Hydrous pyrolysis of a Type III source: fractionation effects during primary migration in natural and artificially matured samples     

C.S. Mishra  U. Samanta  A. Gupta  N.J. Thomas  K.N. Misra 《Organic Geochemistry》1996,25(8):489-505

A core from the Cambay Shale Formation of the Cambay Basin, containing immature Type III organic matter, was pyrolysed at 300°C for different durations of time to different maturation levels. Fractionation effects were studied employing a three-step extraction technique after removal of the expelled pyrolysate. The extractable organic matter (EOM) obtained on extraction of the whole core is assumed to be that present in open pores, while that obtained on finely crushing the sample is assumed to be that present in closed pores. The EOM obtained from 1 cm chips is termed EOM from semi-open pores. The gross composition of the pyrolysates expelled during pyrolysis is not similar to the oils reservoired in the area, and there is no significant fractionation observed between expelled pyrolysates and unexpelled EOM. Our study indicates movement of fluids between closed, semi-open and open pores. In both systems, there is a higher concentration of EOM in open pores than in semi-open and closed pores, and the fraction of EOM in open pores is much greater in the artificial system than in the natural system. Fractionation effects on n-alkane and isoprenoid hydrocarbon-based parameters were also studied. n-Alkenes are present in semi-open and closed pores of the immature core and in the core after it was pyrolysed to 300°C for 6 and 48 h, but are absent in the open pores. n-Alkenes are present in closed pores in the naturally matured core. Presence of n-alkenes in the pyrolysates expelled during the 6 and 48 h experiments, but their absence in the open pores of the core, indicates that expulsion also occurs through temporary microfractures during laboratory pyrolysis, whereas in the natural system expulsion from closed pores seems to be only via semi-open and open pores.  相似文献   

Supercritical Carbon Dioxide Extraction of Organic Matter from Petroleum Source Rocks and Its Implications   总被引：2，自引：0，他引：2  

沈忠民  周光甲等 《中国地球化学学报》1996,15(4):324-330

Organic matter was experimentally extracted by supercritical fluids(CO2 1% isopropanol)from petroleum source rocks of different thermo-maturities at different buried depths in the same stratigraphic unit in the Dongying Basin.The results show that supercritical fluid extraction(SFE)is more effective than Soxhlet extraction(SE),with higher amounts and greater varieties of hydrocarbons and soluble organic matter becoming extractive.The supercritical CO2 extraction is therefore considered more valuable in evaluation of petroleum source rocks and oil resources,particularly those of immature types.  相似文献   

钛（Ⅳ）的反相萃取柱色层新体系研究及应用     

谭龙华  唐祖光 《矿物岩石》1997,17(3):94-97

本文研究了以ｃＨＣｌ＝８ｍｏｌ·Ｌ－１盐酸为移动相，以聚四氟乙烯负载的钽试剂－ＣＨＣｌ３为固定相反相萃取层析钛（Ⅳ）的新体系，柱上层析的钛用ｃＨＣｌ＝３ｍｏｌ·Ｌ－１盐酸洗脱后经二安替比林甲烷光度法测定，不仅钛回收率可达１００％，并可使钛（Ⅳ）与多种离子分离。能用于矿物岩石类复杂样品及其他物质中钛的分离富集与测定，方法简便快速。  相似文献   

Right-Angle Rooftop Polygon Extraction in Regularised Urban Areas: Cutting the Corners   总被引：1，自引：0，他引：1  

A. Croitoru  Y. Doytsher 《The Photogrammetric Record》2004,19(108):311-341

  相似文献   

电吸附找矿方法   总被引：3，自引：2，他引：3  

周奇明  周立宏  董树政 《物探与化探》2004,28(3):199-201

电吸附找矿方法是找隐伏矿的新方法。它是指通过物理化学手段来发现后生地球化学异常的找矿方法。它是建立在异常元素地球化学理论和野外地电提取法的理论基础之上。利用电吸附找矿方法在一些已知矿床进行找矿效果试验,获得了很好的效果,说明了该方法找矿的有效性。  相似文献   

