Surface chemical analysis in coal preparation research: complementary information from XPS and ToF-SIMS     

A. N. Buckley  R. N. Lamb 《International Journal of Coal Geology》1996,32(1-4)

The application of X-ray photoelectron spectroscopy (XPS) to coal surface characterisation for preparation research is described. Progress towards the acquisition of complementary surface chemical information by time-of-flight secondary ion mass spectrometry (ToF-SIMS) is also discussed. Surface-based beneficiation techniques such as flotation are assuming greater importance as the proportion of fines in raw coal increases due to the proliferation of high capacity mining methods. A necessary condition for the floatability of a coal particle is adequate hydrophobicity, and the degree of hydrophobicity of the flotation concentrate is one factor influencing the ease with which its dewatering can be affected. The hydrophobicity of a coal is very difficult to measure directly because of microporosity, and it is often necessary to deduce the degree of hydrophobicity from a knowledge of the surface chemistry. XPS is able to provide sufficient analytical data to allow relative levels of hydrophobicity to be estimated. In principle, ToF-SIMS should be able to supply additional information enabling refinement of such estimates; however, there are insufficient data at present to allow the ionic fragments detected to be related to specific functional groups at the coal surface.  相似文献   

Geodynamic Background of the Mesozoic Intracontinental Magmatism in Southeast China     

毛建仁  陶奎元等 《中国地球化学学报》1997,16(3):230-239

The authors have proposed a dynamic model in this paper based on the ages,rock series and associations,Sr-Nd isotopic signatures of the Mesozoic intracontinental magmatism overlying the Cathaysian and Yangtze blocks.The model describes the relation of intracontinental collision and subduction in the Tethyan tectonic regie with Paleo-Pacific oceanic plate sudbuction-strike slip-extension in the Pacific tectonic regime.During 220-150Ma,the horizontal collision between the North China block and the Yangtze block,as well as the intracontinental subduction of some divergent microcontinental terranes in the southwestern part of South China are ascribed to the influence of the Tethyan tectonic regime,giving rise to a volume of high-Isr and low-εNd(t) S-type granites only in the Cathaysian Block.During 145-90Ma,under the geodynamic backgound of subduction-strike slip-extension of the Paleo-Pacific oceanic plate on the basis of the deep tectonic process in the Tethyan tectonic regime,high-K,alkalirich calc-alkaline and shoshonitic volcano-plutonic complexes were generated in the Yangtze block,and high-K calc-alkalic and bimodal volcano-plutonic complexes were generated in the Cathaysian block.The occurrence of A-type peralkaline granites in the coastal areas of South east China indicates the end of Mesozoic intracontinental magmatism.  相似文献   

简评关于新产业区的国际学术讨论   总被引：36，自引：3，他引：36  

王缉慈 《地理科学进展》1998,17(3):32-38

２０世纪７０年代末和８０年代初，当发达国家的绝大部分地区陷入衰退与停滞时，少数几个地区的经济却呈复苏甚至增长的势头，这些地区在经济运作模式上的相似性，引起了研究者的兴趣。由于它们和历史上马歇尔所描述过的产业区有惊人的相似之处，学者们将他们归为一类，称之为新产业区。本文对正在向纵深发展的关于新产业区的国际学术讨论作了简要的评述，并探讨了新产业区理论在我国的研究背景与进展。  相似文献   

区域采样法测定水中硫酸根离子的研究     

李俊锋  张凯  鲍长利  许天博 《吉林大学学报(地球科学版)》1997,(1)

在分散度不同的区域内进行区域采样用于水中硫酸根离子的测定，结果令人满意。应用此方法测定硫酸根离子的线性范围为２００．０～３０００ｍｇ／Ｌ；进样频率为１２０次／ｈ；相对标准偏差为１．７０％  相似文献   

3-D finite element modeling for evolution of stress field and interaction among strong earthquakes in Sichuan-Yunnan region     

陈化然  陈连旺  马宏生  李轶群  张杰卿  何巧云  王建国 《地震学报(英文版)》2004,17(6)

Introduction Sichuan-Yunnan region is a major area with frequent strong earthquakes in Chinese mainland, especially the middle-southern segment of South-North Seismic Zone, where many strong earth-quakes occurred in history. In the past 30 years, Sichuan-Yunnan region has two seismically active periods: one is from Tonghai earthquake in 1970 to Longling-Songpan earthquake in 1976, the other is from Lancang earthquake in 1988 to now. During this two periods, the M=7.7 Tonghai, M=7.1 Dagua…  相似文献   

