From surface electrical properties to spontaneous potentials in porous media   总被引：1，自引：0，他引：1  

A. Revil  M. Darot  P. A. Pezard 《Surveys in Geophysics》1996,17(3):331-346

This paper deals with the electrical double layer and the related properties of porous media. In particular, the electrical conductivity, the streaming potential, and the membrane potential are described in a self-consistent set of equations. All these properties are shown to be governed by fluid-matrix interface properties, as well as four geometrical parameters.  相似文献   

Strain segmentation and lateral membrane deformation rate of the subducted Ryukyu slab     

LingYun  Chiao 《Island Arc》1993,2(2):94-103

Abstract Focal mechanisms of intermediate-depth earthquakes within the subducted Ryukyu slab indicate a systematic pattern of down-dip extension in the northern part under Kyushu. These mechanisms switch rapidly around the Tokara channel to down-dip compression in the southern part toward Taiwan. This intriguing pattern of strain segmentation, together with the differences between the slab geometry of the northern and southern parts, has raised the question of whether stress segmentation, as defined possibly by a tear fault, might exist in the slab. However the Ryukyu trench has a concave oceanward shape in the northern segment while it is convex in the southern oceanward part toward Taiwan. The inflection zone is located around the Tokara channel. The concept of Gaussian curvature of a curved surface suggests that the along-arc variation of the geometric configuration of a subducted slab is related to the shape of the trench. This is in order to accommodate the lateral membrane deformation of the slab as the oceanic lithosphere subducts from a spherical shell to the geometry delineated by the Wadati-Benioff zone. The membrane deformation regime of the subducted Ryukyu slab and its relation with the trench geometry was examined by assuming that the subduction be modelled by the flow field of a thin viscous sheet. A projection operator was utilized to compute the membrane strain-rate tensor of an arbitrary non-Euclidean surface. Numerical experiments indicated that the northern segment of the slab was dominated by lateral compression and down-dip extension and the southern part by lateral extension and down-dip compression. This transition is sharply located near the Tokara channel. These patterns were compatible with what had been observed from studies of focal mechanisms, suggesting that the strain segmentation might be controlled, at least in part, by the lateral membrane deformation within the slab due to the trench shape in this subduction zone. The slab geometry was predicted by minimizing the integrated total dissipation power; this revealed distinct features that were consistent with observations. This implies that the slab geometry may also be affected by the membrane deformation in a systematic fashion.  相似文献   

Biofouling confounds the uptake of trace organic contaminants by semi-permeable membrane devices (SPMDs)     

Richardson BJ  Lam PK  Zheng GJ  McClellan KE  De Luca-Abbott SB 《Marine pollution bulletin》2002,44(12):1372-1379

The outer layers of layflat, low density polyethylene plastic tubing (the principal component of semi-permeable membrane devices, SPMDs) were biofouled at a clean site in Hong Kong coastal waters for periods of 1–4 weeks. Following pre-fouling, triolein was added to the SPMDs and, along with control (unfouled) devices, they were exposed to a range of organochlorine pesticides (-HCH, aldrin, p,p^′-DDT) and PAHs (anthracene, fluoranthene and benzo(a)pyrene) under laboratory conditions. Results showed that the uptake of contaminants by SPMDs was severely reduced by as much as 50% under fouling conditions in comparison to unfouled controls. The ultimate utility of SPMDs as passive monitors is thus reduced, although alternative measures, such as the use of permeability reference compounds may compensate, and allow for realistic evaluations of dissolved environmental concentrations in aquatic environments. However, due to the complexities involved in such procedures––especially as they need to be conducted on a case-by-case basis––the utility of SPMDs appears to be limited for estimates of bioavailability unless necessary calibrations are undertaken within each environment that the sampler is used.  相似文献   

