石墨炉原子吸收光谱法测定镁基合金中的铍和镍     

牛娜  何超君  凌爽 《地质与资源》2009,18(2):155-156,160

采用石墨炉原子吸收光谱法测定镁基合金中的铍和镍.研究并校正了基体对待测元素的影响.方法简单、快速.对含铍11.4×10^-6、镍9.25×10^-6的样品11份测定,相对标准偏差分别为3.5%、4.3%,铍、镍回收率分别为98.8%、97.5%.  相似文献   

VVVF变频器在电梯系统改造中的应用   总被引：1，自引：0，他引：1  

肖工赠  蒋胜泉 《华东地质学院学报》2000,23(3):264-266

采用交流变频调速器（ＶＶＶＦ变频器）对继电器控制方式的电梯（如：交流双速梯、交流调整梯、直流梯等）进行改造,对改善电梯的运行性能、社会性能、乘坐舒适感、节能等方面有极大的优越性,代表了当今电梯系统改造的主流方向,本文介绍了ＶＶＶＦ变频器在高层电梯系统改造中的实际应用。  相似文献   

全热解石墨管石墨炉原子吸收法测定痕量锶   总被引：2，自引：0，他引：2  

郑衍生  周采菊 《岩矿测试》1992,11(3):236-239

研究了热解涂层和全热解石墨管中Sr的原子吸收信号形状和原子化行为,讨论了CaCl_2、FeCl_3和HClO_4,抑制Sr吸收信号的原因。采用EDTA铵盐作基体改进剂,全热解石墨管石墨炉原子吸收法直接测定河泥中痕量Sr,方法的特征量为6.9pg/0.0044A。  相似文献   

不同原子化方法对样品气化速率的影响   总被引：1，自引：0，他引：1  

侯书恩  常诚 《岩矿测试》1991,10(1):21-24

本文研究了石墨炉原子吸收分析中管壁、平台和探针原子化测量Cd、Pb、Mn、Co、Cu和Cr的吸收信号特征。结果表明,吸收信号形状由被测元素的性质、样品气化速率和原子蒸气扩散速率决定。对于同一元素,在选定仪器条件下,峰形主要由样品气化速率决定。而样品气化速率又与原子化表面的升温速率有关。三种原子化方法中,探针的升温速率最快,得到较窄的信号峰,平台的升温速率最慢,峰形较宽。在提高样品气化速率方面,探针原子化是最理想的方法。  相似文献   

The effects of sodium sulfate on the emissions characteristics of an emulsified marine diesel oil-fired furnace     

Cherng-Yuan Lin  Jenq-Yih Pan 《Ocean Engineering》2001,28(4)

Degraded diesel oils are commonly used in marine power plants to conform to the demands of shipowners for fuel economy. The burning of these marine fuel oils, which frequently contain various extents of oxides of iron, silicon, calcium, vanadium and potassium, such as Na₂SO₄, Fe₂O₃, SiO₂, CaO, V₂O₅, etc., are susceptible to form much more complex compounds of either gaseous or solid phases. The release of these emissions to the environment may cause atmospheric pollution and a health hazard to human beings. Emulsification of a fuel oil with water to produce a micro-water-particles-dispersed-in-oil (W/O) emulsion has been considered as one of the promising techniques to improve combustion characteristics of low-grade marine oils and in turn effectively help to reduce the release of air pollutants. Marine fuel oil A, which approximates ASTM No. 2D oil was used as the test oil and the surfactant Span 80 was used to promote the affinity and integrating force between the components of the emulsion. An emulsifying/homogenizing machine was employed to stir the emulsion mixture of the marine oil, distilled water, surfactant Span 80 and sodium sulfate (Na₂SO₄) powder of 300 ppm. The mechanically blended emulsion mixture was injected, atomized and burned in an oil-fired furnace using an automatic burner. Burning gas composition, burning efficiency and gas temperature were measured and analyzed. Compared to neat marine diesel oil, W/O emulsions had higher combustion efficiencies, higher concentrations of O₂ and SO₂, while gas temperatures were lowered and CO and NO_x production was reduced. The addition of sodium sulfate decreased combustion efficiency and NO_x concentration and increased O₂, CO, and SO₂ concentrations.  相似文献   

