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11.
膜分离技术的应用及发展趋势 总被引:8,自引:0,他引:8
综述世界和中国膜分离技术的发展,并对膜分离技术的基本特性、技术特点、膜材料、分类及膜分离装置进行了简单介绍;并介绍了膜分离法在化工及石油工业、食品工业、医药工业和医疗设备、生物技术和环境工程中的应用,并分析了膜分离技术将会在膜材料、新的膜过程和集成膜过程3个方面的发展趋势。同时指出如果能解决膜产品的价格、膜污染和膜分离性能的提高这3个膜的制约因素,膜分离技术将在人类社会的发展史上起到不可替代的作用。 相似文献
12.
YousifK. Kharaka Evangelos G. Kakouros James J. Thordsen David L. Naftz 《中国地球化学学报》2006,25(B08):100-101
Selenium (Se) is an essential micronutrient to biota, but can become a potent toxicant at elevated concentrations. The natural sources and chemical properties of Se species make the boundary between deficiency and toxicity narrow for some biota, with both phenomena common around the globe. Large areas of farmland in the Colorado River Basin (CRB) generate salinized drainage water with Se concentrations much higher than 5 μg/L, the U.S. Environmental Protection Agency chronic water-quality criterion for the protection of aquatic life. We have carried out detailed field and laboratory studies to investigate Se geochemistry and remediation in two of these areas: the Middle Green River Basin, Utah and the Salton Sea Basin, California, located respectively in the Upper and Lower CRB. Results from these and other studies show that approximately 90% of the dissolved Se in the Colorado River and its tributaries originally is derived from the Upper Cretaceous Mancos Shale and equivalent pyritic marine units that outcrop in the Upper CRB. Selenium is mobilized commonly by biogeochemical oxidation of this pyritic shale and is concentrated mainly as selenate (SeO4^2-) in soils and agricultural drainage water of dry climates by evaporation. Minor (0%-5%) amounts of Se are present as the selenite species (HSeO3^-) and (SEO3^2-), but these species and the more reduced species, elemental Se (SeO) and selenide (Se^2-), have much lower solubility and/or have high sorptive affinity towards organic matter, clay minerals and iron oxyhydroxides. The concentration of dissolved Se (-2.5 μg/L) and salinity in the Lower Colorado River water are among the highest of the world major rivers. Because of low precipitation (7 cm/a) and extreme evapotranspiration (-1.8 m/a) rates in the Salton Sea Basin, California, Se values in irrigation water imported from the Colorado River increase to 〉300 μg/L in drainage wastewater. Removal of Se from contaminated wastewater by nanofiltration membranes was demonstrated in laboratory and pilot-scale field experiments. 相似文献
13.
胞外聚合物对膜生物反应器运行性能的影响 总被引:3,自引:1,他引:3
膜生物反应器处理污水过程中,依据胞外聚合物(EPS)、蛋白质、多糖、粘度等参数随时间的变化趋势以及对膜通量的影响,求出上述参数及蛋白质/多糖的比值与膜通量间的相关系数分别为0.28、0.57、0.38、0.14、0.70。结果表明:蛋白质/多糖的比值与膜通量的衰减速度两者相关系数最大。 相似文献
14.
Rui CHEN Xiaoli WANG Yonggang ZHANG Xueqi FU 《中国地球化学学报》2006,25(B08):128-129
The use of membranes is a widely employed, versatile, and effective separation process. One of the limiting aspects in applying microfiltration (MF) for wastewater treatment is that of problems with membrane fouling and consequent flux reduction. Membrane fouling occurs by the irreversible deposition of retained particles, colloids, macromolecules, salts, etc. at the membrane surface and/or inside the membrane. The predominant fouling mechanisms observed with MF membranes are classified as three categories: the build-up of a cake layer on the membrane surface, blocking of membrane pores, and adsorption of fouling material on the membrane surface or in the pore walls. Although many techniques have been developed to overcome fouling, studies on membrane cleaning still seem to be insufficient for practical membrane filtration systems. Current membrane cleaning technologies include hydraulic, chemical, and mechanical methods. Ultrasound (US) has been widely used as a method of cleaning materials because of the cavitation phenomenon. In this study, US cleaning technique was applied to removing the fouling of polyvinglidenefluoride (PVDF) MF membrane, which was used to treat yeast cell and isolated soybean protein (ISP) solution, respectively. The US employed 40 kHz frequency and the output power of 1.43-2.85 W/cm^2. The evolution of the cleaning effect is followed by the measurements of the flux recovery rate (FRstat) and the cleaning time cycle. Results showed that the membrane property, which was fouled by yeast cell solution, could be recovered by water cleaning with US irradiation. And the cleaning time with the same FRstat decreased with the increase of US intensity. 相似文献
15.