On the Occurrence Time of an Earthquake Cluster in the Shanxi Reservoir     

Niu Anfu 《中国地震研究》2006,20(4):406-411

INTRODUCTIONEarthquake induced byreservoir is a kind of crust motion andis an outcome of the joint functionof current crustal movement andreservoir storage .The cause of reservoir-induced earthquakesincludesthe decrease of strengthand elasticity modulus of rockonthe one hand,andthe decrease of friction offault surface because of water permeation onthe other .The more large-scale reservoirs built ,the more reservoir-induced earthquakes will happen.As iswell known,reservoir-induced earthqua…  相似文献   

桩网复合地基桩土应力比的确定     

陈娟  吴西臣 《水文地质工程地质》2007,34(3):116-119

实践证明,桩网复合地基同时具备竖向增强体复合地基与水平向增强体复合地基的加固优点,能很好地提高地基土体承载力,减小不均匀沉降,特别是桥头过渡段地基处理中能有效控制“桥头跳车”现象的产生。本文主要对桩网复合地基的加固机理进行分析,并结合自然平衡拱理论和加筋垫层拉膜效应理论推导出路堤下桩网复合地基桩土应力比计算公式,同时分析了各设计参数变化对桩土应力比的变化规律。工程实体试验表明,本文所推导的桩土应力比计算公式具有较好的适用性。  相似文献   

磺化层柱状有机膦酸锆的合成及催化反应研究     

谢同  彭广志  杨义芳  王桂芬 《盐湖研究》1998,(Z1)

在氢氟酸溶液中,混合亚磷酸、4,4’-联苯二膦酸和锆离子反应生成4,4’-联苯二膦酸锆／亚磷酸锆（简称MCZP）,改变有机酸和亚磷酸的比例,可以合成具有相同组分但结构不同的一系列化合物。通过磺化反应,在苯环上接上磺酸基团后,它具有类似强酸性阳离子交换树脂特性．该文首次对这类化合物催化酯化、醚化等典型的酸催化有机反应进行了研究,结果表明其催化转化率高、催化剂可重复使用和再生,是一种很有发展前途的新型固体酸催化剂．  相似文献   

闪电和固、液态降水关系差异的数值模拟     

郭凤霞  吴鑫  梁梦雪  江涛  陆干沂 《大气科学》2015,39(6):1204-1214

为了进一步认识闪电和固、液态降水的关系,本文利用三维雷暴云动力-电耦合数值模式,通过设置敏感性试验组,模拟了一次雷暴过程,分析雷暴中闪电和降水的特征,以及闪电和固、液态降水对垂直风速的依赖关系,探讨闪电与固、液态降水的时空分布关系和单次闪电表征的降水量(RPF:rainyields per flash)。结果表明:对流云降水中,液态降水占主要部分,但固态降水比液态降水对于垂直风速的依赖性更强。随着对流的增强,固态降水在总降水中占的比重越来越大。首次放电时间不断提前,闪电峰值落后垂直风速峰值,总闪数一开始随对流的增强而增加,对流一旦增强到一定程度,总闪数则逐渐减小。固态降水和液态降水的开始时间和峰值时间均随着对流的增强而不断提前,而液态降水出现时间和峰值时间均提前于固态降水。雷暴云首次放电的时间滞后于液态降水,而闪电峰值提前固态降水峰值或与固态降水峰值同时产生。雷暴云中的放电活动集中在强降水区域前缘的较弱降水区,强降水区对应的闪电较少,对流的增强会使降水区域面积、降水量和降水强度增加。由于液态降水总量远大于固态降水总量,固、液态RPF的数值相差达到一个量级,但单位时间内固态降水和液态降水增加的速率相近。在单位时间内闪电次数越多,RPF则越小,而固态RPF和闪电次数的线性相关性明显好于液态RPF,所以利用固态降水可以更好地预报闪电。这些结果有助于进一步认识闪电和降水的关系,并可为闪电预报提供新的思路。  相似文献   