重庆城区浓雾的基本特征   总被引：13，自引：5，他引：13  

江玉华王强  李子华马力 《气象科技》2004,32(6):450-455

统计分析沙坪坝1951～2002年间发生的浓雾事件，结合2001年12月重庆市雾的外场试验资料，探索重庆市主城区浓雾的基本特征。重庆主城区浓雾随年代演变有减缓趋势；主城区浓雾是自然雾与烟尘等的混合物，河谷及城市效应使雾更浓；城市中出现浓雾的大气边界层特征是在近地面层有逆温及增湿降温现象；高浓度气溶胶的净辐射效应阻碍白天混合层发展，使大气边界层趋于稳定，它是重庆连续几天有雾的原因之一；浓雾具有一定的湿沉降作用，能有限地清洁空气；有浓雾的天气条件下，建议降低污染物的排放总量，以避免严重大气污染事件发生。  相似文献   

大气季节内振荡对印度洋—西太平洋地区热带低压/气旋生成的影响   总被引：24，自引：4，他引：24  

祝从文  Tetsuo Nakazaw  李建平 《气象学报》2004,62(1):42-50

文中利用EOF分析大气季节内振荡 (MJO)的时空变化的方法 ,研究了 1996年 9月～ 1997年 6月间的MJO活动对生成在印度洋—西太平洋海域的热带低压 /气旋的影响。结果发现 ,除西北太平洋之外 ,发生在其他区域的热带低压 /气旋有半数以上生成在向东移动的MJO的湿位相中。伴随MJO的向东传播 ,热带低压 /气旋平均生成位置也随之向东移动 ,而生成在西北太平洋的热带低压 /气旋分别受到向东和向西传播的MJO影响  相似文献   

南京-镇江地区多目标地球化学调查初步成果   总被引：8，自引：1，他引：8  

廖启林  吴新民  金洋 《物探与化探》2004,28(3):257-260

报道了南京—镇江地区开展的多目标地球化学调查工作以来所取得的初步成果,讨论了如何确定土壤中元素的背景值、如何检查评价地球化学异常、如何针对农业地质的需要开展深入研究等问题,并提出了开展调查工作的具体建议。  相似文献   

内蒙古东部闹牛山铜矿成矿地质背景分析   总被引：4，自引：0，他引：4  

耿文辉  姚金炎 《矿产与地质》2004,18(3):240-244

通过对闹牛山铜矿区与成矿有关的次火山岩岩石化学分析，以及对矿区火山一次火山岩微量元素、稀土元素的分析，结合相关的铅同位素分析，综合分析了该矿床的成矿地质背景。认为：闹牛山铜矿床构造环境属于大陆边缘裂陷带的局部隆起区，成矿火山岩浆为钙碱性，其来源于地壳深部或上地慢，并有上部地壳物质混染。  相似文献   

湘中南二叠系孤峰组硅质岩的成因属性及其地球动力学指示意义   总被引：5，自引：0，他引：5  

付伟  周永章  杨志军  何俊国  张澄博  杨海生 《矿物岩石地球化学通报》2004,23(4):292-300

华南二叠系底部的硅质岩及同一层位对应于华南重要的地幔强活动期和成矿期，有非常重要的动力学指示意义。研究表明，孤峰组剖面的岩性可划分为三段：泥页岩段、厚层状硅质岩段和薄层状硅质岩段。沿剖面自下而上，Al2O3、K2O和TiO2含量逐渐降低，MnO、TFe等组分逐渐升高；稀土元素显示出一定的铈负异常，∑REE偏低，且向上∑REE逐渐减少而HREE／LREE逐渐增高；一些热水沉积诊断性微量元素如As、Sb、Hg等也显示出一定程度的异常。这些特征均表明硅质岩的成岩过程中包含有正常沉积和热水沉积的共同作用，且自下而上热水沉积作用逐渐增强的趋势。这种成岩作用的演化特征，代表了下扬子地台拉张裂陷盆地对晚古生代伸展背景的沉积响应，对于探讨裂谷盆地阶段性发育的动力学特征有一定的指示意义。  相似文献