高温高压下电解质溶液热力学性质的研究不仅对探讨地球内部流体的作用具有重要意义,而且在很多实际工业过程中也都有广泛应用。本综述了近10年来高温高压下电解质溶液热力学参数的实验测量和理论计算的进展,实验设备还有待进一步的改进和完善,以获得更高温度和压力下的数据,理论计算不仅有待于实验的发展,也与溶液的结构理论密切相关。 相似文献
16.
17.
Y. J. Lee R. J. Reeder R. W. Wenskus E. J. Elzinga 《Physics and Chemistry of Minerals》2002,29(9):585-594
Mn K-edge EXAFS spectroscopy of solid-solution samples encompassing the complete MnCO3–CaCO3 series shows that first-shell Mn–O distances deviate little from the 2.19-Å distance observed in pure MnCO3. Very slight lengthening is observed only in the limiting case of dilute Mn(II) calcite solid solutions, where the Mn–O distance is 2.21 Å. The observed nearly complete structural relaxation and the composition independence of the Mn–O distance are consistent with the Pauling model behavior of solid solutions, and agree with previous studies showing a high degree of relaxation around hetero-sized substituents in the calcite structure. Strain occurs through bond bending, which is facilitated by the exclusively corner-sharing topology of calcite. Observed distances from Mn to more distant neighbors show significant variation across the solid-solution series that resembles Vegard's law-type behavior but reflects averaging. The high degree of relaxation suggests modest enthalpies of mixing in the solution, consistent with calorimetric studies. 相似文献
18.
通过月整点值数据文件和滑动值数据文件这两种数据处理形式。对九江台地倾斜资料进行调和分析计算。分析了M2潮汐因子与瑞昌ML4.9级地震的关系。认为存在震前短临异常或震后异常,并与趋势异常得到相互印证。 相似文献
19.
20.
Vegetation, microclimate, seedling frequency, freezing tolerance, and cold acclimation were compared for seedlings of Artemisia tridentata collected from 1775, 2175, and 2575 m elevation in the eastern Sierra Nevada, California. Data were used to test the hypothesis that ecotypic differences in stress physiology are important for seedling survival along gradients from desert to montane ecosystems. The vegetation canopy cover and A. tridentata seedling frequency were greatest at 2575 m, compared to 1775 and 2175 m. Snow cover ameliorated temperatures near the soil surface for part of the winter and depth varied across elevations. Freezing tolerance was compared for seedlings maintained in growth chambers at day/night air temperatures of 25°C/15°C. The temperature at which electrolyte leakage and Photosystem II function (FV/FM) from leaves were half-maximum was approximately −13·5°C for leaves of seedlings from all three elevations. Shifting day/night air temperatures from 25°C/15°C to 15°C/5°C initiated about 1·5° of acclimation by plants from all three altitudes, with seedlings from the highest elevation exhibiting the greatest acclimation change. Measurements of ambient air and canopy temperatures at the three elevations indicated that wintertime average low temperatures were consistent with the measured degree of freezing tolerance. At small spatial scales used in this study, pollen and seed dispersal between study sites may have precluded resolution of ecotypic differences. Patterns of freezing tolerance and cold acclimation may depend on a combination of mesoclimate and microclimate temperatures, canopy cover, snow depth, and snow melt patterns. 相似文献