条斑紫菜类囊体膜蛋白质组双向电泳研究方法     

周伟  何林文  陆勤勤  朱建一  高山  杨睿灵  杨芳  王广策 《海洋科学》2014,38(3):63-68

以蓝绿温和胶电泳为工具,首次在国内用于条斑紫菜(Porphyra yezoensis)类囊体膜色素蛋白质复合物的研究。结果显示:(1)利用非离子型去污剂十二烷基麦芽糖苷(DM)增溶条斑紫菜类囊体膜,DM/Chla(w/w)15︰1产生的效果较好,在BN-PAGE胶中可以分离到较多较清晰的条带。(2)选取蔗糖密度层50%条带制备得到的类囊体膜样品进行第一向BN-PAGE和第二向SDS-Urea-PAGE电泳实验。第一向电泳分离出4个蛋白复合物,对第二向电泳胶上的15个蛋白点切取做质谱鉴定,检测到PSⅡ47ku,PSⅡ44ku,cytochrome f,PSⅡD2,PSⅡD1等蛋白。本实验证实了温和胶电泳与SDS电泳结合对于条斑紫菜这种原始红藻的类囊体膜研究方面应用的可行性。  相似文献   

商业平板式超滤膜包完整性检验：对海洋胶体生物地球化学研究的启示     

LIN Liangshi  CAI Yihu  SUN Xiuwu  CHEN Min 《海洋学报(英文版)》2014,33(9):109-116

The performance and integrity of a cassette cross-flow ultrafilter(Pellicon 2, Millipore) are examined with a suite of macromolecules of different molecular masses. The retention coefficient during the cross-flow ultrafiltration experiments increases with increasing molecular mass and reaches 90% with 10 kDa dextran in both milli-Q water and ultrafiltered seawater media. Based on a 90% retention coefficient, the molecular mass cut-off for the ultrafiltration membrane is defined at 10 kDa, which is ten times(1 kDa) that rated by the manufacturer. To further validate the accuracy of the laboratory calibration, the samples from the lower Zhujiang River and the Jiulong River Estuary are ultrafiltered with the cassette ultrafiltration membrane and the colloidal organic carbon abundances in these samples are quantified with the ultrafiltration permeation model based on time series permeation subsamples. The colloidal organic carbon abundances are 5.8%–21.1% in the Jiulong River Estuary and 5.6%–11.0% in the lower Zhujiang River. These are consistent with the reported values for both estuaries as well as with the colloidal organic carbon abundances in marine environments over the coastal and open oceans with 10 kDa cut-off membranes. Therefore, these field data support the laboratory calibration result and indicate the validity of the experimental and quantification procedure adopted. The discrepancy between the nominal molecular mass cut-off and the actual pore size of the ultrafiltration membrane should be of great concern for research in colloidal and nanoparticle biogeochemistry. Careful examination of the membrane integrity should be taken during ultrafiltration experiments in order to avoid misleading molecular mass cut-off information.  相似文献   

华北平原某集约化种植区地下水污染探讨   总被引：2，自引：0，他引：2  

刘瑾  费宇红  张兆吉  李亚松  崔向向  雷廷  吴国庆 《地球学报》2014,35(2):197-203

以华北平原某集约化种植区为典型研究区域,通过对采集的8个地下水样品及11个土壤样品分析,探讨集约化种植区地下水的污染程度,解析其污染影响机制。结果表明:该集约化种植地区土壤中残留物主要为有机氯农药,多环芳烃及邻苯二甲酸酯类有机化合物。地下水中硝酸盐含量显著增加;重金属中以Cr含量最高,但均未超标;地下水并未受到有机氯农药的污染,但仍显示有多氯联苯的输入;半挥发性有机物检出种类较多,其中残留农膜释放的邻苯二甲酸酯类有机化合物浓度最高;地下水已受到较为严重的污染。集约化种植区大量施用化肥、农药和覆盖农膜,污染负荷严重,灌溉频繁且量大,污染质运移驱动力大是地下水污染的根本原因;当地包气带中黏性土厚度不均以及井孔止水不严等因素也成为了地下水受到污染的直接原因。  相似文献