Forced vibration analysis of an offshore tower carrying an eccentric tip mass with rotary inertia due to support excitation     

Jong-Shyong Wu  Chin-Tzu Chen 《Ocean Engineering》2007,34(8-9):1235-1244

Dynamic responses of structures due to earthquake excitation are the important problems in engineering, thus, the information concerned is plenty. However, most of the literature is relating to the discrete methods, particularly to the finite element method (FEM), and the one relating to the method combining both the “continuous” and “discrete” models is rare. The objective of this paper is to provide some information in this respect. First, the analytical solution for the natural frequencies and normal mode shapes of a “continuous” tower, without contacting water (or “dry” tower), carrying an eccentric tip mass possessing rotary inertia is determined. Next, the partial differential equation of motion for the forced vibration of the tower, contacting water (or “wet” tower), subjected to support excitation is transformed into a matrix equation by using the last natural frequencies and normal modes shape of the freely vibrating dry tower. Finally, the numerical integration method is used to solve the matrix equation to yield the seismic response of the wet tower. In theory, the mode superposition method is correct only if the total number of modes considered approaches infinity, however, numerical results of this paper reveal that superposition of only the lowest six modes will yield excellent results to be very close to the corresponding ones obtained from the conventional FEM. For this reason, the CPU time required by the presented approach is less than 5% of that required by the conventional FEM.  相似文献   

Emission characteristics of marine furnaces burned at varying inlet air temperatures and humidity     

Cherng-Yuan Lin  Wei-Cheng Chen 《Ocean Engineering》2003,30(18):2405-2422

Marine power plants are frequently operated under varying atmospheric air temperature and humidity conditions. The effects of inlet air temperatures and humidity of marine furnaces such as incinerators and boilers thus attract much research interest. An industrial furnace incorporated with an automatic burner was employed to experimentally investigate the influences of the inlet air temperature and humidity on the emission characteristics. The inlet air humidity and temperature were adjusted using an air-conditioning machine to preset values before being admitted into the burner. ASTM No. 2D diesel oil was atomized, mixed with the inlet air and burned inside the industrial furnace. Eight small rectangular slots were cut on the upper side of the furnace to allow gas analyzer and thermocouple probes to be inserted into the furnace center to measure the axial variations in the gas temperature, burning efficiency and burning gas compositions such as NO_x, SO₂, CO. The experimental results show that the O₂ and NOx emission concentrations decreased while the CO₂ emission concentration and burning efficiency increased with either increasing inlet air humidity or temperature.  相似文献   

转柱式散气增氧装置水动力特性的研究     

宋协法  高清廉  周玉光 《海洋科学》1995,19(5):52-56

从理论上分析了转柱式散气增氧装置扩散帽的水动力性能和影响进气量、功率消耗等方面的因素。同时选择了两个系列４种技术参数的扩散帽装置进行对比试验，试验结果与理论分析情况基本吻合。通过理论分析与试验测试，最后选定出扩散帽的最佳技术参数。  相似文献   

An enhanced homogenization approach for masonry structures with compressible joints. Application to hearth thermomechanical computations     

N. J. Mathieu  K. Sab  S. A. Zaïmi 《国际地质力学数值与分析法杂志》2012,36(9):1102-1124

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微晶萘共沉淀富集－石墨炉原子吸收法测定痕量银金钯     

肖宏展  梁树权 《岩矿测试》1995,(1)

基于贵金属同２－巯基苯并噻唑（ＭＢＴ）定量反应时的温度差异，在常温下采用ＭＢＴ为Ａｇ、Ａｕ和Ｐｄ的沉淀剂并藉微晶素共沉淀法富集痕量Ａｇ、Ａｕ和Ｐｄ，使之与Ｐｔ、Ｒｈ及贱金属分离。固相富集物溶解于Ｎ，Ｎ－二甲基甲酰胺后，直接用原子吸收法测定。试验了定量共沉淀的最佳条件，方法用标样分析验证，结果吻合较好。  相似文献