised and cross-compared in order to distinguish geochemical patterns characteristic
for the Drava River floodplain sediments. Based on data representing total element concentrations in samples collected from
alluvium (A), terrace (T), and unconsolidated bedrock (B) at the border of a floodplain, four element clusters emerged accounting
for discrimination between the referred groups of sediments. The most prominent is contaminant/carbonate cluster characteristic
for alluvium. The other two are: silicate cluster typical for unconsolidated geological substrate (Neogene sedimentary rocks);
and naturally dispersed heavy metal cluster separating terrace from the former two groups. Models introducing depth intervals
and single profiles as grouping criteria reveal identical sediment-heavy metal matrices. The second important issue of this
paper is possibility of reclassification of samples originally assigned to one of the a priori defined groups of sediments,
based on established geochemical pattern. The mapped geological units can be reconsidered by the post hoc assignments to a
different group if geological border between alluvium and terrace or between terrace and bedrock can not be established geologically
with absolute certainty. 相似文献
38.
Glacier change and glacier runoff variation in the Tuotuo River basin,the source region of Yangtze River in western China 总被引:3,自引:0,他引:3
Glaciers in the Tuotuo River basin, western China, have been monitored in recent decades by applying topographical maps and
high-resolution satellite images. Results indicate that most of glaciers in the Tuotuo River basin have retreated in the period
from 1968/1971 to 2001/2002, and their shrinkage area is 3.2% of the total area in the late 1960s. To assess the influence
of glacier runoff on river runoff, a modified degree–day model including potential clear-sky direct solar radiation has been
applied to the glaciated regions of the river basin over the period 1961–2004. It was found that glacier runoff has increased
in the last 44 years, especially in the 1990s when a two-thirds increase in river runoff was derived from the increase in
glacier runoff caused by loss of ice mass in the entire Tuotuo River basin. 相似文献
39.
M. Beatriz Aguirre-Urreta Pablo J. Pazos Darío G. Lazo C. Mark Fanning Vanesa D. Litvak 《Journal of South American Earth Sciences》2008,26(1):91-99
A high-resolution ion-microprobe (SHRIMP) U–Pb zircon age from a tuff layer intercalated in the ammonoid bearing sedimentary succession of the Neuquén Basin in Argentina provides a robust geochronologic date to add to the absolute ages and to improve the relative chronology of the Early Cretaceous Hauterivian stage. The tuff layer appears interbedded between shales of the upper member (Agua de la Mula) of the Agrio Formation within the Spitidiscus riccardii ammonoid zone (base of the Late Hauterivian) yielding a date of 132.5 ± 1.3 Ma. This date confirms and supports an accurate correlation between the ammonoid biostratigraphy of the Neuquén Basin with the Western Mediterranean Province of the Tethys during the Early Cretaceous and matches with the most recently published time scale. It also casts doubts on the validity of K–Ar ages on glauconite-grains recently reported from the Lower Cretaceous of the Vocontian Basin of France. 相似文献
40.
Quantitative sinkhole hazard assessments in karst areas allow calculation of the potential sinkhole risk and the performance
of cost-benefit analyses. These estimations are of practical interest for planning, engineering, and insurance purposes. The
sinkhole hazard assessments should include two components: the probability of occurrence of sinkholes (sinkholes/km2 year) and the severity of the sinkholes, which mainly refers to the subsidence mechanisms (progressive passive bending or
catastrophic collapse) and the size of the sinkholes at the time of formation; a critical engineering design parameter. This
requires the compilation of an exhaustive database on recent sinkholes, including information on the: (1) location, (2) chronology
(precise date or age range), (3) size, and (4) subsidence mechanisms and rate. This work presents a hazard assessment from
an alluvial evaporite karst area (0.81 km2) located in the periphery of the city of Zaragoza (Ebro River valley, NE Spain). Five sinkholes and four locations with features
attributable to karstic subsidence where identified in an initial investigation phase providing a preliminary probability
of occurrence of 0.14 sinkholes/km2 year (11.34% in annual probability). A trenching program conducted in a subsequent investigation phase allowed us to rule
out the four probable sinkholes, reducing the probability of occurrence to 0.079 sinkholes/km2 year (6.4% in annual probability). The information on the severity indicates that collapse sinkholes 10–15 m in diameter
may occur in the area. A detailed study of the deposits and deformational structures exposed by trenching in one of the sinkholes
allowed us to infer a modern collapse sinkhole approximately 12 m in diameter and with a vertical throw of 8 m. This collapse
structure is superimposed on a subsidence sinkhole around 80 m across that records at least 1.7 m of synsedimentary subsidence.
Trenching, in combination with dating techniques, is proposed as a useful methodology to elucidate the origin of depressions
with uncertain diagnosis and to gather practical information with predictive utility about particular sinkholes in alluvial
karst settings: precise location, subsidence mechanisms and magnitude, and timing and rate of the subsidence episodes. 相似文献