High-pressure experimental growth of diamond using C–K₂CO₃–KCl as an analogue for Cl-bearing carbonate fluid     

Emma Tomlinson  Adrian Jones  Judith Milledge 《Lithos》2004,77(1-4):287-294

High-pressure, high-temperature diamond growth experiments have been conducted in the system C–K₂CO₃–KCl at 1050–1420 °C, 7.0–7.7 GPa. KCl is of interest because of the strong effect of halogens on the phase relations of carbonate-rich systems [Geophys. Res. Lett. 30 (2003) 1022] and because of the occurrence of KCl coexisting with alkali silicate–carbonate fluids in natural-coated diamond [Geochim. Cosmochim. Acta 64 (2000) 717]. We have used system C–K₂CO₃–KCl as an analogue for these mantle fluids in diamond growth experiments. The presence of KCl reduces the potassium carbonate liquidus to ≤1000 °C at 7.7 GPa, allowing it to act as a solvent catalyst for diamond growth at temperatures below the continental geotherm. This is a reduction on the minimum diamond growth temperature reported in the alkali-carbonate–C–O–H system [Lithos 60 (2002) 145]. Diamond growth using carbonate solvent catalysts is characterised by a relatively long induction period. However, the addition of KCl also reduced the period for diamond growth in carbonate to 5 min; no such induction period appears to be necessary. It is suggested that KCl destabilises carbonate, allowing greater solubility and diffusion of carbon.  相似文献   

基于PRS的遥感图像地物信息提取模型     

高芳琴  孙建中 《国土资源遥感》2004,15(3):18-22

点源理论(PRS)是一种面向应用需求的集中信息处理方式。不同尺度、不同分辨率的点都是一定的综合信息场,是客观世界的真实反映。本文在数字图像处理过程中引入点源理论,探讨针对地物空间信息应用服务的遥感信息分析和处理模型,讨论基于点源的图像构造、知识构造及地物模型建造过程,给出基于点源的遥感图像地物提取流程。  相似文献   

Automatic Road Change Detection and GIS Updating from High Spatial Remotely-Sensed Imagery     

ZHANGQiaoping IsabelleCouloigner 《地球空间信息科学学报》2004,7(2):89-95

This paper presents a tramework for road network change detectlon In order to upctate the Canadian National Topographic DataBase (NTDB). The methodology has been developed on the basis of road extraction from IRS-pan images (with a 5.8 m spatial resolution) by using a wavelet approach. The feature matching and conflation techniques are used to road change detection and updating. Elementary experiments have showed that the proposed framework could be used for developing an operational road database updating system.  相似文献   

基于灰度形态学的高分辨率遥感影像预处理   总被引：6，自引：0，他引：6  

王耀苹王玉海  朱长青陈星 《测绘学院学报》2004,21(2):108-110

提出了一种从高分辨率遥感影像中提取线性目标时影像预处理的方法。该方法基于灰度形态学的Top-Hat运算和灰度膨胀运算，用Top-Hat算子除去影像的噪声，再利用灰度膨胀增强影像目标和背景之间的对比度，使目标更易于识别。经过处理的遥感影像，能够更有效地提取影像的目标。  相似文献   

基于模糊算子理论的道路半自动提取   总被引：2，自引：0，他引：2  

王天鹏  姜挺 《测绘学院学报》2004,21(3):187-189

提出了一种基于模糊算子理论的道路半自动提取方法。该方法在对小比例尺影像进行Sobel边缘检测的基础上，定义了12种模糊算子表示2维道路的各种可能的结构，然后在给定道路种子点附近形成的一定范围内进行搜索，提取出道路的中心线。实验结果表明，该算法速度较快并且具有较强的鲁棒性。  相似文献